IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-38460-2.html
   My bibliography  Save this article

Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries

Author

Listed:
  • Chang Li

    (University of Waterloo
    Argonne National Laboratory)

  • Ryan Kingsbury

    (Lawrence Berkeley National Laboratory)

  • Arashdeep Singh Thind

    (Argonne National Laboratory
    University of Illinois - Chicago)

  • Abhinandan Shyamsunder

    (University of Waterloo
    Argonne National Laboratory)

  • Timothy T. Fister

    (Argonne National Laboratory
    Argonne National Laboratory)

  • Robert F. Klie

    (Argonne National Laboratory
    University of Illinois - Chicago)

  • Kristin A. Persson

    (Argonne National Laboratory
    Lawrence Berkeley National Laboratory
    Department of Materials Science and Engineering, UC Berkeley)

  • Linda F. Nazar

    (University of Waterloo
    Argonne National Laboratory)

Abstract

Two major challenges hinder the advance of aqueous zinc metal batteries for sustainable stationary storage: (1) achieving predominant Zn-ion (de)intercalation at the oxide cathode by suppressing adventitious proton co-intercalation and dissolution, and (2) simultaneously overcoming Zn dendrite growth at the anode that triggers parasitic electrolyte reactions. Here, we reveal the competition between Zn2+ vs proton intercalation chemistry of a typical oxide cathode using ex-situ/operando techniques, and alleviate side reactions by developing a cost-effective and non-flammable hybrid eutectic electrolyte. A fully hydrated Zn2+ solvation structure facilitates fast charge transfer at the solid/electrolyte interface, enabling dendrite-free Zn plating/stripping with a remarkably high average coulombic efficiency of 99.8% at commercially relevant areal capacities of 4 mAh cm−2 and function up to 1600 h at 8 mAh cm−2. By concurrently stabilizing Zn redox at both electrodes, we achieve a new benchmark in Zn-ion battery performance of 4 mAh cm−2 anode-free cells that retain 85% capacity over 100 cycles at 25 °C. Using this eutectic-design electrolyte, Zn | |Iodine full cells are further realized with 86% capacity retention over 2500 cycles. The approach represents a new avenue for long-duration energy storage.

Suggested Citation

  • Chang Li & Ryan Kingsbury & Arashdeep Singh Thind & Abhinandan Shyamsunder & Timothy T. Fister & Robert F. Klie & Kristin A. Persson & Linda F. Nazar, 2023. "Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38460-2
    DOI: 10.1038/s41467-023-38460-2
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-38460-2
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-023-38460-2?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Lin Ma & Marshall A. Schroeder & Oleg Borodin & Travis P. Pollard & Michael S. Ding & Chunsheng Wang & Kang Xu, 2020. "Realizing high zinc reversibility in rechargeable batteries," Nature Energy, Nature, vol. 5(10), pages 743-749, October.
    2. Dipan Kundu & Brian D. Adams & Victor Duffort & Shahrzad Hosseini Vajargah & Linda F. Nazar, 2016. "A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode," Nature Energy, Nature, vol. 1(10), pages 1-8, October.
    3. Yifei Yuan & Ryan Sharpe & Kun He & Chenghang Li & Mahmoud Tamadoni Saray & Tongchao Liu & Wentao Yao & Meng Cheng & Huile Jin & Shun Wang & Khalil Amine & Reza Shahbazian-Yassar & M. Saiful Islam & J, 2022. "Understanding intercalation chemistry for sustainable aqueous zinc–manganese dioxide batteries," Nature Sustainability, Nature, vol. 5(10), pages 890-898, October.
    4. Huilin Pan & Yuyan Shao & Pengfei Yan & Yingwen Cheng & Kee Sung Han & Zimin Nie & Chongmin Wang & Jihui Yang & Xiaolin Li & Priyanka Bhattacharya & Karl T. Mueller & Jun Liu, 2016. "Reversible aqueous zinc/manganese oxide energy storage from conversion reactions," Nature Energy, Nature, vol. 1(5), pages 1-7, May.
    5. Ning Zhang & Fangyi Cheng & Junxiang Liu & Liubin Wang & Xinghui Long & Xiaosong Liu & Fujun Li & Jun Chen, 2017. "Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Quanquan Guo & Wei Li & Xiaodong Li & Jiaxu Zhang & Davood Sabaghi & Jianjun Zhang & Bowen Zhang & Dongqi Li & Jingwei Du & Xingyuan Chu & Sein Chung & Kilwon Cho & Nguyen Ngan Nguyen & Zhongquan Liao, 2024. "Proton-selective coating enables fast-kinetics high-mass-loading cathodes for sustainable zinc batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shengmei Chen & Yiran Ying & Longtao Ma & Daming Zhu & Haitao Huang & Li Song & Chunyi Zhi, 2023. "An asymmetric electrolyte to simultaneously meet contradictory requirements of anode and cathode," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Alessandro Innocenti & Dominic Bresser & Jürgen Garche & Stefano Passerini, 2024. "A critical discussion of the current availability of lithium and zinc for use in batteries," Nature Communications, Nature, vol. 15(1), pages 1-6, December.
    3. Yu Wang & Tairan Wang & Shuyu Bu & Jiaxiong Zhu & Yanbo Wang & Rong Zhang & Hu Hong & Wenjun Zhang & Jun Fan & Chunyi Zhi, 2023. "Sulfolane-containing aqueous electrolyte solutions for producing efficient ampere-hour-level zinc metal battery pouch cells," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    4. Yuwei Zhao & Yue Lu & Huiping Li & Yongbin Zhu & You Meng & Na Li & Donghong Wang & Feng Jiang & Funian Mo & Changbai Long & Ying Guo & Xinliang Li & Zhaodong Huang & Qing Li & Johnny C. Ho & Jun Fan , 2022. "Few-layer bismuth selenide cathode for low-temperature quasi-solid-state aqueous zinc metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    5. Kefu Zhu & Shiqiang Wei & Hongwei Shou & Feiran Shen & Shuangming Chen & Pengjun Zhang & Changda Wang & Yuyang Cao & Xin Guo & Mi Luo & Hongjun Zhang & Bangjiao Ye & Xiaojun Wu & Lunhua He & Li Song, 2021. "Defect engineering on V2O3 cathode for long-cycling aqueous zinc metal batteries," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    6. Quanquan Guo & Wei Li & Xiaodong Li & Jiaxu Zhang & Davood Sabaghi & Jianjun Zhang & Bowen Zhang & Dongqi Li & Jingwei Du & Xingyuan Chu & Sein Chung & Kilwon Cho & Nguyen Ngan Nguyen & Zhongquan Liao, 2024. "Proton-selective coating enables fast-kinetics high-mass-loading cathodes for sustainable zinc batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    7. Zhiyang Zheng & Xiongwei Zhong & Qi Zhang & Mengtian Zhang & Lixin Dai & Xiao Xiao & Jiahe Xu & Miaolun Jiao & Boran Wang & Hong Li & Yeyang Jia & Rui Mao & Guangmin Zhou, 2024. "An extended substrate screening strategy enabling a low lattice mismatch for highly reversible zinc anodes," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    8. Choudhary, Ram Bilash & Ansari, Sarfaraz & Majumder, Mandira, 2021. "Recent advances on redox active composites of metal-organic framework and conducting polymers as pseudocapacitor electrode material," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    9. Qingshun Nian & Xuan Luo & Digen Ruan & Yecheng Li & Bing-Qing Xiong & Zhuangzhuang Cui & Zihong Wang & Qi Dong & Jiajia Fan & Jinyu Jiang & Jun Ma & Zhihao Ma & Dazhuang Wang & Xiaodi Ren, 2024. "Highly reversible zinc metal anode enabled by strong Brønsted acid and hydrophobic interfacial chemistry," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    10. Zhiwei Li & Yinghong Xu & Langyuan Wu & Jiaxin Cui & Hui Dou & Xiaogang Zhang, 2023. "Enabling giant thermopower by heterostructure engineering of hydrated vanadium pentoxide for zinc ion thermal charging cells," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    11. Chen, Binbin & Xuan, Jin & Offer, Gregory James & Wang, Huizhi, 2020. "Multiplex measurement of diffusion in zinc battery electrolytes from microfluidics using Raman microspectroscopy," Applied Energy, Elsevier, vol. 279(C).
    12. Amiri, Ahmad & Swart, Edward Ned & Polycarpou, Andreas A., 2021. "Recent advances in electrochemically-efficient materials for zinc-ion hybrid supercapacitors," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    13. Ruirui Zhao & Haifeng Wang & Haoran Du & Ying Yang & Zhonghui Gao & Long Qie & Yunhui Huang, 2022. "Lanthanum nitrate as aqueous electrolyte additive for favourable zinc metal electrodeposition," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    14. Alanne, Kari & Cao, Sunliang, 2019. "An overview of the concept and technology of ubiquitous energy," Applied Energy, Elsevier, vol. 238(C), pages 284-302.
    15. Shuo Jin & Jiefu Yin & Xiaosi Gao & Arpita Sharma & Pengyu Chen & Shifeng Hong & Qing Zhao & Jingxu Zheng & Yue Deng & Yong Lak Joo & Lynden A. Archer, 2022. "Production of fast-charge Zn-based aqueous batteries via interfacial adsorption of ion-oligomer complexes," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    16. Yunxiang Zhao & Shan Guo & Manjing Chen & Bingan Lu & Xiaotan Zhang & Shuquan Liang & Jiang Zhou, 2023. "Tailoring grain boundary stability of zinc-titanium alloy for long-lasting aqueous zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    17. Xinhua Zheng & Zaichun Liu & Jifei Sun & Ruihao Luo & Kui Xu & Mingyu Si & Ju Kang & Yuan Yuan & Shuang Liu & Touqeer Ahmad & Taoli Jiang & Na Chen & Mingming Wang & Yan Xu & Mingyan Chuai & Zhengxin , 2023. "Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    18. Priya Lakshmanan & Subadevi Rengapillai & Sivakumar Marimuthu & Suryanarayanan Vembu, 2022. "Turning Trash to Treasure: Reusable Glucose Kit as a Cell Using ZnO Derived from Metal Organic Framework (MOF) Electrode for Redox Flow Battery," Energies, MDPI, vol. 15(20), pages 1-15, October.
    19. Qing Li & Ao Chen & Donghong Wang & Yuwei Zhao & Xiaoqi Wang & Xu Jin & Bo Xiong & Chunyi Zhi, 2022. "Tailoring the metal electrode morphology via electrochemical protocol optimization for long-lasting aqueous zinc batteries," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    20. Yangmoon Kim & Youngbin Park & Minkwan Kim & Jimin Lee & Ki Jae Kim & Jang Wook Choi, 2022. "Corrosion as the origin of limited lifetime of vanadium oxide-based aqueous zinc ion batteries," Nature Communications, Nature, vol. 13(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38460-2. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.