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Cellulose gasification with Ca–Fe oxygen carrier in chemical-looping process

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  • Tang, Genyang
  • Gu, Jing
  • Huang, Zhen
  • Yuan, Haoran
  • Chen, Yong

Abstract

Biomass-derived chemical looping gasification (BCLG) is a novel technology for lignocellulose energy applications. Ca–Fe oxygen carriers have been proven to be a potential material for efficient lignocellulose conversion and hydrogen-enriched syngas production in process studies. In this study, Thermogravimetry-mass spectrometry (TG-MS), pyrolysis chromatography-mass spectrometry (Py-GC-MS) and fixed-bed experiments were conducted, and the cellulose BCLG product was analyzed to explore the mechanism of reaction between Ca–Fe OCs and biomass char or volatiles. The mechanism of the synergistic effect of Ca–Fe was analyzed to explain the characteristics of the OCs. The results suggest the Ca-based materials act as catalysts to promote the decomposition of cellulose monomers at primary reaction and char at secondary reaction, and also promote the reforming and oxidation of volatiles by chemisorption. Ca participates in the construction of inert substances, such as Ca2Fe2O5, to avoid the deep oxidation of CO and H2. Fe-based material supplies oxygen and promotes the reforming of volatile. Compared with Fe2O3 and CaO/Fe2O3, CaFe2O4 shows a better performance on carbon conversion and H2 production below 850 °C.

Suggested Citation

  • Tang, Genyang & Gu, Jing & Huang, Zhen & Yuan, Haoran & Chen, Yong, 2022. "Cellulose gasification with Ca–Fe oxygen carrier in chemical-looping process," Energy, Elsevier, vol. 239(PD).
    • Handle: RePEc:eee:energy:v:239:y:2022:i:pd:s036054422102452x
    DOI: 10.1016/j.energy.2021.122204
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    1. Sadeghinezhad, E. & Kazi, S.N. & Sadeghinejad, Foad & Badarudin, A. & Mehrali, Mohammad & Sadri, Rad & Reza Safaei, Mohammad, 2014. "A comprehensive literature review of bio-fuel performance in internal combustion engine and relevant costs involvement," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 29-44.
    2. Ronald W. Breault, 2010. "Gasification Processes Old and New: A Basic Review of the Major Technologies," Energies, MDPI, vol. 3(2), pages 1-25, February.
    3. Sansaniwal, S.K. & Rosen, M.A. & Tyagi, S.K., 2017. "Global challenges in the sustainable development of biomass gasification: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 23-43.
    4. Sun, Zhao & Chen, Shiyi & Russell, Christopher K. & Hu, Jun & Rony, Asif H. & Tan, Gang & Chen, Aimin & Duan, Lunbo & Boman, John & Tang, Jinke & Chien, TeYu & Fan, Maohong & Xiang, Wenguo, 2018. "Improvement of H2-rich gas production with tar abatement from pine wood conversion over bi-functional Ca2Fe2O5 catalyst: Investigation of inner-looping redox reaction and promoting mechanisms," Applied Energy, Elsevier, vol. 212(C), pages 931-943.
    5. Fang, Shiwen & Deng, Zhengbing & Lin, Yan & Huang, Zhen & Ding, Lixing & Deng, Lisheng & Huang, Hongyu, 2021. "Nitrogen migration in sewage sludge chemical looping gasification using copper slag modified by NiO as an oxygen carrier," Energy, Elsevier, vol. 228(C).
    6. Detchusananard, Thanaphorn & Im-orb, Karittha & Maréchal, François & Arpornwichanop, Amornchai, 2020. "Analysis of the sorption-enhanced chemical looping biomass gasification process: Performance assessment and optimization through design of experiment approach," Energy, Elsevier, vol. 207(C).
    7. Soudagar, Manzoore Elahi M. & Mujtaba, M.A. & Safaei, Mohammad Reza & Afzal, Asif & V, Dhana Raju & Ahmed, Waqar & Banapurmath, N.R. & Hossain, Nazia & Bashir, Shahid & Badruddin, Irfan Anjum & Goodar, 2021. "Effect of Sr@ZnO nanoparticles and Ricinus communis biodiesel-diesel fuel blends on modified CRDI diesel engine characteristics," Energy, Elsevier, vol. 215(PA).
    8. Wang, Kun & An, Zewen & Wang, Fengyin & Liang, Wenzheng & Wang, Cuiping & Guo, Qingjie & Liu, Yongzhuo & Yue, Guangxi, 2021. "Effect of ash on the performance of iron-based oxygen carrier in the chemical looping gasification of municipal sludge," Energy, Elsevier, vol. 231(C).
    9. M. M. Sarafraz & Mohammad Reza Safaei & M. Jafarian & Marjan Goodarzi & M. Arjomandi, 2019. "High Quality Syngas Production with Supercritical Biomass Gasification Integrated with a Water–Gas Shift Reactor," Energies, MDPI, vol. 12(13), pages 1-14, July.
    10. Siriwardane, Ranjani & Riley, Jarrett & Tian, Hanjing & Richards, George, 2016. "Chemical looping coal gasification with calcium ferrite and barium ferrite via solid–solid reactions," Applied Energy, Elsevier, vol. 165(C), pages 952-966.
    11. Riley, Jarrett & Siriwardane, Ranjani & Tian, Hanjing & Benincosa, William & Poston, James, 2017. "Kinetic analysis of the interactions between calcium ferrite and coal char for chemical looping gasification applications: Identifying reduction routes and modes of oxygen transfer," Applied Energy, Elsevier, vol. 201(C), pages 94-110.
    12. Huang, Zhen & Deng, Zhengbing & Chen, Dezhen & He, Fang & Liu, Shuai & Zhao, Kun & Wei, Guoqiang & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2017. "Thermodynamic analysis and kinetic investigations on biomass char chemical looping gasification using Fe-Ni bimetallic oxygen carrier," Energy, Elsevier, vol. 141(C), pages 1836-1844.
    13. Liu, Guicai & Liao, Yanfen & Wu, Yuting & Ma, Xiaoqian, 2018. "Synthesis gas production from microalgae gasification in the presence of Fe2O3 oxygen carrier and CaO additive," Applied Energy, Elsevier, vol. 212(C), pages 955-965.
    Full references (including those not matched with items on IDEAS)

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