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Subnanometer high-entropy alloy nanowires enable remarkable hydrogen oxidation catalysis

Author

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  • Changhong Zhan

    (State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University)

  • Yong Xu

    (Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology)

  • Lingzheng Bu

    (State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University)

  • Huaze Zhu

    (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences)

  • Yonggang Feng

    (College of Chemistry, Chemical Engineering and Materials Science, Soochow University)

  • Tang Yang

    (State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University)

  • Ying Zhang

    (State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University)

  • Zhiqing Yang

    (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences)

  • Bolong Huang

    (The Hong Kong Polytechnic University, Hung Hom)

  • Qi Shao

    (College of Chemistry, Chemical Engineering and Materials Science, Soochow University)

  • Xiaoqing Huang

    (State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University)

Abstract

High-entropy alloys (HEAs) with unique physicochemical properties have attracted tremendous attention in many fields, yet the precise control on dimension and morphology at atomic level remains formidable challenges. Herein, we synthesize unique PtRuNiCoFeMo HEA subnanometer nanowires (SNWs) for alkaline hydrogen oxidation reaction (HOR). The mass and specific activities of HEA SNWs/C reach 6.75 A mgPt+Ru−1 and 8.96 mA cm−2, respectively, which are 2.8/2.6, 4.1/2.4, and 19.8/18.7 times higher than those of HEA NPs/C, commercial PtRu/C and Pt/C, respectively. It can even display enhanced resistance to CO poisoning during HOR in the presence of 1000 ppm CO. Density functional theory calculations reveal that the strong interactions between different metal sites in HEA SNWs can greatly regulate the binding strength of proton and hydroxyl, and therefore enhances the HOR activity. This work not only provides a viable synthetic route for the fabrication of Pt-based HEA subnano/nano materials, but also promotes the fundamental researches on catalysis and beyond.

Suggested Citation

  • Changhong Zhan & Yong Xu & Lingzheng Bu & Huaze Zhu & Yonggang Feng & Tang Yang & Ying Zhang & Zhiqing Yang & Bolong Huang & Qi Shao & Xiaoqing Huang, 2021. "Subnanometer high-entropy alloy nanowires enable remarkable hydrogen oxidation catalysis," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26425-2
    DOI: 10.1038/s41467-021-26425-2
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    4. Yin, Yan & Yue, Runfei & Pei, Yabiao & Zhu, Weikang & Liu, Haotian & Yin, Shuoyao & Liu, Xin & Wang, Lianqin & Zhang, Junfeng, 2023. "Synthesis of fine nano-Pt supported on carbon nanotubes for hydrogen oxidation under alkaline conditions," Energy, Elsevier, vol. 281(C).
    5. Zhi Wen Chen & Jian Li & Pengfei Ou & Jianan Erick Huang & Zi Wen & LiXin Chen & Xue Yao & GuangMing Cai & Chun Cheng Yang & Chandra Veer Singh & Qing Jiang, 2024. "Unusual Sabatier principle on high entropy alloy catalysts for hydrogen evolution reactions," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Xiaoning Wang & Lianming Zhao & Xuejin Li & Yong Liu & Yesheng Wang & Qiaofeng Yao & Jianping Xie & Qingzhong Xue & Zifeng Yan & Xun Yuan & Wei Xing, 2022. "Atomic-precision Pt6 nanoclusters for enhanced hydrogen electro-oxidation," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Jiaqi Feng & Libing Zhang & Shoujie Liu & Liang Xu & Xiaodong Ma & Xingxing Tan & Limin Wu & Qingli Qian & Tianbin Wu & Jianling Zhang & Xiaofu Sun & Buxing Han, 2023. "Modulating adsorbed hydrogen drives electrochemical CO2-to-C2 products," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    8. Qiqi Mao & Xu Mu & Wenxin Wang & Kai Deng & Hongjie Yu & Ziqiang Wang & You Xu & Liang Wang & Hongjing Wang, 2023. "Atomically dispersed Cu coordinated Rh metallene arrays for simultaneously electrochemical aniline synthesis and biomass upgrading," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    9. Xiaoning Wang & Yanfu Tong & Wenting Feng & Pengyun Liu & Xuejin Li & Yongpeng Cui & Tonghui Cai & Lianming Zhao & Qingzhong Xue & Zifeng Yan & Xun Yuan & Wei Xing, 2023. "Embedding oxophilic rare-earth single atom in platinum nanoclusters for efficient hydrogen electro-oxidation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
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