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Identifying iron-based oxygen carrier reduction during biomass chemical looping gasification on a thermogravimetric fixed-bed reactor

Author

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  • Zeng, Jimin
  • Xiao, Rui
  • Zhang, Shuai
  • Zhang, Huiyan
  • Zeng, Dewang
  • Qiu, Yu
  • Ma, Zhong

Abstract

Establishing a direct relationship between the mass change of iron-based oxygen carrier and gas production is crucial for the efficient operation and the control of the lattice oxygen release in biomass chemical looping gasification. In this study, a thermogravimetric fixed-bed reactor was designed to achieve the simultaneous measurement of the mass change and gas composition in the reduction of the oxygen carrier. Three oxygen carriers of pure iron (III) oxide, natural hematite, and red mud were used as candidates. The phase transfer of the oxygen carrier along with the biomass pyrolysis/gasification was studied. The mass loss rates and the gas composition were matched by three significant phase transition stages. The phase transitions from Fe2O3 to Fe3O4, Fe3O4 to FeO, and FeO to Fe occurred when CO appeared, CO/CO2 = 0.97, and CO/CO2 = 2.61, respectively. The extent of oxygen carrier reduction was 28.61% of pure iron (III) oxide, whereas the oxygen carrier reduction molar ratio was 74.50% of red mud. X-ray diffraction (XRD) spectrums showed the oxygen carrier was reduced to the metallic iron phase. Sintering and agglomeration were found in the reacted oxygen carriers of the scanning electron microscope (SEM) images.

Suggested Citation

  • Zeng, Jimin & Xiao, Rui & Zhang, Shuai & Zhang, Huiyan & Zeng, Dewang & Qiu, Yu & Ma, Zhong, 2018. "Identifying iron-based oxygen carrier reduction during biomass chemical looping gasification on a thermogravimetric fixed-bed reactor," Applied Energy, Elsevier, vol. 229(C), pages 404-412.
    • Handle: RePEc:eee:appene:v:229:y:2018:i:c:p:404-412
    DOI: 10.1016/j.apenergy.2018.08.025
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    1. Chen, Liangyong & Bao, Jinhua & Kong, Liang & Combs, Megan & Nikolic, Heather S. & Fan, Zhen & Liu, Kunlei, 2016. "The direct solid-solid reaction between coal char and iron-based oxygen carrier and its contribution to solid-fueled chemical looping combustion," Applied Energy, Elsevier, vol. 184(C), pages 9-18.
    2. Chen, Liangyong & Kong, Liang & Bao, Jinhua & Combs, Megan & Nikolic, Heather S. & Fan, Zhen & Liu, Kunlei, 2017. "Experimental evaluations of solid-fueled pressurized chemical looping combustion – The effects of pressure, solid fuel and iron-based oxygen carriers," Applied Energy, Elsevier, vol. 195(C), pages 1012-1022.
    3. Zhang, Shuai & Xiao, Rui & Zheng, Wenguang, 2014. "Comparative study between fluidized-bed and fixed-bed operation modes in pressurized chemical looping combustion of coal," Applied Energy, Elsevier, vol. 130(C), pages 181-189.
    4. Darmawan, Arif & Ajiwibowo, Muhammad W. & Yoshikawa, Kunio & Aziz, Muhammad & Tokimatsu, Koji, 2018. "Energy-efficient recovery of black liquor through gasification and syngas chemical looping," Applied Energy, Elsevier, vol. 219(C), pages 290-298.
    5. Huang, Zhen & He, Fang & Zhu, Huangqing & Chen, Dezhen & Zhao, Kun & Wei, Guoqiang & Feng, Yipeng & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2015. "Thermodynamic analysis and thermogravimetric investigation on chemical looping gasification of biomass char under different atmospheres with Fe2O3 oxygen carrier," Applied Energy, Elsevier, vol. 157(C), pages 546-553.
    6. Shuai Zhang & Rui Xiao, 2016. "Performance of iron ore oxygen carrier modified by biomass ashes in coal‐fueled chemical looping combustion," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 6(5), pages 695-709, October.
    7. Zaini, Ilman Nuran & Nurdiawati, Anissa & Aziz, Muhammad, 2017. "Cogeneration of power and H2 by steam gasification and syngas chemical looping of macroalgae," Applied Energy, Elsevier, vol. 207(C), pages 134-145.
    8. Sarafraz, M.M. & Jafarian, M. & Arjomandi, M. & Nathan, G.J., 2017. "Potential use of liquid metal oxides for chemical looping gasification: A thermodynamic assessment," Applied Energy, Elsevier, vol. 195(C), pages 702-712.
    9. Umeki, Kentaro & Yamamoto, Kouichi & Namioka, Tomoaki & Yoshikawa, Kunio, 2010. "High temperature steam-only gasification of woody biomass," Applied Energy, Elsevier, vol. 87(3), pages 791-798, March.
    10. Siriwardane, Ranjani & Riley, Jarrett & Tian, Hanjing & Richards, George, 2016. "Chemical looping coal gasification with calcium ferrite and barium ferrite via solid–solid reactions," Applied Energy, Elsevier, vol. 165(C), pages 952-966.
    11. Tong, Andrew & Bayham, Samuel & Kathe, Mandar V. & Zeng, Liang & Luo, Siwei & Fan, Liang-Shih, 2014. "Iron-based syngas chemical looping process and coal-direct chemical looping process development at Ohio State University," Applied Energy, Elsevier, vol. 113(C), pages 1836-1845.
    12. Riley, Jarrett & Siriwardane, Ranjani & Tian, Hanjing & Benincosa, William & Poston, James, 2017. "Kinetic analysis of the interactions between calcium ferrite and coal char for chemical looping gasification applications: Identifying reduction routes and modes of oxygen transfer," Applied Energy, Elsevier, vol. 201(C), pages 94-110.
    13. Huang, Zhen & He, Fang & Zheng, Anqing & Zhao, Kun & Chang, Sheng & Zhao, Zengli & Li, Haibin, 2013. "Synthesis gas production from biomass gasification using steam coupling with natural hematite as oxygen carrier," Energy, Elsevier, vol. 53(C), pages 244-251.
    14. Cho, Won Chul & Lee, Doyeon & Kim, Chang Hee & Cho, Hyun Suk & Kim, Sang Done, 2018. "Feasibility study of the use of by-product iron oxide and industrial off-gas for application to chemical looping hydrogen production," Applied Energy, Elsevier, vol. 216(C), pages 466-481.
    15. Källén, Malin & Rydén, Magnus & Lyngfelt, Anders & Mattisson, Tobias, 2015. "Chemical-looping combustion using combined iron/manganese/silicon oxygen carriers," Applied Energy, Elsevier, vol. 157(C), pages 330-337.
    16. Wetterlund, Elisabeth & Söderström, Mats, 2010. "Biomass gasification in district heating systems - The effect of economic energy policies," Applied Energy, Elsevier, vol. 87(9), pages 2914-2922, September.
    17. Huang, Zhen & Deng, Zhengbing & Chen, Dezhen & He, Fang & Liu, Shuai & Zhao, Kun & Wei, Guoqiang & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2017. "Thermodynamic analysis and kinetic investigations on biomass char chemical looping gasification using Fe-Ni bimetallic oxygen carrier," Energy, Elsevier, vol. 141(C), pages 1836-1844.
    18. Hua, Xiuning & Fan, Yiran & Wang, Yidi & Fu, Tiantian & Fowler, G.D. & Zhao, Dongmei & Wang, Wei, 2017. "The behaviour of multiple reaction fronts during iron (III) oxide reduction in a non-steady state packed bed for chemical looping water splitting," Applied Energy, Elsevier, vol. 193(C), pages 96-111.
    19. Tang, Mingchen & Xu, Long & Fan, Maohong, 2015. "Progress in oxygen carrier development of methane-based chemical-looping reforming: A review," Applied Energy, Elsevier, vol. 151(C), pages 143-156.
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