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A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode

Author

Listed:
  • Dipan Kundu

    (University of Waterloo)

  • Brian D. Adams

    (University of Waterloo)

  • Victor Duffort

    (University of Waterloo)

  • Shahrzad Hosseini Vajargah

    (University of Waterloo)

  • Linda F. Nazar

    (University of Waterloo)

Abstract

Although non-aqueous Li-ion batteries possess significantly higher energy density than their aqueous counterparts, the latter can be more feasible for grid-scale applications when cost, safety and cycle life are taken into consideration. Moreover, aqueous Zn-ion batteries have an energy storage advantage over alkali-based batteries as they can employ Zn metal as the negative electrode, dramatically increasing energy density. However, their development is plagued by a limited choice of positive electrodes, which often show poor rate capability and inadequate cycle life. Here we report a vanadium oxide bronze pillared by interlayer Zn2+ ions and water (Zn0.25V2O5⋅nH2O), as the positive electrode for a Zn cell. A reversible Zn2+ ion (de)intercalation storage process at fast rates, with more than one Zn2+ per formula unit (a capacity up to 300 mAh g−1), is characterized. The Zn cell offers an energy density of ∼450 Wh l−1 and exhibits a capacity retention of more than 80% over 1,000 cycles, with no dendrite formation at the Zn electrode.

Suggested Citation

  • Dipan Kundu & Brian D. Adams & Victor Duffort & Shahrzad Hosseini Vajargah & Linda F. Nazar, 2016. "A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode," Nature Energy, Nature, vol. 1(10), pages 1-8, October.
    • Handle: RePEc:nat:natene:v:1:y:2016:i:10:d:10.1038_nenergy.2016.119
    DOI: 10.1038/nenergy.2016.119
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    Cited by:

    1. Songshan Bi & Shuai Wang & Fang Yue & Zhiwei Tie & Zhiqiang Niu, 2021. "A rechargeable aqueous manganese-ion battery based on intercalation chemistry," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    2. Chen, Binbin & Xuan, Jin & Offer, Gregory James & Wang, Huizhi, 2020. "Multiplex measurement of diffusion in zinc battery electrolytes from microfluidics using Raman microspectroscopy," Applied Energy, Elsevier, vol. 279(C).
    3. Yangmoon Kim & Youngbin Park & Minkwan Kim & Jimin Lee & Ki Jae Kim & Jang Wook Choi, 2022. "Corrosion as the origin of limited lifetime of vanadium oxide-based aqueous zinc ion batteries," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    4. Feifei Wang & Jipeng Zhang & Haotian Lu & Hanbing Zhu & Zihui Chen & Lu Wang & Jinyang Yu & Conghui You & Wenhao Li & Jianwei Song & Zhe Weng & Chunpeng Yang & Quan-Hong Yang, 2023. "Production of gas-releasing electrolyte-replenishing Ah-scale zinc metal pouch cells with aqueous gel electrolyte," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Shengmei Chen & Yiran Ying & Longtao Ma & Daming Zhu & Haitao Huang & Li Song & Chunyi Zhi, 2023. "An asymmetric electrolyte to simultaneously meet contradictory requirements of anode and cathode," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Kefu Zhu & Shiqiang Wei & Hongwei Shou & Feiran Shen & Shuangming Chen & Pengjun Zhang & Changda Wang & Yuyang Cao & Xin Guo & Mi Luo & Hongjun Zhang & Bangjiao Ye & Xiaojun Wu & Lunhua He & Li Song, 2021. "Defect engineering on V2O3 cathode for long-cycling aqueous zinc metal batteries," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    7. Yu Wang & Tairan Wang & Shuyu Bu & Jiaxiong Zhu & Yanbo Wang & Rong Zhang & Hu Hong & Wenjun Zhang & Jun Fan & Chunyi Zhi, 2023. "Sulfolane-containing aqueous electrolyte solutions for producing efficient ampere-hour-level zinc metal battery pouch cells," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    8. Zhiwei Li & Yinghong Xu & Langyuan Wu & Jiaxin Cui & Hui Dou & Xiaogang Zhang, 2023. "Enabling giant thermopower by heterostructure engineering of hydrated vanadium pentoxide for zinc ion thermal charging cells," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    9. Priya Lakshmanan & Subadevi Rengapillai & Sivakumar Marimuthu & Suryanarayanan Vembu, 2022. "Turning Trash to Treasure: Reusable Glucose Kit as a Cell Using ZnO Derived from Metal Organic Framework (MOF) Electrode for Redox Flow Battery," Energies, MDPI, vol. 15(20), pages 1-15, October.
    10. Chang Li & Ryan Kingsbury & Arashdeep Singh Thind & Abhinandan Shyamsunder & Timothy T. Fister & Robert F. Klie & Kristin A. Persson & Linda F. Nazar, 2023. "Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    11. Song Chen & Deluo Ji & Qianwu Chen & Jizhen Ma & Shaoqi Hou & Jintao Zhang, 2023. "Coordination modulation of hydrated zinc ions to enhance redox reversibility of zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    12. Yuwei Zhao & Yue Lu & Huiping Li & Yongbin Zhu & You Meng & Na Li & Donghong Wang & Feng Jiang & Funian Mo & Changbai Long & Ying Guo & Xinliang Li & Zhaodong Huang & Qing Li & Johnny C. Ho & Jun Fan , 2022. "Few-layer bismuth selenide cathode for low-temperature quasi-solid-state aqueous zinc metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.

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