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Demonstrating the potential of iron-doped strontium titanate electrolyte with high-performance for low temperature ceramic fuel cells

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  • Shah, M.A.K. Yousaf
  • Lu, Yuzheng
  • Mushtaq, Naveed
  • Rauf, Sajid
  • Yousaf, Muhammad
  • Asghar, Muhammad Imran
  • Lund, Peter D.
  • Zhu, Bin

Abstract

Electrolytes with high-proton conduction and low activation energy are attractive for reducing the high operating temperature of solid-oxide fuel cells to less than <600 °C. In this work, we have fabricated semiconducting electrolyte SrFeTiO3-δ (SFT) material exhibiting high ionic conduction and exceptionally high protonic conduction at low operating temperature but with low electronic conduction to evade the short-circuiting issue. The prepared fuel cell device exhibited high open-circuit voltage (OCV) and a high-power output of 534 mW/cm2, of which 474 mW/cm2 could be for sure be related to the protonic part. The current study suggests that usage of semiconductor SrFeTiO3-δ facilitates a high concentration of oxygen vacancies on the surface of SFT, which mainly benefits proton conduction. Moreover, lower grain boundary resistance leads to obtain higher performance. Also, the Schottky junction phenomena are proposed to inhibit the e-conduction and excel the ions transportation. The high performance and ionic conductivity suggest that SFT could be a promising electrolyte for protonic ceramic fuel cells.

Suggested Citation

  • Shah, M.A.K. Yousaf & Lu, Yuzheng & Mushtaq, Naveed & Rauf, Sajid & Yousaf, Muhammad & Asghar, Muhammad Imran & Lund, Peter D. & Zhu, Bin, 2022. "Demonstrating the potential of iron-doped strontium titanate electrolyte with high-performance for low temperature ceramic fuel cells," Renewable Energy, Elsevier, vol. 196(C), pages 901-911.
    • Handle: RePEc:eee:renene:v:196:y:2022:i:c:p:901-911
    DOI: 10.1016/j.renene.2022.06.154
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    References listed on IDEAS

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    1. Chen Xia & Youquan Mi & Baoyuan Wang & Bin Lin & Gang Chen & Bin Zhu, 2019. "Shaping triple-conducting semiconductor BaCo0.4Fe0.4Zr0.1Y0.1O3-δ into an electrolyte for low-temperature solid oxide fuel cells," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    2. You Zhou & Xiaofei Guan & Hua Zhou & Koushik Ramadoss & Suhare Adam & Huajun Liu & Sungsik Lee & Jian Shi & Masaru Tsuchiya & Dillon D. Fong & Shriram Ramanathan, 2016. "Strongly correlated perovskite fuel cells," Nature, Nature, vol. 534(7606), pages 231-234, June.
    3. Seungdoo Park & John M. Vohs & Raymond J. Gorte, 2000. "Direct oxidation of hydrocarbons in a solid-oxide fuel cell," Nature, Nature, vol. 404(6775), pages 265-267, March.
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    Cited by:

    1. Shah, M.A.K. Yousaf & Lu, Yuzheng & Mushtaq, Naveed & Yousaf, Muhammad & Akbar, Nabeela & Xia, Chen & Yun, Sining & Zhu, Bin, 2023. "Semiconductor-membrane fuel cell (SMFC) for renewable energy technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 185(C).

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