IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-51123-0.html
   My bibliography  Save this article

Maximizing interface stability in all-solid-state lithium batteries through entropy stabilization and fast kinetics

Author

Listed:
  • Xiangkun Kong

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Run Gu

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Zongzi Jin

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Lei Zhang

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Chi Zhang

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Wenyi Xiang

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Cui Li

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Kang Zhu

    (University of Science and Technology of China)

  • Yifan Xu

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Huang Huang

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Xiaoye Liu

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Ranran Peng

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Chengwei Wang

    (University of Science and Technology of China
    University of Science and Technology of China)

Abstract

The positive electrode|electrolyte interface plays an important role in all-solid-state Li batteries (ASSLBs) based on garnet-type solid-state electrolytes (SSEs) like Li6.4La3Zr1.4Ta0.6O12 (LLZTO). However, the trade-off between solid-solid contact and chemical stability leads to a poor positive electrode|electrolyte interface and cycle performance. In this study, we achieve thermodynamic compatibility and adequate physical contact between high-entropy cationic disordered rock salt positive electrodes (HE-DRXs) and LLZTO through ultrafast high-temperature sintering (UHS). This approach constructs a highly stable positive electrode|electrolyte interface, reducing the interface resistance to 31.6 Ω·cm2 at 25 °C, making a 700 times reduction compared to the LiCoO2 | LLZTO interface. Moreover, the conformal and tight HE-DRX | LLZTO solid-state interface avoids the transition metal migration issue observed with HE-DRX in liquid electrolytes. At 150 °C, HE-DRXs in ASSLBs (Li|LLZTO | HE-DRXs) exhibit an average specific capacity of 239.7 ± 2 mAh/g at 25 mA/g, with a capacity retention of 95% after 100 cycles relative to the initial cycle—a stark contrast to the 76% retention after 20 cycles at 25 °C in conventional liquid batteries. Our strategy, which considers the principles of thermodynamics and kinetics, may open avenues for tackling the positive electrode|electrolyte interface issue in ASSLBs based on garnet-type SSEs.

Suggested Citation

  • Xiangkun Kong & Run Gu & Zongzi Jin & Lei Zhang & Chi Zhang & Wenyi Xiang & Cui Li & Kang Zhu & Yifan Xu & Huang Huang & Xiaoye Liu & Ranran Peng & Chengwei Wang, 2024. "Maximizing interface stability in all-solid-state lithium batteries through entropy stabilization and fast kinetics," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51123-0
    DOI: 10.1038/s41467-024-51123-0
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-51123-0
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-51123-0?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Jianping Huang & Peichen Zhong & Yang Ha & Deok-Hwang Kwon & Matthew J. Crafton & Yaosen Tian & Mahalingam Balasubramanian & Bryan D. McCloskey & Wanli Yang & Gerbrand Ceder, 2021. "Non-topotactic reactions enable high rate capability in Li-rich cathode materials," Nature Energy, Nature, vol. 6(7), pages 706-714, July.
    2. Yang Jin & Kai Liu & Jialiang Lang & Denys Zhuo & Zeya Huang & Chang-an Wang & Hui Wu & Yi Cui, 2018. "An intermediate temperature garnet-type solid electrolyte-based molten lithium battery for grid energy storage," Nature Energy, Nature, vol. 3(9), pages 732-738, September.
    3. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    4. Jürgen Janek & Wolfgang G. Zeier, 2016. "A solid future for battery development," Nature Energy, Nature, vol. 1(9), pages 1-4, September.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Yubao & Huang, Xiaozhou & Huang, Zhendong, 2024. "Energy-related uncertainty and Chinese stock market returns," Finance Research Letters, Elsevier, vol. 62(PB).
    2. Chen, Xuejun & Yang, Yongming & Cui, Zhixin & Shen, Jun, 2019. "Vibration fault diagnosis of wind turbines based on variational mode decomposition and energy entropy," Energy, Elsevier, vol. 174(C), pages 1100-1109.
    3. Muhammad Habib Ur Rehman & Luigi Coppola & Ernestino Lufrano & Isabella Nicotera & Cataldo Simari, 2023. "Enhancing Water Retention, Transport, and Conductivity Performance in Fuel Cell Applications: Nafion-Based Nanocomposite Membranes with Organomodified Graphene Oxide Nanoplatelets," Energies, MDPI, vol. 16(23), pages 1-11, November.
    4. Pin Li & Jinsuo Zhang, 2019. "Is China’s Energy Supply Sustainable? New Research Model Based on the Exponential Smoothing and GM(1,1) Methods," Energies, MDPI, vol. 12(2), pages 1-30, January.
    5. Mao, Guozhu & Zou, Hongyang & Chen, Guanyi & Du, Huibin & Zuo, Jian, 2015. "Past, current and future of biomass energy research: A bibliometric analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1823-1833.
    6. Luo, Rongrong & Wang, Liuwei & Yu, Wei & Shao, Feilong & Shen, Haikuo & Xie, Huaqing, 2023. "High energy storage density titanium nitride-pentaerythritol solid–solid composite phase change materials for light-thermal-electric conversion," Applied Energy, Elsevier, vol. 331(C).
    7. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    8. Géremi Gilson Dranka & Paula Ferreira, 2020. "Electric Vehicles and Biofuels Synergies in the Brazilian Energy System," Energies, MDPI, vol. 13(17), pages 1-22, August.
    9. Yang, Jingluan & Chen, Wei, 2023. "Unravelling the landscape of global cobalt trade: Patterns, robustness, and supply chain security," Resources Policy, Elsevier, vol. 86(PB).
    10. Lili Zhang & Ning Zhang & Huishan Shang & Zhiyi Sun & Zihao Wei & Jingtao Wang & Yuanting Lei & Xiaochen Wang & Dan Wang & Yafei Zhao & Zhongti Sun & Fang Zhang & Xu Xiang & Bing Zhang & Wenxing Chen, 2024. "High-density asymmetric iron dual-atom sites for efficient and stable electrochemical water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    11. Sebastian Scheld, Walter & Charlotte Hoff, Linda & Vedder, Christian & Stollenwerk, Jochen & Grüner, Daniel & Rosen, Melanie & Lobe, Sandra & Ihrig, Martin & Seok, Ah–Ram & Finsterbusch, Martin & Uhle, 2023. "Enabling metal substrates for garnet-based composite cathodes by laser sintering," Applied Energy, Elsevier, vol. 345(C).
    12. Neves, Renato Cruz & Klein, Bruno Colling & da Silva, Ricardo Justino & Rezende, Mylene Cristina Alves Ferreira & Funke, Axel & Olivarez-Gómez, Edgardo & Bonomi, Antonio & Maciel-Filho, Rubens, 2020. "A vision on biomass-to-liquids (BTL) thermochemical routes in integrated sugarcane biorefineries for biojet fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    13. Li, Jinpeng & Chen, Xiangjie & Li, Guiqiang, 2023. "Effect of separation wavelength on a novel solar-driven hybrid hydrogen production system (SDHPS) by solar full spectrum energy," Renewable Energy, Elsevier, vol. 215(C).
    14. Sicong Wang & Changhai Qin & Yong Zhao & Jing Zhao & Yuping Han, 2023. "The Evolutionary Path of the Center of Gravity for Water Use, the Population, and the Economy, and Their Decomposed Contributions in China from 1965 to 2019," Sustainability, MDPI, vol. 15(12), pages 1-20, June.
    15. Cheng, Qian & Liu, Pan & Xia, Qian & Cheng, Lei & Ming, Bo & Zhang, Wei & Xu, Weifeng & Zheng, Yalian & Han, Dongyang & Xia, Jun, 2023. "An analytical method to evaluate curtailment of hydro–photovoltaic hybrid energy systems and its implication under climate change," Energy, Elsevier, vol. 278(C).
    16. Feng Zhou & Chunhui Wen, 2023. "Research on the Level of Agricultural Green Development, Regional Disparities, and Dynamic Distribution Evolution in China from the Perspective of Sustainable Development," Agriculture, MDPI, vol. 13(7), pages 1-47, July.
    17. Zhang, Kaiqiang & Jia, Na & Liu, Lirong, 2019. "CO2 storage in fractured nanopores underground: Phase behaviour study," Applied Energy, Elsevier, vol. 238(C), pages 911-928.
    18. Chen, Xinhui & Wei, Jianfeng & Sheng, Songwei & Wang, Wensheng & Wang, Kunlin & Zhang, Yaqun & Wang, Zhenpeng, 2023. "Design and experimental study of a novel type water-filled submerged flexible bag wave energy converter," Renewable Energy, Elsevier, vol. 218(C).
    19. Cai, Hua & Hu, Xiaojun & Xu, Ming, 2013. "Impact of emerging clean vehicle system on water stress," Applied Energy, Elsevier, vol. 111(C), pages 644-651.
    20. Griffin, Paul A. & Jaffe, Amy Myers & Lont, David H. & Dominguez-Faus, Rosa, 2015. "Science and the stock market: Investors' recognition of unburnable carbon," Energy Economics, Elsevier, vol. 52(PA), pages 1-12.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51123-0. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.