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Realizing high zinc reversibility in rechargeable batteries

Author

Listed:
  • Lin Ma

    (US Army Research Laboratory)

  • Marshall A. Schroeder

    (US Army Research Laboratory)

  • Oleg Borodin

    (US Army Research Laboratory)

  • Travis P. Pollard

    (US Army Research Laboratory)

  • Michael S. Ding

    (US Army Research Laboratory)

  • Chunsheng Wang

    (University of Maryland)

  • Kang Xu

    (US Army Research Laboratory)

Abstract

Rechargeable zinc metal batteries (RZMBs) offer a compelling complement to existing lithium ion and emerging lithium metal batteries for meeting the increasing energy storage demands of the future. Multiple recent reports have suggested that optimized electrolytes resolve a century-old challenge for RZMBs by achieving extremely reversible zinc plating/stripping with Coulombic efficiencies (CEs) approaching 100%. However, the disparity among published testing methods and conditions severely convolutes electrolyte performance comparisons. The lack of rigorous and standardized protocols is rapidly becoming an impediment to ongoing research and commercialization thrusts. This Perspective examines recent efforts to improve the reversibility of the zinc metal anode in terms of key parameters, including CE protocols, plating morphology, dendrite formation and long-term stability. Then we suggest the most appropriate standard protocols for future CE determination. Finally, we envision future strategies to improve zinc/electrolyte stability so that research efforts can be better aligned towards realistic performance targets for RZMB commercialization.

Suggested Citation

  • Lin Ma & Marshall A. Schroeder & Oleg Borodin & Travis P. Pollard & Michael S. Ding & Chunsheng Wang & Kang Xu, 2020. "Realizing high zinc reversibility in rechargeable batteries," Nature Energy, Nature, vol. 5(10), pages 743-749, October.
    • Handle: RePEc:nat:natene:v:5:y:2020:i:10:d:10.1038_s41560-020-0674-x
    DOI: 10.1038/s41560-020-0674-x
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    Cited by:

    1. Shengmei Chen & Yiran Ying & Longtao Ma & Daming Zhu & Haitao Huang & Li Song & Chunyi Zhi, 2023. "An asymmetric electrolyte to simultaneously meet contradictory requirements of anode and cathode," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Minghao Zhang & Chenxi Sun & Guanhong Chen & Yuanhong Kang & Zeheng Lv & Jin Yang & Siyang Li & Pengxiang Lin & Rong Tang & Zhipeng Wen & Cheng Chao Li & Jinbao Zhao & Yang Yang, 2024. "Synergetic bifunctional Cu-In alloy interface enables Ah-level Zn metal pouch cells," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    3. Ruirui Zhao & Haifeng Wang & Haoran Du & Ying Yang & Zhonghui Gao & Long Qie & Yunhui Huang, 2022. "Lanthanum nitrate as aqueous electrolyte additive for favourable zinc metal electrodeposition," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Yunxiang Zhao & Shan Guo & Manjing Chen & Bingan Lu & Xiaotan Zhang & Shuquan Liang & Jiang Zhou, 2023. "Tailoring grain boundary stability of zinc-titanium alloy for long-lasting aqueous zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Ze Chen & Tairan Wang & Zhuoxi Wu & Yue Hou & Ao Chen & Yanbo Wang & Zhaodong Huang & Oliver G. Schmidt & Minshen Zhu & Jun Fan & Chunyi Zhi, 2024. "Polymer hetero-electrolyte enabled solid-state 2.4-V Zn/Li hybrid batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    6. Chang Li & Ryan Kingsbury & Arashdeep Singh Thind & Abhinandan Shyamsunder & Timothy T. Fister & Robert F. Klie & Kristin A. Persson & Linda F. Nazar, 2023. "Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    7. Qing Li & Ao Chen & Donghong Wang & Yuwei Zhao & Xiaoqi Wang & Xu Jin & Bo Xiong & Chunyi Zhi, 2022. "Tailoring the metal electrode morphology via electrochemical protocol optimization for long-lasting aqueous zinc batteries," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

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