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Reversible aqueous zinc/manganese oxide energy storage from conversion reactions

Author

Listed:
  • Huilin Pan

    (Energy & Environment Directorate, Pacific Northwest National Laboratory)

  • Yuyan Shao

    (Energy & Environment Directorate, Pacific Northwest National Laboratory)

  • Pengfei Yan

    (Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory)

  • Yingwen Cheng

    (Energy & Environment Directorate, Pacific Northwest National Laboratory)

  • Kee Sung Han

    (Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory)

  • Zimin Nie

    (Energy & Environment Directorate, Pacific Northwest National Laboratory)

  • Chongmin Wang

    (Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory)

  • Jihui Yang

    (University of Washington)

  • Xiaolin Li

    (Energy & Environment Directorate, Pacific Northwest National Laboratory)

  • Priyanka Bhattacharya

    (Energy & Environment Directorate, Pacific Northwest National Laboratory)

  • Karl T. Mueller

    (Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory
    Pennsylvania State University)

  • Jun Liu

    (Energy & Environment Directorate, Pacific Northwest National Laboratory)

Abstract

Rechargeable aqueous batteries such as alkaline zinc/manganese oxide batteries are highly desirable for large-scale energy storage owing to their low cost and high safety; however, cycling stability is a major issue for their applications. Here we demonstrate a highly reversible zinc/manganese oxide system in which optimal mild aqueous ZnSO4-based solution is used as the electrolyte, and nanofibres of a manganese oxide phase, α-MnO2, are used as the cathode. We show that a chemical conversion reaction mechanism between α-MnO2 and H+ is mainly responsible for the good performance of the system. This includes an operating voltage of 1.44 V, a capacity of 285 mAh g−1 (MnO2), and capacity retention of 92% over 5,000 cycles. The Zn metal anode also shows high stability. This finding opens new opportunities for the development of low-cost, high-performance rechargeable aqueous batteries.

Suggested Citation

  • Huilin Pan & Yuyan Shao & Pengfei Yan & Yingwen Cheng & Kee Sung Han & Zimin Nie & Chongmin Wang & Jihui Yang & Xiaolin Li & Priyanka Bhattacharya & Karl T. Mueller & Jun Liu, 2016. "Reversible aqueous zinc/manganese oxide energy storage from conversion reactions," Nature Energy, Nature, vol. 1(5), pages 1-7, May.
    • Handle: RePEc:nat:natene:v:1:y:2016:i:5:d:10.1038_nenergy.2016.39
    DOI: 10.1038/nenergy.2016.39
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    Cited by:

    1. Wenyao Zhang & Muyao Dong & Keren Jiang & Diling Yang & Xuehai Tan & Shengli Zhai & Renfei Feng & Ning Chen & Graham King & Hao Zhang & Hongbo Zeng & Hui Li & Markus Antonietti & Zhi Li, 2022. "Self-repairing interphase reconstructed in each cycle for highly reversible aqueous zinc batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    2. Wenjiao Ma & Tingting Liu & Chen Xu & Chengjun Lei & Pengjie Jiang & Xin He & Xiao Liang, 2023. "A twelve-electron conversion iodine cathode enabled by interhalogen chemistry in aqueous solution," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Huajun Tian & Guangxia Feng & Qi Wang & Zhao Li & Wei Zhang & Marcos Lucero & Zhenxing Feng & Zi-Le Wang & Yuning Zhang & Cheng Zhen & Meng Gu & Xiaonan Shan & Yang Yang, 2022. "Three-dimensional Zn-based alloys for dendrite-free aqueous Zn battery in dual-cation electrolytes," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    4. Amiri, Ahmad & Swart, Edward Ned & Polycarpou, Andreas A., 2021. "Recent advances in electrochemically-efficient materials for zinc-ion hybrid supercapacitors," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    5. Shengmei Chen & Yiran Ying & Longtao Ma & Daming Zhu & Haitao Huang & Li Song & Chunyi Zhi, 2023. "An asymmetric electrolyte to simultaneously meet contradictory requirements of anode and cathode," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Kefu Zhu & Shiqiang Wei & Hongwei Shou & Feiran Shen & Shuangming Chen & Pengjun Zhang & Changda Wang & Yuyang Cao & Xin Guo & Mi Luo & Hongjun Zhang & Bangjiao Ye & Xiaojun Wu & Lunhua He & Li Song, 2021. "Defect engineering on V2O3 cathode for long-cycling aqueous zinc metal batteries," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    7. Shuo Jin & Jiefu Yin & Xiaosi Gao & Arpita Sharma & Pengyu Chen & Shifeng Hong & Qing Zhao & Jingxu Zheng & Yue Deng & Yong Lak Joo & Lynden A. Archer, 2022. "Production of fast-charge Zn-based aqueous batteries via interfacial adsorption of ion-oligomer complexes," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    8. Zhiyang Zheng & Xiongwei Zhong & Qi Zhang & Mengtian Zhang & Lixin Dai & Xiao Xiao & Jiahe Xu & Miaolun Jiao & Boran Wang & Hong Li & Yeyang Jia & Rui Mao & Guangmin Zhou, 2024. "An extended substrate screening strategy enabling a low lattice mismatch for highly reversible zinc anodes," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    9. Alanne, Kari & Cao, Sunliang, 2019. "An overview of the concept and technology of ubiquitous energy," Applied Energy, Elsevier, vol. 238(C), pages 284-302.
    10. Choudhary, Ram Bilash & Ansari, Sarfaraz & Majumder, Mandira, 2021. "Recent advances on redox active composites of metal-organic framework and conducting polymers as pseudocapacitor electrode material," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    11. Rongyu Deng & Zhenjiang He & Fulu Chu & Jie Lei & Yi Cheng & You Zhou & Feixiang Wu, 2023. "An aqueous electrolyte densified by perovskite SrTiO3 enabling high-voltage zinc-ion batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    12. Alessandro Innocenti & Dominic Bresser & Jürgen Garche & Stefano Passerini, 2024. "A critical discussion of the current availability of lithium and zinc for use in batteries," Nature Communications, Nature, vol. 15(1), pages 1-6, December.
    13. Chang Li & Ryan Kingsbury & Arashdeep Singh Thind & Abhinandan Shyamsunder & Timothy T. Fister & Robert F. Klie & Kristin A. Persson & Linda F. Nazar, 2023. "Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    14. Quanquan Guo & Wei Li & Xiaodong Li & Jiaxu Zhang & Davood Sabaghi & Jianjun Zhang & Bowen Zhang & Dongqi Li & Jingwei Du & Xingyuan Chu & Sein Chung & Kilwon Cho & Nguyen Ngan Nguyen & Zhongquan Liao, 2024. "Proton-selective coating enables fast-kinetics high-mass-loading cathodes for sustainable zinc batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    15. Yuwei Zhao & Yue Lu & Huiping Li & Yongbin Zhu & You Meng & Na Li & Donghong Wang & Feng Jiang & Funian Mo & Changbai Long & Ying Guo & Xinliang Li & Zhaodong Huang & Qing Li & Johnny C. Ho & Jun Fan , 2022. "Few-layer bismuth selenide cathode for low-temperature quasi-solid-state aqueous zinc metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.

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