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Galvanic hydrogenation reaction in metal oxide

Author

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  • JunHwa Kwon

    (Gwangju Institute of Science Technology (GIST)
    Korea Institute of Science and Technology (KIST))

  • Soonsung So

    (Gwangju Institute of Science Technology (GIST))

  • Ki-Yeop Cho

    (Gwangju Institute of Science Technology (GIST))

  • Seungmin Lee

    (Gwangju Institute of Science Technology (GIST))

  • Kiyeon Sim

    (Gwangju Institute of Science Technology (GIST))

  • Subin Kim

    (Gwangju Institute of Science Technology (GIST))

  • Seunghyun Jo

    (Gwangju Institute of Science Technology (GIST))

  • Byeol Kang

    (Gwangju Institute of Science Technology (GIST))

  • Youn-Ki Lee

    (Gwangju Institute of Science Technology (GIST))

  • Hee-Young Park

    (Korea Institute of Science and Technology (KIST))

  • Jung Tae Lee

    (Kyung Hee University)

  • Joo-Hyoung Lee

    (Gwangju Institute of Science Technology (GIST))

  • KwangSup Eom

    (Gwangju Institute of Science Technology (GIST)
    Georgia Institute of Technology)

  • Thomas F. Fuller

    (Georgia Institute of Technology)

Abstract

Rational reforming of metal oxide has a potential importance to modulate their inherent properties toward appealing characteristics for various applications. Here, we present a detailed fundamental study of the proton migration phenomena between mediums and propose the methodology for controllable metal oxide hydrogenation through galvanic reactions with metallic cation under ambient atmosphere. As a proof of concept for hydrogenation, we study the role of proton adoption on the structural properties of molybdenum trioxide, as a representative, and its impact on redox characteristics in Li-ion battery (LiB) systems using electrochemical experiments and first-principles calculation. The proton adoption contributes to a lattice rearrangement facilitating the faster Li-ion diffusion along the selected layered and mediates the diffusion pathway that promote the enhancements of high-rate performance and cyclic stability. Our work provides physicochemical insights of hydrogenations and underscores the viable approach for improving the redox characteristics of layered oxide materials.

Suggested Citation

  • JunHwa Kwon & Soonsung So & Ki-Yeop Cho & Seungmin Lee & Kiyeon Sim & Subin Kim & Seunghyun Jo & Byeol Kang & Youn-Ki Lee & Hee-Young Park & Jung Tae Lee & Joo-Hyoung Lee & KwangSup Eom & Thomas F. Fu, 2024. "Galvanic hydrogenation reaction in metal oxide," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-54999-0
    DOI: 10.1038/s41467-024-54999-0
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    References listed on IDEAS

    as
    1. Nianpeng Lu & Zhuo Zhang & Yujia Wang & Hao-Bo Li & Shuang Qiao & Bo Zhao & Qing He & Sicheng Lu & Cong Li & Yongshun Wu & Mingtong Zhu & Xiangyu Lyu & Xiaokun Chen & Zhuolu Li & Meng Wang & Jingzhao , 2022. "Enhanced low-temperature proton conductivity in hydrogen-intercalated brownmillerite oxide," Nature Energy, Nature, vol. 7(12), pages 1208-1216, December.
    2. You Zhou & Xiaofei Guan & Hua Zhou & Koushik Ramadoss & Suhare Adam & Huajun Liu & Sungsik Lee & Jian Shi & Masaru Tsuchiya & Dillon D. Fong & Shriram Ramanathan, 2016. "Strongly correlated perovskite fuel cells," Nature, Nature, vol. 534(7606), pages 231-234, June.
    3. Minghao Yu & Hui Shao & Gang Wang & Fan Yang & Chaolun Liang & Patrick Rozier & Cai-Zhuang Wang & Xihong Lu & Patrice Simon & Xinliang Feng, 2020. "Interlayer gap widened α-phase molybdenum trioxide as high-rate anodes for dual-ion-intercalation energy storage devices," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    4. Tiezhu Xu & Zhenming Xu & Tengyu Yao & Miaoran Zhang & Duo Chen & Xiaogang Zhang & Laifa Shen, 2023. "Discovery of fast and stable proton storage in bulk hexagonal molybdenum oxide," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    5. Yuliang Chen & Zhaowu Wang & Shi Chen & Hui Ren & Liangxin Wang & Guobin Zhang & Yalin Lu & Jun Jiang & Chongwen Zou & Yi Luo, 2018. "Non-catalytic hydrogenation of VO2 in acid solution," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
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