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Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities

Author

Listed:
  • Ning Zhang

    (Nankai University)

  • Fangyi Cheng

    (Nankai University
    Nankai University)

  • Junxiang Liu

    (Nankai University)

  • Liubin Wang

    (Nankai University)

  • Xinghui Long

    (Chinese Academy of Sciences)

  • Xiaosong Liu

    (Chinese Academy of Sciences)

  • Fujun Li

    (Nankai University)

  • Jun Chen

    (Nankai University
    Nankai University)

Abstract

Although alkaline zinc-manganese dioxide batteries have dominated the primary battery applications, it is challenging to make them rechargeable. Here we report a high-performance rechargeable zinc-manganese dioxide system with an aqueous mild-acidic zinc triflate electrolyte. We demonstrate that the tunnel structured manganese dioxide polymorphs undergo a phase transition to layered zinc-buserite on first discharging, thus allowing subsequent intercalation of zinc cations in the latter structure. Based on this electrode mechanism, we formulate an aqueous zinc/manganese triflate electrolyte that enables the formation of a protective porous manganese oxide layer. The cathode exhibits a high reversible capacity of 225 mAh g−1 and long-term cyclability with 94% capacity retention over 2000 cycles. Remarkably, the pouch zinc-manganese dioxide battery delivers a total energy density of 75.2 Wh kg−1. As a result of the superior battery performance, the high safety of aqueous electrolyte, the facile cell assembly and the cost benefit of the source materials, this zinc-manganese dioxide system is believed to be promising for large-scale energy storage applications.

Suggested Citation

  • Ning Zhang & Fangyi Cheng & Junxiang Liu & Liubin Wang & Xinghui Long & Xiaosong Liu & Fujun Li & Jun Chen, 2017. "Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:8:y:2017:i:1:d:10.1038_s41467-017-00467-x
    DOI: 10.1038/s41467-017-00467-x
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    Cited by:

    1. Xinhua Zheng & Zaichun Liu & Jifei Sun & Ruihao Luo & Kui Xu & Mingyu Si & Ju Kang & Yuan Yuan & Shuang Liu & Touqeer Ahmad & Taoli Jiang & Na Chen & Mingming Wang & Yan Xu & Mingyan Chuai & Zhengxin , 2023. "Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Shengmei Chen & Yiran Ying & Longtao Ma & Daming Zhu & Haitao Huang & Li Song & Chunyi Zhi, 2023. "An asymmetric electrolyte to simultaneously meet contradictory requirements of anode and cathode," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Bomian Zhang & Jinghui Chen & Weiyi Sun & Yubo Shao & Lei Zhang & Kangning Zhao, 2022. "Challenges and Perspectives for Doping Strategy for Manganese-Based Zinc-ion Battery Cathode," Energies, MDPI, vol. 15(13), pages 1-20, June.
    4. Zhiyang Zheng & Xiongwei Zhong & Qi Zhang & Mengtian Zhang & Lixin Dai & Xiao Xiao & Jiahe Xu & Miaolun Jiao & Boran Wang & Hong Li & Yeyang Jia & Rui Mao & Guangmin Zhou, 2024. "An extended substrate screening strategy enabling a low lattice mismatch for highly reversible zinc anodes," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    5. Yu Wang & Tairan Wang & Shuyu Bu & Jiaxiong Zhu & Yanbo Wang & Rong Zhang & Hu Hong & Wenjun Zhang & Jun Fan & Chunyi Zhi, 2023. "Sulfolane-containing aqueous electrolyte solutions for producing efficient ampere-hour-level zinc metal battery pouch cells," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    6. Qingshun Nian & Xuan Luo & Digen Ruan & Yecheng Li & Bing-Qing Xiong & Zhuangzhuang Cui & Zihong Wang & Qi Dong & Jiajia Fan & Jinyu Jiang & Jun Ma & Zhihao Ma & Dazhuang Wang & Xiaodi Ren, 2024. "Highly reversible zinc metal anode enabled by strong Brønsted acid and hydrophobic interfacial chemistry," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    7. Alessandro Innocenti & Dominic Bresser & Jürgen Garche & Stefano Passerini, 2024. "A critical discussion of the current availability of lithium and zinc for use in batteries," Nature Communications, Nature, vol. 15(1), pages 1-6, December.
    8. Chang Li & Ryan Kingsbury & Arashdeep Singh Thind & Abhinandan Shyamsunder & Timothy T. Fister & Robert F. Klie & Kristin A. Persson & Linda F. Nazar, 2023. "Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    9. Lyn Marie De Juan-Corpuz & Ryan Dula Corpuz & Anongnat Somwangthanaroj & Mai Thanh Nguyen & Tetsu Yonezawa & Jianmin Ma & Soorathep Kheawhom, 2019. "Binder-Free Centimeter-Long V 2 O 5 Nanofibers on Carbon Cloth as Cathode Material for Zinc-Ion Batteries," Energies, MDPI, vol. 13(1), pages 1-13, December.

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