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Corrosion as the origin of limited lifetime of vanadium oxide-based aqueous zinc ion batteries

Author

Listed:
  • Yangmoon Kim

    (Seoul National University)

  • Youngbin Park

    (Seoul National University)

  • Minkwan Kim

    (Seoul National University)

  • Jimin Lee

    (Seoul National University)

  • Ki Jae Kim

    (Konkuk University)

  • Jang Wook Choi

    (Seoul National University)

Abstract

Aqueous zinc ion batteries are receiving increasing attention for large-scale energy storage systems owing to their attractive features with respect to safety, cost, and scalability. Although vanadium oxides with various compositions have been demonstrated to store zinc ions reversibly, their limited cyclability especially at low current densities and their poor calendar life impede their widespread practical adoption. Herein, we reveal that the electrochemically inactive zinc pyrovanadate (ZVO) phase formed on the cathode surface is the main cause of the limited sustainability. Moreover, the formation of ZVO is closely related to the corrosion of the zinc metal counter electrode by perturbing the pH of the electrolyte. Thus, the dissolution of VO2(OH)2−, the source of the vanadium in the ZVO, is no longer prevented. The proposed amalgamated Zn anode improves the cyclability drastically by blocking the corrosion at the anode, verifying the importance of pH control and the interplay between both electrodes.

Suggested Citation

  • Yangmoon Kim & Youngbin Park & Minkwan Kim & Jimin Lee & Ki Jae Kim & Jang Wook Choi, 2022. "Corrosion as the origin of limited lifetime of vanadium oxide-based aqueous zinc ion batteries," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29987-x
    DOI: 10.1038/s41467-022-29987-x
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    References listed on IDEAS

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    1. Dipan Kundu & Brian D. Adams & Victor Duffort & Shahrzad Hosseini Vajargah & Linda F. Nazar, 2016. "A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode," Nature Energy, Nature, vol. 1(10), pages 1-8, October.
    2. Zirui Lin & Hua-Yu Shi & Lu Lin & Xianpeng Yang & Wanlong Wu & Xiaoqi Sun, 2021. "A high capacity small molecule quinone cathode for rechargeable aqueous zinc-organic batteries," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Kwan Woo Nam & Sarah S. Park & Roberto dos Reis & Vinayak P. Dravid & Heejin Kim & Chad A. Mirkin & J. Fraser Stoddart, 2019. "Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
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    Cited by:

    1. Yunxiang Zhao & Shan Guo & Manjing Chen & Bingan Lu & Xiaotan Zhang & Shuquan Liang & Jiang Zhou, 2023. "Tailoring grain boundary stability of zinc-titanium alloy for long-lasting aqueous zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Yu Wang & Tairan Wang & Shuyu Bu & Jiaxiong Zhu & Yanbo Wang & Rong Zhang & Hu Hong & Wenjun Zhang & Jun Fan & Chunyi Zhi, 2023. "Sulfolane-containing aqueous electrolyte solutions for producing efficient ampere-hour-level zinc metal battery pouch cells," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    3. Qingshun Nian & Xuan Luo & Digen Ruan & Yecheng Li & Bing-Qing Xiong & Zhuangzhuang Cui & Zihong Wang & Qi Dong & Jiajia Fan & Jinyu Jiang & Jun Ma & Zhihao Ma & Dazhuang Wang & Xiaodi Ren, 2024. "Highly reversible zinc metal anode enabled by strong Brønsted acid and hydrophobic interfacial chemistry," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Kadam, Nishad & Sarkar, A., 2023. "A high voltage zinc–air battery with two isolated electrolytes and moving auxiliary electrodes," Applied Energy, Elsevier, vol. 344(C).
    5. Xin Shi & Jinhao Xie & Jin Wang & Shilei Xie & Zujin Yang & Xihong Lu, 2024. "A weakly solvating electrolyte towards practical rechargeable aqueous zinc-ion batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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