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Anti-dendrite separator interlayer enabling staged zinc deposition for enhanced cycling stability of aqueous zinc batteries

Author

Listed:
  • Dun Wang

    (Shenzhen University of Advanced Technology)

  • Sanlue Hu

    (Chinese Academy of Sciences)

  • Titi Li

    (Shenzhen University of Advanced Technology)

  • Caiyun Chang

    (Chinese Academy of Sciences)

  • Senlin Li

    (Shenzhen University of Advanced Technology
    Chinese Academy of Sciences)

  • Songde Guo

    (Shenzhen University of Advanced Technology)

  • Huan Li

    (Shenzhen University of Advanced Technology)

  • Qingming Liu

    (Towngas Energy Academy)

  • Jinqiu Gong

    (Towngas Energy Academy)

  • Jun Zhou

    (Towngas Energy Academy)

  • Cuiping Han

    (Shenzhen University of Advanced Technology
    Chinese Academy of Sciences)

Abstract

Aqueous zinc ion batteries exhibit great prospects due to their low cost and high safety, while their lifespan is limited by severe dendritic growth problems. Herein, we develop an anti-dendrite hot-pressing separator interlayer through a mass-producible hot-pressing strategy, by spreading metal-organic framework (MOF) precursor on nonwoven matrix followed by a simple hot-pressing process. The in situ modification of MOF crystals on fiber surface processes abundant nitrogenous functional groups and high specific surface area (190.8 m2 g−1) with a strong attraction to Zn2+. These features contribute to a staged deposition behavior to promote uniform nucleation at high concentrations and two-dimensional grain growth at low concentrations. Consequently, Zn | |Zn symmetrical cells with hot-pressing separator interlayer demonstrate cycle lives of 3000 hours at 2 mA cm−2, 2 mAh cm−2. Moreover, Zn | |I2 pouch batteries with hot-pressing separator interlayer realizes 840 cycles lifespan with a capacity retention of 90.9% and a final discharge capacity of 110.6 mAh at 25 °C.

Suggested Citation

  • Dun Wang & Sanlue Hu & Titi Li & Caiyun Chang & Senlin Li & Songde Guo & Huan Li & Qingming Liu & Jinqiu Gong & Jun Zhou & Cuiping Han, 2025. "Anti-dendrite separator interlayer enabling staged zinc deposition for enhanced cycling stability of aqueous zinc batteries," Nature Communications, Nature, vol. 16(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-024-55153-6
    DOI: 10.1038/s41467-024-55153-6
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    References listed on IDEAS

    as
    1. Chang Li & Ryan Kingsbury & Arashdeep Singh Thind & Abhinandan Shyamsunder & Timothy T. Fister & Robert F. Klie & Kristin A. Persson & Linda F. Nazar, 2023. "Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    2. Xinhua Zheng & Zaichun Liu & Jifei Sun & Ruihao Luo & Kui Xu & Mingyu Si & Ju Kang & Yuan Yuan & Shuang Liu & Touqeer Ahmad & Taoli Jiang & Na Chen & Mingming Wang & Yan Xu & Mingyan Chuai & Zhengxin , 2023. "Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
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