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Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries

Author

Listed:
  • Chang Li

    (University of Waterloo
    Argonne National Laboratory)

  • Ryan Kingsbury

    (Lawrence Berkeley National Laboratory)

  • Arashdeep Singh Thind

    (Argonne National Laboratory
    University of Illinois - Chicago)

  • Abhinandan Shyamsunder

    (University of Waterloo
    Argonne National Laboratory)

  • Timothy T. Fister

    (Argonne National Laboratory
    Argonne National Laboratory)

  • Robert F. Klie

    (Argonne National Laboratory
    University of Illinois - Chicago)

  • Kristin A. Persson

    (Argonne National Laboratory
    Lawrence Berkeley National Laboratory
    Department of Materials Science and Engineering, UC Berkeley)

  • Linda F. Nazar

    (University of Waterloo
    Argonne National Laboratory)

Abstract

Two major challenges hinder the advance of aqueous zinc metal batteries for sustainable stationary storage: (1) achieving predominant Zn-ion (de)intercalation at the oxide cathode by suppressing adventitious proton co-intercalation and dissolution, and (2) simultaneously overcoming Zn dendrite growth at the anode that triggers parasitic electrolyte reactions. Here, we reveal the competition between Zn2+ vs proton intercalation chemistry of a typical oxide cathode using ex-situ/operando techniques, and alleviate side reactions by developing a cost-effective and non-flammable hybrid eutectic electrolyte. A fully hydrated Zn2+ solvation structure facilitates fast charge transfer at the solid/electrolyte interface, enabling dendrite-free Zn plating/stripping with a remarkably high average coulombic efficiency of 99.8% at commercially relevant areal capacities of 4 mAh cm−2 and function up to 1600 h at 8 mAh cm−2. By concurrently stabilizing Zn redox at both electrodes, we achieve a new benchmark in Zn-ion battery performance of 4 mAh cm−2 anode-free cells that retain 85% capacity over 100 cycles at 25 °C. Using this eutectic-design electrolyte, Zn | |Iodine full cells are further realized with 86% capacity retention over 2500 cycles. The approach represents a new avenue for long-duration energy storage.

Suggested Citation

  • Chang Li & Ryan Kingsbury & Arashdeep Singh Thind & Abhinandan Shyamsunder & Timothy T. Fister & Robert F. Klie & Kristin A. Persson & Linda F. Nazar, 2023. "Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38460-2
    DOI: 10.1038/s41467-023-38460-2
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    References listed on IDEAS

    as
    1. Lin Ma & Marshall A. Schroeder & Oleg Borodin & Travis P. Pollard & Michael S. Ding & Chunsheng Wang & Kang Xu, 2020. "Realizing high zinc reversibility in rechargeable batteries," Nature Energy, Nature, vol. 5(10), pages 743-749, October.
    2. Dipan Kundu & Brian D. Adams & Victor Duffort & Shahrzad Hosseini Vajargah & Linda F. Nazar, 2016. "A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode," Nature Energy, Nature, vol. 1(10), pages 1-8, October.
    3. Yifei Yuan & Ryan Sharpe & Kun He & Chenghang Li & Mahmoud Tamadoni Saray & Tongchao Liu & Wentao Yao & Meng Cheng & Huile Jin & Shun Wang & Khalil Amine & Reza Shahbazian-Yassar & M. Saiful Islam & J, 2022. "Understanding intercalation chemistry for sustainable aqueous zinc–manganese dioxide batteries," Nature Sustainability, Nature, vol. 5(10), pages 890-898, October.
    4. Ning Zhang & Fangyi Cheng & Junxiang Liu & Liubin Wang & Xinghui Long & Xiaosong Liu & Fujun Li & Jun Chen, 2017. "Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    5. Huilin Pan & Yuyan Shao & Pengfei Yan & Yingwen Cheng & Kee Sung Han & Zimin Nie & Chongmin Wang & Jihui Yang & Xiaolin Li & Priyanka Bhattacharya & Karl T. Mueller & Jun Liu, 2016. "Reversible aqueous zinc/manganese oxide energy storage from conversion reactions," Nature Energy, Nature, vol. 1(5), pages 1-7, May.
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    1. Quanquan Guo & Wei Li & Xiaodong Li & Jiaxu Zhang & Davood Sabaghi & Jianjun Zhang & Bowen Zhang & Dongqi Li & Jingwei Du & Xingyuan Chu & Sein Chung & Kilwon Cho & Nguyen Ngan Nguyen & Zhongquan Liao, 2024. "Proton-selective coating enables fast-kinetics high-mass-loading cathodes for sustainable zinc batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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