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Spinel ferrite-contained industrial materials as oxygen carriers in chemical looping combustion

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  • Di, Zichen
  • Yilmaz, Duygu
  • Biswas, Arijit
  • Cheng, Fangqin
  • Leion, Henrik

Abstract

Spinel ferrites (MxFe3-xO4) as oxygen carriers (OC) in chemical looping combustion (CLC) process have drawn significant interest owing to unique lattice structure and oxygen transfer properties. However, their employment in practice is likely cost prohibitive due to the complicated synthesis processes compared to natural occurring materials. In the work, several of the low-cost industrial materials naturally containing ferrite spinel structure (MxFe3-xO4, M = Cr and Mn) were, for the first time, investigated to explore the possibility as an alternative of synthetic OCs. The reactivity and their cyclic performance during the chemical looping combustion were examined by lab-scale fluidized bed and TGA. It was demonstrated that all the tested materials contain spinel structures, especially after CLC cycles. They exhibited almost the same reactivity and stability, and less agglomeration occurred when compared to the synthetic materials contain the same kind of spinel structure. But the tested materials presented lower oxygen transport capacity than the synthetic ones. Specifically, the FM1 material containing MnFe2O4 showed best reactivity towards CH4 and syngas conversion, which may attribute to the oxygen uncoupling ability of Mn based species and the formation of spinel ferromanganese structure. But the stability was not good enough. It may because of the cracked particles attributing to the shrinking during the reduction of Mn2O3 to Mn3O4. The Fe-Cr based sample showed more superior stability and improved performance due to the formation of (Fe,Mg)(Cr,Fe)2O4 spinel structure. The Fe-Cr based samples exhibit poor performance for complete combustion of fuel; however, it appears to convert more CH4 to CO which may be desirable for hydrogenation, gasification, and cracking processes. It is worth noting that these industrial materials did not show significant difference in reactivity and stability when compared to the same kind of synthetic materials, presenting a possibility of potential substitution, especially taking its low cost into account.

Suggested Citation

  • Di, Zichen & Yilmaz, Duygu & Biswas, Arijit & Cheng, Fangqin & Leion, Henrik, 2022. "Spinel ferrite-contained industrial materials as oxygen carriers in chemical looping combustion," Applied Energy, Elsevier, vol. 307(C).
    • Handle: RePEc:eee:appene:v:307:y:2022:i:c:s0306261921015579
    DOI: 10.1016/j.apenergy.2021.118298
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    References listed on IDEAS

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    1. Gu, Zhenhua & Zhang, Ling & Lu, Chunqiang & Qing, Shan & Li, Kongzhai, 2020. "Enhanced performance of copper ore oxygen carrier by red mud modification for chemical looping combustion," Applied Energy, Elsevier, vol. 277(C).
    2. Rane, V. H. & Rajput, A. M. & Karkamkar, A. J. & Choudhary, V. R., 2004. "Energy-efficient conversion of propane to propylene and ethylene over a V2O5/CeO2/SA5205 catalyst in the presence of limited oxygen," Applied Energy, Elsevier, vol. 77(4), pages 375-382, April.
    3. Do, Jeong Yeon & Son, Namgyu & Park, No-Kuk & Kwak, Byeong Sub & Baek, Jeom-In & Ryu, Ho-Jung & Kang, Misook, 2018. "Reliable oxygen transfer in MgAl2O4 spinel through the reversible formation of oxygen vacancies by Cu2+/Fe3+ anchoring," Applied Energy, Elsevier, vol. 219(C), pages 138-150.
    4. Benincosa, William & Siriwardane, Ranjani & Tian, Hanjing & Riley, Jarrett & Poston, James, 2020. "A particle-scale reduction model of copper iron manganese oxide with CO for chemical looping combustion," Applied Energy, Elsevier, vol. 262(C).
    5. Abad, A. & Pérez-Vega, R. & de Diego, L.F. & Gayán, P. & Izquierdo, M.T. & García-Labiano, F. & Adánez, J., 2019. "Thermochemical assessment of chemical looping assisted by oxygen uncoupling with a MnFe-based oxygen carrier," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    6. Miller, Duane D. & Siriwardane, Ranjani & Poston, James, 2015. "Fluidized-bed and fixed-bed reactor testing of methane chemical looping combustion with MgO-promoted hematite," Applied Energy, Elsevier, vol. 146(C), pages 111-121.
    7. Zeng, Jimin & Xiao, Rui & Zhang, Shuai & Zhang, Huiyan & Zeng, Dewang & Qiu, Yu & Ma, Zhong, 2018. "Identifying iron-based oxygen carrier reduction during biomass chemical looping gasification on a thermogravimetric fixed-bed reactor," Applied Energy, Elsevier, vol. 229(C), pages 404-412.
    8. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.
    9. Wang, Haiming & Dou, Xiaomin & Veksha, Andrei & Liu, Wen & Giannis, Apostolos & Ge, Liya & Thye Lim, Teik & Lisak, Grzegorz, 2020. "Barium aluminate improved iron ore for the chemical looping combustion of syngas," Applied Energy, Elsevier, vol. 272(C).
    10. Haider, S.K. & Azimi, G. & Duan, L. & Anthony, E.J. & Patchigolla, K. & Oakey, J.E. & Leion, H. & Mattisson, T. & Lyngfelt, A., 2016. "Enhancing properties of iron and manganese ores as oxygen carriers for chemical looping processes by dry impregnation," Applied Energy, Elsevier, vol. 163(C), pages 41-50.
    11. Rydén, Magnus & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Combined oxides as oxygen-carrier material for chemical-looping with oxygen uncoupling," Applied Energy, Elsevier, vol. 113(C), pages 1924-1932.
    12. Liu, Shuai & Xiang, Dong & Xu, Ying & Sun, Zhe & Cao, Yan, 2017. "Relationship between electronic properties of Fe3O4 substituted by Ca and Ba and their reactivity in chemical looping process: A first-principles study," Applied Energy, Elsevier, vol. 202(C), pages 550-557.
    13. Deng, Guixian & Li, Kongzhai & Zhang, Guifang & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Wang, Hua, 2019. "Enhanced performance of red mud-based oxygen carriers by CuO for chemical looping combustion of methane," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    14. Arjmand, Mehdi & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Investigation of different manganese ores as oxygen carriers in chemical-looping combustion (CLC) for solid fuels," Applied Energy, Elsevier, vol. 113(C), pages 1883-1894.
    15. Guo, Jian-Xin & Huang, Chen, 2020. "Feasible roadmap for CCS retrofit of coal-based power plants to reduce Chinese carbon emissions by 2050," Applied Energy, Elsevier, vol. 259(C).
    16. Sun, Zhenkun & Lu, Dennis Y. & Ridha, Firas N. & Hughes, Robin W. & Filippou, Dimitrios, 2017. "Enhanced performance of ilmenite modified by CeO2, ZrO2, NiO, and Mn2O3 as oxygen carriers in chemical looping combustion," Applied Energy, Elsevier, vol. 195(C), pages 303-315.
    17. Qiu, Yu & Zhang, Shuai & Cui, Dongxu & Li, Min & Zeng, Jimin & Zeng, Dewang & Xiao, Rui, 2019. "Enhanced hydrogen production performance at intermediate temperatures through the synergistic effects of binary oxygen carriers," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    18. Chen, Yu-Yen & Nadgouda, Sourabh & Shah, Vedant & Fan, Liang-Shih & Tong, Andrew, 2020. "Oxidation kinetic modelling of Fe-based oxygen carriers for chemical looping applications: Impact of the topochemical effect," Applied Energy, Elsevier, vol. 279(C).
    19. Zhao, Haibo & Guo, Lei & Zou, Xixian, 2015. "Chemical-looping auto-thermal reforming of biomass using Cu-based oxygen carrier," Applied Energy, Elsevier, vol. 157(C), pages 408-415.
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    2. Wu, Shijie & Ren, Zongqiang & Hu, Qiang & Yao, Dingding & Yang, Haiping, 2024. "Upcycling plastic waste into syngas by staged chemical looping gasification with modified Fe-based oxygen carriers," Applied Energy, Elsevier, vol. 353(PB).

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