IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v12y2021i1d10.1038_s41467-021-27203-w.html
   My bibliography  Save this article

Defect engineering on V2O3 cathode for long-cycling aqueous zinc metal batteries

Author

Listed:
  • Kefu Zhu

    (University of Science and Technology of China)

  • Shiqiang Wei

    (University of Science and Technology of China)

  • Hongwei Shou

    (University of Science and Technology of China
    University of Science and Technology of China)

  • Feiran Shen

    (Spallation Neutron Source Science Center)

  • Shuangming Chen

    (University of Science and Technology of China)

  • Pengjun Zhang

    (University of Science and Technology of China)

  • Changda Wang

    (University of Science and Technology of China)

  • Yuyang Cao

    (University of Science and Technology of China)

  • Xin Guo

    (University of Science and Technology of China)

  • Mi Luo

    (University of Science and Technology of China)

  • Hongjun Zhang

    (University of Science and Technology of China)

  • Bangjiao Ye

    (University of Science and Technology of China)

  • Xiaojun Wu

    (University of Science and Technology of China)

  • Lunhua He

    (Spallation Neutron Source Science Center
    Chinese Academy of Sciences
    Songshan Lake Materials Laboratory)

  • Li Song

    (University of Science and Technology of China)

Abstract

Defect engineering is a strategy that is attracting widespread attention for the possibility of modifying battery active materials in order to improve the cycling stability of the electrodes. However, accurate investigation and quantification of the effect of the defects on the electrochemical energy storage performance of the cell are not trivial tasks. Herein, we report the quantification of vanadium-defective clusters (i.e., up to 5.7%) in the V2O3 lattice via neutron and X-ray powder diffraction measurements, positron annihilation lifetime spectroscopy, and synchrotron-based X-ray analysis. When the vanadium-defective V2O3 is employed as cathode active material in an aqueous Zn coin cell configuration, capacity retention of about 81% after 30,000 cycles at 5 A g−1 is achieved. Density functional theory calculations indicate that the vanadium-defective clusters can provide favorable sites for reversible Zn-ion storage. Moreover, the vanadium-defective clusters allow the storage of Zn ions in V2O3, which reduces the electrostatic interaction between the host material and the multivalent ions.

Suggested Citation

  • Kefu Zhu & Shiqiang Wei & Hongwei Shou & Feiran Shen & Shuangming Chen & Pengjun Zhang & Changda Wang & Yuyang Cao & Xin Guo & Mi Luo & Hongjun Zhang & Bangjiao Ye & Xiaojun Wu & Lunhua He & Li Song, 2021. "Defect engineering on V2O3 cathode for long-cycling aqueous zinc metal batteries," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-27203-w
    DOI: 10.1038/s41467-021-27203-w
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-021-27203-w
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-021-27203-w?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Fang Wan & Linlin Zhang & Xi Dai & Xinyu Wang & Zhiqiang Niu & Jun Chen, 2018. "Aqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    2. Dipan Kundu & Brian D. Adams & Victor Duffort & Shahrzad Hosseini Vajargah & Linda F. Nazar, 2016. "A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode," Nature Energy, Nature, vol. 1(10), pages 1-8, October.
    3. Huilin Pan & Yuyan Shao & Pengfei Yan & Yingwen Cheng & Kee Sung Han & Zimin Nie & Chongmin Wang & Jihui Yang & Xiaolin Li & Priyanka Bhattacharya & Karl T. Mueller & Jun Liu, 2016. "Reversible aqueous zinc/manganese oxide energy storage from conversion reactions," Nature Energy, Nature, vol. 1(5), pages 1-7, May.
    4. Hyun Deog Yoo & Yanliang Liang & Hui Dong & Junhao Lin & Hua Wang & Yisheng Liu & Lu Ma & Tianpin Wu & Yifei Li & Qiang Ru & Yan Jing & Qinyou An & Wu Zhou & Jinghua Guo & Jun Lu & Sokrates T. Panteli, 2017. "Fast kinetics of magnesium monochloride cations in interlayer-expanded titanium disulfide for magnesium rechargeable batteries," Nature Communications, Nature, vol. 8(1), pages 1-10, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tiezhu Xu & Zhenming Xu & Tengyu Yao & Miaoran Zhang & Duo Chen & Xiaogang Zhang & Laifa Shen, 2023. "Discovery of fast and stable proton storage in bulk hexagonal molybdenum oxide," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    2. Jiabao Lv & Ang Cao & Yunhao Zhong & Qingyang Lin & Xiaodong Li & Hao Bin Wu & Jianhua Yan & Angjian Wu, 2024. "Promoting the OH cycle on an activated dynamic interface for electrocatalytic ammonia synthesis," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chang Li & Ryan Kingsbury & Arashdeep Singh Thind & Abhinandan Shyamsunder & Timothy T. Fister & Robert F. Klie & Kristin A. Persson & Linda F. Nazar, 2023. "Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    2. Shengmei Chen & Yiran Ying & Longtao Ma & Daming Zhu & Haitao Huang & Li Song & Chunyi Zhi, 2023. "An asymmetric electrolyte to simultaneously meet contradictory requirements of anode and cathode," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Yuwei Zhao & Yue Lu & Huiping Li & Yongbin Zhu & You Meng & Na Li & Donghong Wang & Feng Jiang & Funian Mo & Changbai Long & Ying Guo & Xinliang Li & Zhaodong Huang & Qing Li & Johnny C. Ho & Jun Fan , 2022. "Few-layer bismuth selenide cathode for low-temperature quasi-solid-state aqueous zinc metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Songshan Bi & Shuai Wang & Fang Yue & Zhiwei Tie & Zhiqiang Niu, 2021. "A rechargeable aqueous manganese-ion battery based on intercalation chemistry," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    5. Quanquan Guo & Wei Li & Xiaodong Li & Jiaxu Zhang & Davood Sabaghi & Jianjun Zhang & Bowen Zhang & Dongqi Li & Jingwei Du & Xingyuan Chu & Sein Chung & Kilwon Cho & Nguyen Ngan Nguyen & Zhongquan Liao, 2024. "Proton-selective coating enables fast-kinetics high-mass-loading cathodes for sustainable zinc batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Choudhary, Ram Bilash & Ansari, Sarfaraz & Majumder, Mandira, 2021. "Recent advances on redox active composites of metal-organic framework and conducting polymers as pseudocapacitor electrode material," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    7. Zhiwei Li & Yinghong Xu & Langyuan Wu & Jiaxin Cui & Hui Dou & Xiaogang Zhang, 2023. "Enabling giant thermopower by heterostructure engineering of hydrated vanadium pentoxide for zinc ion thermal charging cells," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    8. Alessandro Innocenti & Dominic Bresser & Jürgen Garche & Stefano Passerini, 2024. "A critical discussion of the current availability of lithium and zinc for use in batteries," Nature Communications, Nature, vol. 15(1), pages 1-6, December.
    9. Chen, Binbin & Xuan, Jin & Offer, Gregory James & Wang, Huizhi, 2020. "Multiplex measurement of diffusion in zinc battery electrolytes from microfluidics using Raman microspectroscopy," Applied Energy, Elsevier, vol. 279(C).
    10. Amiri, Ahmad & Swart, Edward Ned & Polycarpou, Andreas A., 2021. "Recent advances in electrochemically-efficient materials for zinc-ion hybrid supercapacitors," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    11. Alanne, Kari & Cao, Sunliang, 2019. "An overview of the concept and technology of ubiquitous energy," Applied Energy, Elsevier, vol. 238(C), pages 284-302.
    12. Shuo Jin & Jiefu Yin & Xiaosi Gao & Arpita Sharma & Pengyu Chen & Shifeng Hong & Qing Zhao & Jingxu Zheng & Yue Deng & Yong Lak Joo & Lynden A. Archer, 2022. "Production of fast-charge Zn-based aqueous batteries via interfacial adsorption of ion-oligomer complexes," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    13. Yu Wang & Tairan Wang & Shuyu Bu & Jiaxiong Zhu & Yanbo Wang & Rong Zhang & Hu Hong & Wenjun Zhang & Jun Fan & Chunyi Zhi, 2023. "Sulfolane-containing aqueous electrolyte solutions for producing efficient ampere-hour-level zinc metal battery pouch cells," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    14. Priya Lakshmanan & Subadevi Rengapillai & Sivakumar Marimuthu & Suryanarayanan Vembu, 2022. "Turning Trash to Treasure: Reusable Glucose Kit as a Cell Using ZnO Derived from Metal Organic Framework (MOF) Electrode for Redox Flow Battery," Energies, MDPI, vol. 15(20), pages 1-15, October.
    15. Xin Shi & Jinhao Xie & Jin Wang & Shilei Xie & Zujin Yang & Xihong Lu, 2024. "A weakly solvating electrolyte towards practical rechargeable aqueous zinc-ion batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    16. Yangmoon Kim & Youngbin Park & Minkwan Kim & Jimin Lee & Ki Jae Kim & Jang Wook Choi, 2022. "Corrosion as the origin of limited lifetime of vanadium oxide-based aqueous zinc ion batteries," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    17. Song Chen & Deluo Ji & Qianwu Chen & Jizhen Ma & Shaoqi Hou & Jintao Zhang, 2023. "Coordination modulation of hydrated zinc ions to enhance redox reversibility of zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    18. Wenyao Zhang & Muyao Dong & Keren Jiang & Diling Yang & Xuehai Tan & Shengli Zhai & Renfei Feng & Ning Chen & Graham King & Hao Zhang & Hongbo Zeng & Hui Li & Markus Antonietti & Zhi Li, 2022. "Self-repairing interphase reconstructed in each cycle for highly reversible aqueous zinc batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    19. Rongyu Deng & Zhenjiang He & Fulu Chu & Jie Lei & Yi Cheng & You Zhou & Feixiang Wu, 2023. "An aqueous electrolyte densified by perovskite SrTiO3 enabling high-voltage zinc-ion batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    20. Wenjiao Ma & Tingting Liu & Chen Xu & Chengjun Lei & Pengjie Jiang & Xin He & Xiao Liang, 2023. "A twelve-electron conversion iodine cathode enabled by interhalogen chemistry in aqueous solution," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-27203-w. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.