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Chemical-looping combustion using combined iron/manganese/silicon oxygen carriers

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  • Källén, Malin
  • Rydén, Magnus
  • Lyngfelt, Anders
  • Mattisson, Tobias

Abstract

Combined oxides of iron, manganese and silicon have been used as oxygen carriers for chemical-looping combustion. Three materials with varying composition of iron, manganese and silicon have been evaluated in oxygen release experiments and during continuous operation with syngas and natural gas as fuels. The concentration of oxygen released increased as a function of temperature and the highest concentrations of oxygen were measured with the material with the highest fraction of manganese. It was also this material which gave the best conversion of both syngas and natural gas; essentially full conversion of syngas and above 95% conversion of natural gas above 900°C. The other two materials showed similar performance, albeit with higher syngas conversion for the material with the lowest manganese fraction and the lowest conversion of natural gas for the same material. The materials lasted for 10–14h of operation with fuel addition before circulation disruption occurred, which was likely caused by particle attrition in all three cases. A phase diagram of the iron–manganese–silicon–oxide system was constructed and the possible relevant phase transitions were identified. This analysis showed that more phase transitions could be expected for the materials with higher manganese content which could explain the superior performance during fuel operation of the material with the highest manganese content. It should however be noted that this material was operated with the highest fuel reactor inventory per thermal power which could also be a contributing factor to the better performance of this material.

Suggested Citation

  • Källén, Malin & Rydén, Magnus & Lyngfelt, Anders & Mattisson, Tobias, 2015. "Chemical-looping combustion using combined iron/manganese/silicon oxygen carriers," Applied Energy, Elsevier, vol. 157(C), pages 330-337.
    • Handle: RePEc:eee:appene:v:157:y:2015:i:c:p:330-337
    DOI: 10.1016/j.apenergy.2015.03.136
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    References listed on IDEAS

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    1. Arjmand, Mehdi & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Investigation of different manganese ores as oxygen carriers in chemical-looping combustion (CLC) for solid fuels," Applied Energy, Elsevier, vol. 113(C), pages 1883-1894.
    2. Lyngfelt, Anders, 2014. "Chemical-looping combustion of solid fuels – Status of development," Applied Energy, Elsevier, vol. 113(C), pages 1869-1873.
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    Cited by:

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    2. Zeng, Jimin & Xiao, Rui & Zhang, Shuai & Zhang, Huiyan & Zeng, Dewang & Qiu, Yu & Ma, Zhong, 2018. "Identifying iron-based oxygen carrier reduction during biomass chemical looping gasification on a thermogravimetric fixed-bed reactor," Applied Energy, Elsevier, vol. 229(C), pages 404-412.
    3. Adánez-Rubio, Iñaki & Abad, Alberto & Gayán, Pilar & García-Labiano, Francisco & de Diego, Luis F. & Adánez, Juan, 2017. "Coal combustion with a spray granulated Cu-Mn mixed oxide for the Chemical Looping with Oxygen Uncoupling (CLOU) process," Applied Energy, Elsevier, vol. 208(C), pages 561-570.
    4. Cho, Won Chul & Lee, Jun Kyu & Nam, Gyeong Duk & Kim, Chang Hee & Cho, Hyun-Seok & Joo, Jong Hoon, 2019. "Degradation analysis of mixed ionic-electronic conductor-supported iron-oxide oxygen carriers for chemical-looping conversion of methane," Applied Energy, Elsevier, vol. 239(C), pages 644-657.
    5. Khallaghi, Navid & Hanak, Dawid P. & Manovic, Vasilije, 2019. "Gas-fired chemical looping combustion with supercritical CO2 cycle," Applied Energy, Elsevier, vol. 249(C), pages 237-244.
    6. Huang, Xin & Fan, Maohong & Wang, Xingjun & Wang, Yonggang & Argyle, Morris D. & Zhu, Yufei, 2018. "A cost-effective approach to realization of the efficient methane chemical-looping combustion by using coal fly ash as a support for oxygen carrier," Applied Energy, Elsevier, vol. 230(C), pages 393-402.
    7. Ksepko, Ewelina & Babiński, Piotr & Nalbandian, Lori, 2017. "The redox reaction kinetics of Sinai ore for chemical looping combustion applications," Applied Energy, Elsevier, vol. 190(C), pages 1258-1274.

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