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Atomic-precision Pt6 nanoclusters for enhanced hydrogen electro-oxidation

Author

Listed:
  • Xiaoning Wang

    (China University of Petroleum)

  • Lianming Zhao

    (China University of Petroleum)

  • Xuejin Li

    (China University of Petroleum)

  • Yong Liu

    (Qingdao University of Science and Technology)

  • Yesheng Wang

    (China University of Petroleum)

  • Qiaofeng Yao

    (National University of Singapore
    Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City)

  • Jianping Xie

    (National University of Singapore
    Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City)

  • Qingzhong Xue

    (China University of Petroleum)

  • Zifeng Yan

    (China University of Petroleum)

  • Xun Yuan

    (Qingdao University of Science and Technology)

  • Wei Xing

    (China University of Petroleum)

Abstract

The discord between the insufficient abundance and the excellent electrocatalytic activity of Pt urgently requires its atomic-level engineering for minimal Pt dosage yet maximized electrocatalytic performance. Here we report the design of ultrasmall triphenylphosphine-stabilized Pt6 nanoclusters for electrocatalytic hydrogen oxidation reaction in alkaline solution. Benefiting from the self-optimized ligand effect and atomic-precision structure, the nanocluster electrocatalyst demonstrates a high mass activity, a high stability, and outperforms both Pt single atoms and Pt nanoparticle analogues, uncovering an unexpected size optimization principle for designing Pt electrocatalysts. Moreover, the nanocluster electrocatalyst delivers a high CO-tolerant ability that conventional Pt/C catalyst lacks. Theoretical calculations confirm that the enhanced electrocatalytic performance is attributable to the bifold effects of the triphenylphosphine ligand, which can not only tune the formation of atomically precise platinum nanoclusters, but also shift the d-band center of Pt atoms for favorable adsorption kinetics of *H, *OH, and CO.

Suggested Citation

  • Xiaoning Wang & Lianming Zhao & Xuejin Li & Yong Liu & Yesheng Wang & Qiaofeng Yao & Jianping Xie & Qingzhong Xue & Zifeng Yan & Xun Yuan & Wei Xing, 2022. "Atomic-precision Pt6 nanoclusters for enhanced hydrogen electro-oxidation," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29276-7
    DOI: 10.1038/s41467-022-29276-7
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    2. Lin Li & Ying Lv & Hongting Sheng & Yonglei Du & Haifeng Li & Yapei Yun & Ziyi Zhang & Haizhu Yu & Manzhou Zhu, 2023. "A low-nuclear Ag4 nanocluster as a customized catalyst for the cyclization of propargylamine with CO2," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
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    6. Yong Yin & Bingcheng Luo & Kezhi Li & Benjamin M. Moskowitz & Bar Mosevitzky Lis & Israel E. Wachs & Minghui Zhu & Ye Sun & Tianle Zhu & Xiang Li, 2024. "Plasma-assisted manipulation of vanadia nanoclusters for efficient selective catalytic reduction of NOx," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    7. Xiaoning Wang & Yanfu Tong & Wenting Feng & Pengyun Liu & Xuejin Li & Yongpeng Cui & Tonghui Cai & Lianming Zhao & Qingzhong Xue & Zifeng Yan & Xun Yuan & Wei Xing, 2023. "Embedding oxophilic rare-earth single atom in platinum nanoclusters for efficient hydrogen electro-oxidation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
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