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A stable room-temperature sodium–sulfur battery

Author

Listed:
  • Shuya Wei

    (School of Chemical and Biomolecular Engineering, Cornell University)

  • Shaomao Xu

    (School of Chemical and Biomolecular Engineering, Cornell University)

  • Akanksha Agrawral

    (School of Chemical and Biomolecular Engineering, Cornell University)

  • Snehashis Choudhury

    (School of Chemical and Biomolecular Engineering, Cornell University)

  • Yingying Lu

    (College of Chemical and Biological Engineering, Zhejiang University)

  • Zhengyuan Tu

    (Cornell University)

  • Lin Ma

    (Cornell University)

  • Lynden A. Archer

    (School of Chemical and Biomolecular Engineering, Cornell University)

Abstract

High-energy rechargeable batteries based on earth-abundant materials are important for mobile and stationary storage technologies. Rechargeable sodium–sulfur batteries able to operate stably at room temperature are among the most sought-after platforms because such cells take advantage of a two-electron-redox process to achieve high storage capacity from inexpensive electrode materials. Here we report a room-temperature sodium–sulfur battery that uses a microporous carbon–sulfur composite cathode, and a liquid carbonate electrolyte containing the ionic liquid 1-methyl-3-propylimidazolium-chlorate tethered to SiO2 nanoparticles. We show that these cells can cycle stably at a rate of 0.5 C (1 C=1675, mAh g−1) with 600 mAh g−1 reversible capacity and nearly 100% Coulombic efficiency. By means of spectroscopic and electrochemical analysis, we find that the particles form a sodium-ion conductive film on the anode, which stabilizes deposition of sodium. We also find that sulfur remains interred in the carbon pores and undergo solid-state electrochemical reactions with sodium ions.

Suggested Citation

  • Shuya Wei & Shaomao Xu & Akanksha Agrawral & Snehashis Choudhury & Yingying Lu & Zhengyuan Tu & Lin Ma & Lynden A. Archer, 2016. "A stable room-temperature sodium–sulfur battery," Nature Communications, Nature, vol. 7(1), pages 1-10, September.
    • Handle: RePEc:nat:natcom:v:7:y:2016:i:1:d:10.1038_ncomms11722
    DOI: 10.1038/ncomms11722
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    Cited by:

    1. Yuruo Qi & Qing-Jie Li & Yuanke Wu & Shu-juan Bao & Changming Li & Yuming Chen & Guoxiu Wang & Maowen Xu, 2021. "A Fe3N/carbon composite electrocatalyst for effective polysulfides regulation in room-temperature Na-S batteries," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    2. Wanqing Song & Xinyi Yang & Tao Zhang & Zechuan Huang & Haozhi Wang & Jie Sun & Yunhua Xu & Jia Ding & Wenbin Hu, 2024. "Optimizing potassium polysulfides for high performance potassium-sulfur batteries," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    3. Tang, Kejian & Peng, Xiangqi & Chen, Shuijiao & Song, Fei & Liu, Zhichao & Hu, Jian & Xie, Xiuqiang & Wu, Zhenjun, 2022. "Hierarchically porous carbon derived from delignified biomass for high sulfur-loading room-temperature sodium-sulfur batteries," Renewable Energy, Elsevier, vol. 201(P1), pages 832-840.
    4. Liu, Ying & Lee, Dong Jun & Ahn, Hyo-Jun & Nam, Sang Yong & Cho, Kwon-Koo & Ahn, Jou-Hyeon, 2023. "Waste coffee grounds-derived carbon: Nanoarchitectured pore-structure regulation for sustainable room-temperature sodium–sulfur batteries," Renewable Energy, Elsevier, vol. 212(C), pages 865-874.
    5. Chao Ye & Huan Li & Yujie Chen & Junnan Hao & Jiahao Liu & Jieqiong Shan & Shi-Zhang Qiao, 2024. "The role of electrocatalytic materials for developing post-lithium metal||sulfur batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    6. Shuo Wang & Jiamin Fu & Yunsheng Liu & Ramanuja Srinivasan Saravanan & Jing Luo & Sixu Deng & Tsun-Kong Sham & Xueliang Sun & Yifei Mo, 2023. "Design principles for sodium superionic conductors," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    7. Yao-Jie Lei & Xinxin Lu & Hirofumi Yoshikawa & Daiju Matsumura & Yameng Fan & Lingfei Zhao & Jiayang Li & Shijian Wang & Qinfen Gu & Hua-Kun Liu & Shi-Xue Dou & Shanmukaraj Devaraj & Teofilo Rojo & We, 2024. "Understanding the charge transfer effects of single atoms for boosting the performance of Na-S batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    8. Chao Ye & Huanyu Jin & Jieqiong Shan & Yan Jiao & Huan Li & Qinfen Gu & Kenneth Davey & Haihui Wang & Shi-Zhang Qiao, 2021. "A Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries," Nature Communications, Nature, vol. 12(1), pages 1-11, December.

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