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Constructing CO-immune water dissociation sites around Pt to achieve stable operation in high CO concentration environment

Author

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  • Daojun Long

    (Chongqing University)

  • Yongduo Liu

    (Chongqing University)

  • Xinyu Ping

    (Chongqing University)

  • Fadong Chen

    (Chongqing University)

  • Xiongxin Tao

    (Chongqing University)

  • Zhenyang Xie

    (Chongqing University)

  • Minjian Wang

    (Chongqing University)

  • Meng Wang

    (Chongqing University)

  • Li Li

    (Chongqing University)

  • Lin Guo

    (Research Institute of Petroleum Processing Co., Ltd., SINOPEC)

  • Siguo Chen

    (Chongqing University)

  • Zidong Wei

    (Chongqing University)

Abstract

The serious problem of carbon monoxide (CO) poisoning on the surface of Pt-based catalysts has long constrained the commercialization of proton exchange membrane fuel cells (PEMFCs). Regeneration of Pt sites by maintaining CO scavenging ability through precise construction of the surface and interface structure of the catalyst is the key to obtaining high-performance CO-resistant catalysts. Here, we used molybdenum carbide (MoCx) as the support for Pt and introduced Ru single atoms (SA-Ru) at the Pt-MoCx interface to jointly decrease the CO adsorption strength on Pt. More importantly, the MoCx and SA-Ru are immune to CO poisoning, which continuously assists in the oxidation of adsorbed CO by generating oxygen species from water dissociation. These two effects combine to confer this anode catalyst (SA-Ru@Pt/MoCx) remarkable CO tolerance and the ability to operate stably in fuel cell with high CO concentration (power output 85.5 mW cm−2@20,000 ppm CO + H2 – O2), making it possible to directly use the cheap reformed hydrogen as the fuel for PEMFCs.

Suggested Citation

  • Daojun Long & Yongduo Liu & Xinyu Ping & Fadong Chen & Xiongxin Tao & Zhenyang Xie & Minjian Wang & Meng Wang & Li Li & Lin Guo & Siguo Chen & Zidong Wei, 2024. "Constructing CO-immune water dissociation sites around Pt to achieve stable operation in high CO concentration environment," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51562-9
    DOI: 10.1038/s41467-024-51562-9
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    1. Xiaoning Wang & Lianming Zhao & Xuejin Li & Yong Liu & Yesheng Wang & Qiaofeng Yao & Jianping Xie & Qingzhong Xue & Zifeng Yan & Xun Yuan & Wei Xing, 2022. "Atomic-precision Pt6 nanoclusters for enhanced hydrogen electro-oxidation," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Lili Lin & Wu Zhou & Rui Gao & Siyu Yao & Xiao Zhang & Wenqian Xu & Shijian Zheng & Zheng Jiang & Qiaolin Yu & Yong-Wang Li & Chuan Shi & Xiao-Dong Wen & Ding Ma, 2017. "Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts," Nature, Nature, vol. 544(7648), pages 80-83, April.
    3. Mengqiu Xu & Fangfang Wu & Ye Zhang & Yuanhui Yao & Genping Zhu & Xiaoyu Li & Liang Chen & Gan Jia & Xiaohong Wu & Youju Huang & Peng Gao & Wei Ye, 2023. "Kinetically matched C–N coupling toward efficient urea electrosynthesis enabled on copper single-atom alloy," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Lei Zhang & Rutong Si & Hanshuo Liu & Ning Chen & Qi Wang & Keegan Adair & Zhiqiang Wang & Jiatang Chen & Zhongxin Song & Junjie Li & Mohammad Norouzi Banis & Ruying Li & Tsun-Kong Sham & Meng Gu & Li, 2019. "Atomic layer deposited Pt-Ru dual-metal dimers and identifying their active sites for hydrogen evolution reaction," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    5. Li, Zheng & Wang, Yameng & Mu, Yongbiao & Wu, Buke & Jiang, Yuting & Zeng, Lin & Zhao, Tianshou, 2023. "Recent advances in the anode catalyst layer for proton exchange membrane fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).
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