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Experimental evaluation of a pilot-scale thermochemical storage system for a concentrated solar power plant

Author

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  • Tescari, S.
  • Singh, A.
  • Agrafiotis, C.
  • de Oliveira, L.
  • Breuer, S.
  • Schlögl-Knothe, B.
  • Roeb, M.
  • Sattler, C.

Abstract

A first of its kind pilot-scale redox-based thermochemical storage system has been set up and operated under near-realistic conditions inside a solar power tower plant. The storage unit is made of inert honeycomb supports (cordierite) coated with 88kg of redox active material (cobalt oxide). An experimental campaign has been carried out consisting of 22 thermochemical charge-discharge cycles. The heat absorbed or released by the chemical reaction became clearly evident through the temperature evolution inside the reactive material. It allows to store or release energy at constant temperature when crossing respectively the reduction/oxidation temperature of the Co3O4/CoO pair. A storage performance factor (PF) was defined to evaluate how each experiment approaches the ideal behavior. During the complete campaign no measurable cycle-to-cycle degradation was observed and the system average capacity was very close to the ideal case of PF=0.84. The advantage of thermochemical storage could be quantified by comparing the storage capacity, to that of a sensible-only storage unit made of uncoated cordierite honeycombs. The thermochemical system offered almost double storage capacity (47.0kWh) cf. the same volume of the sensible-only case (25.3kWh).

Suggested Citation

  • Tescari, S. & Singh, A. & Agrafiotis, C. & de Oliveira, L. & Breuer, S. & Schlögl-Knothe, B. & Roeb, M. & Sattler, C., 2017. "Experimental evaluation of a pilot-scale thermochemical storage system for a concentrated solar power plant," Applied Energy, Elsevier, vol. 189(C), pages 66-75.
    • Handle: RePEc:eee:appene:v:189:y:2017:i:c:p:66-75
    DOI: 10.1016/j.apenergy.2016.12.032
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    14. Avila-Marin, Antonio L. & Alvarez de Lara, Monica & Fernandez-Reche, Jesus, 2018. "Experimental results of gradual porosity volumetric air receivers with wire meshes," Renewable Energy, Elsevier, vol. 122(C), pages 339-353.
    15. Mehrabadi, Abbas & Crotet, Engie & Farid, Mohammed, 2018. "An innovative approach for storing low-grade thermal energy using liquid phase thermoreversible reaction," Applied Energy, Elsevier, vol. 222(C), pages 823-829.
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    18. Benitez-Guerrero, Monica & Valverde, Jose Manuel & Perejon, Antonio & Sanchez-Jimenez, Pedro E. & Perez-Maqueda, Luis A., 2018. "Low-cost Ca-based composites synthesized by biotemplate method for thermochemical energy storage of concentrated solar power," Applied Energy, Elsevier, vol. 210(C), pages 108-116.
    19. Piperopoulos, Elpida & Mastronardo, Emanuela & Fazio, Marianna & Lanza, Maurizio & Galvagno, Signorino & Milone, Candida, 2018. "Enhancing the volumetric heat storage capacity of Mg(OH)2 by the addition of a cationic surfactant during its synthesis," Applied Energy, Elsevier, vol. 215(C), pages 512-522.
    20. Avila-Marin, A.L. & Fernandez-Reche, J. & Martinez-Tarifa, A., 2019. "Modelling strategies for porous structures as solar receivers in central receiver systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 15-33.
    21. Imponenti, Luca & Albrecht, Kevin J. & Kharait, Rounak & Sanders, Michael D. & Jackson, Gregory S., 2018. "Redox cycles with doped calcium manganites for thermochemical energy storage to 1000 °C," Applied Energy, Elsevier, vol. 230(C), pages 1-18.
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    23. Hofsink, Jordy & Singh, Abhishek K., 2024. "Sodium thermal electrochemical converter coupled with organic Rankine cycle and thermochemical heat storage for power-heat-power application," Renewable Energy, Elsevier, vol. 222(C).

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