IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v345y2023ics0306261923006992.html
   My bibliography  Save this article

Enabling metal substrates for garnet-based composite cathodes by laser sintering

Author

Listed:
  • Sebastian Scheld, Walter
  • Charlotte Hoff, Linda
  • Vedder, Christian
  • Stollenwerk, Jochen
  • Grüner, Daniel
  • Rosen, Melanie
  • Lobe, Sandra
  • Ihrig, Martin
  • Seok, Ah–Ram
  • Finsterbusch, Martin
  • Uhlenbruck, Sven
  • Guillon, Olivier
  • Fattakhova–Rohlfing, Dina

Abstract

In this study, a laser irradiation method developed by Fraunhofer ILT was used to sinter screen-printed cathode layers of LiCoO2 (LCO) and Li7La3Zr2O12 (LLZO) directly on a stainless steel current collector. The laser sintering method was proved to be a promising method to sinter the composite cathode onto steel with greatly reduced side reactions and material degradation. In comparison, conventional sintering and another light-absorption-based sintering method, namely rapid thermal processing (RTP) in a lamp furnace, led to almost complete decomposition of the LLZO phase accompanying with the detrimental formation of LaCoO3 and CoO. Phase and morphology analysis of the laser-sintered cathodes using Raman spectroscopy, X-ray diffraction, and scanning electron microscopy confirmed sintering of LCO and LLZO through the layer with small amounts of secondary phases (LaCoO3, Li0.5La2Co0.5O4 and CoO). The resulting porous matrix of the laser-sintered cathode was infiltrated with a polyethylene oxide (PEO) electrolyte to connect the cathode to an LLZO separator and a Li metal anode without an additional sintering step. This model cell was used to evaluate the electrochemical activity of the laser-sintered composite cathodes, which exhibited a specific discharge capacity of 102 mAh g−1 at 4.0 V in the first electrochemical cycle.

Suggested Citation

  • Sebastian Scheld, Walter & Charlotte Hoff, Linda & Vedder, Christian & Stollenwerk, Jochen & Grüner, Daniel & Rosen, Melanie & Lobe, Sandra & Ihrig, Martin & Seok, Ah–Ram & Finsterbusch, Martin & Uhle, 2023. "Enabling metal substrates for garnet-based composite cathodes by laser sintering," Applied Energy, Elsevier, vol. 345(C).
    • Handle: RePEc:eee:appene:v:345:y:2023:i:c:s0306261923006992
    DOI: 10.1016/j.apenergy.2023.121335
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261923006992
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2023.121335?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Jürgen Janek & Wolfgang G. Zeier, 2016. "A solid future for battery development," Nature Energy, Nature, vol. 1(9), pages 1-4, September.
    2. Jiung Cho & Mark D. Losego & Hui Gang Zhang & Honggyu Kim & Jianmin Zuo & Ivan Petrov & David G. Cahill & Paul V. Braun, 2014. "Electrochemically tunable thermal conductivity of lithium cobalt oxide," Nature Communications, Nature, vol. 5(1), pages 1-6, September.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hyeokjin Kwon & Hyun-Ji Choi & Jung-kyu Jang & Jinhong Lee & Jinkwan Jung & Wonjun Lee & Youngil Roh & Jaewon Baek & Dong Jae Shin & Ju-Hyuk Lee & Nam-Soon Choi & Ying Shirley Meng & Hee-Tak Kim, 2023. "Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Sewon Kim & Ju-Sik Kim & Lincoln Miara & Yan Wang & Sung-Kyun Jung & Seong Yong Park & Zhen Song & Hyungsub Kim & Michael Badding & JaeMyung Chang & Victor Roev & Gabin Yoon & Ryounghee Kim & Jung-Hwa, 2022. "High-energy and durable lithium metal batteries using garnet-type solid electrolytes with tailored lithium-metal compatibility," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Jessica Kersey & Natalie D. Popovich & Amol A. Phadke, 2022. "Rapid battery cost declines accelerate the prospects of all-electric interregional container shipping," Nature Energy, Nature, vol. 7(7), pages 664-674, July.
    4. Shuo Wang & Jiamin Fu & Yunsheng Liu & Ramanuja Srinivasan Saravanan & Jing Luo & Sixu Deng & Tsun-Kong Sham & Xueliang Sun & Yifei Mo, 2023. "Design principles for sodium superionic conductors," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    5. Abdulrahman S. Binfaris & Alexander G. Zestos & Jandro L. Abot, 2023. "Development of Carbon Nanotube Yarn Supercapacitors and Energy Storage for Integrated Structural Health Monitoring," Energies, MDPI, vol. 16(15), pages 1-14, August.
    6. Bornmann, Lutz & Haunschild, Robin, 2022. "Empirical analysis of recent temporal dynamics of research fields: Annual publications in chemistry and related areas as an example," Journal of Informetrics, Elsevier, vol. 16(2).
    7. Nian Zhang & Guoxi Ren & Lili Li & Zhi Wang & Pengfei Yu & Xiaobao Li & Jing Zhou & Hui Zhang & Linjuan Zhang & Zhi Liu & Xiaosong Liu, 2024. "Dynamical evolution of CO2 and H2O on garnet electrolyte elucidated by ambient pressure X-ray spectroscopies," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    8. Lv Hu & Jinzhu Wang & Kai Wang & Zhenqi Gu & Zhiwei Xi & Hui Li & Fang Chen & Youxi Wang & Zhenyu Li & Cheng Ma, 2023. "A cost-effective, ionically conductive and compressible oxychloride solid-state electrolyte for stable all-solid-state lithium-based batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    9. Yingying Zhang & William M. Postiglione & Rui Xie & Chi Zhang & Hao Zhou & Vipul Chaturvedi & Kei Heltemes & Hua Zhou & Tianli Feng & Chris Leighton & Xiaojia Wang, 2023. "Wide-range continuous tuning of the thermal conductivity of La0.5Sr0.5CoO3-δ films via room-temperature ion-gel gating," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    10. Chao Zhu & Till Fuchs & Stefan A. L. Weber & Felix. H. Richter & Gunnar Glasser & Franjo Weber & Hans-Jürgen Butt & Jürgen Janek & Rüdiger Berger, 2023. "Understanding the evolution of lithium dendrites at Li6.25Al0.25La3Zr2O12 grain boundaries via operando microscopy techniques," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    11. Coester, Andreas & Hofkes, Marjan W. & Papyrakis, Elissaios, 2020. "Economic analysis of batteries: Impact on security of electricity supply and renewable energy expansion in Germany," Applied Energy, Elsevier, vol. 275(C).
    12. Xinxin Wang & Jingjing Chen & Dajian Wang & Zhiyong Mao, 2021. "Improving the alkali metal electrode/inorganic solid electrolyte contact via room-temperature ultrasound solid welding," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    13. Ruiz, V. & Pfrang, A. & Kriston, A. & Omar, N. & Van den Bossche, P. & Boon-Brett, L., 2018. "A review of international abuse testing standards and regulations for lithium ion batteries in electric and hybrid electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1427-1452.
    14. Camilo A. Mesa & Michael Sachs & Ernest Pastor & Nicolas Gauriot & Alice J. Merryweather & Miguel A. Gomez-Gonzalez & Konstantin Ignatyev & Sixto Giménez & Akshay Rao & James R. Durrant & Raj Pandya, 2024. "Correlating activities and defects in (photo)electrocatalysts using in-situ multi-modal microscopic imaging," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    15. Ziyu Song & Fangfang Chen & Maria Martinez-Ibañez & Wenfang Feng & Maria Forsyth & Zhibin Zhou & Michel Armand & Heng Zhang, 2023. "A reflection on polymer electrolytes for solid-state lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    16. Ziteng Liang & Yuxuan Xiang & Kangjun Wang & Jianping Zhu & Yanting Jin & Hongchun Wang & Bizhu Zheng & Zirong Chen & Mingming Tao & Xiangsi Liu & Yuqi Wu & Riqiang Fu & Chunsheng Wang & Martin Winter, 2023. "Understanding the failure process of sulfide-based all-solid-state lithium batteries via operando nuclear magnetic resonance spectroscopy," Nature Communications, Nature, vol. 14(1), pages 1-15, December.
    17. Zhenyou Song & Tengrui Wang & Hua Yang & Wang Hay Kan & Yuwei Chen & Qian Yu & Likuo Wang & Yini Zhang & Yiming Dai & Huaican Chen & Wen Yin & Takashi Honda & Maxim Avdeev & Henghui Xu & Jiwei Ma & Yu, 2024. "Promoting high-voltage stability through local lattice distortion of halide solid electrolytes," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    18. Xiangkun Kong & Run Gu & Zongzi Jin & Lei Zhang & Chi Zhang & Wenyi Xiang & Cui Li & Kang Zhu & Yifan Xu & Huang Huang & Xiaoye Liu & Ranran Peng & Chengwei Wang, 2024. "Maximizing interface stability in all-solid-state lithium batteries through entropy stabilization and fast kinetics," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    19. Mergo Mbeya, Karrick & Damay, Nicolas & Friedrich, Guy & Forgez, Christophe & Juston, Maxime, 2021. "Off-line method to determine the electrode balancing of Li-ion batteries," Mathematics and Computers in Simulation (MATCOM), Elsevier, vol. 183(C), pages 34-47.
    20. Tong-Tong Zuo & Raffael Rueß & Ruijun Pan & Felix Walther & Marcus Rohnke & Satoshi Hori & Ryoji Kanno & Daniel Schröder & Jürgen Janek, 2021. "A mechanistic investigation of the Li10GeP2S12|LiNi1-x-yCoxMnyO2 interface stability in all-solid-state lithium batteries," Nature Communications, Nature, vol. 12(1), pages 1-10, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:345:y:2023:i:c:s0306261923006992. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.