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Reversible hydrogen spillover in Ru-WO3-x enhances hydrogen evolution activity in neutral pH water splitting

Author

Listed:
  • Jiadong Chen

    (Zhejiang University
    Nanyang Technological University)

  • Chunhong Chen

    (Zhejiang University)

  • Minkai Qin

    (Zhejiang University)

  • Ben Li

    (Zhejiang University)

  • Binbin Lin

    (Zhejiang University)

  • Qing Mao

    (Dalian University of Technology)

  • Hongbin Yang

    (Nanyang Technological University)

  • Bin Liu

    (Nanyang Technological University
    Nanyang Technological University)

  • Yong Wang

    (Zhejiang University)

Abstract

Noble metal electrocatalysts (e.g., Pt, Ru, etc.) suffer from sluggish kinetics of water dissociation for the electrochemical reduction of water to molecular hydrogen in alkaline and neutral pH environments. Herein, we found that an integration of Ru nanoparticles (NPs) on oxygen-deficient WO3-x manifested a 24.0-fold increase in hydrogen evolution reaction (HER) activity compared with commercial Ru/C electrocatalyst in neutral electrolyte. Oxygen-deficient WO3-x is shown to possess large capacity for storing protons, which could be transferred to the Ru NPs under cathodic potential. This significantly increases the hydrogen coverage on the surface of Ru NPs in HER and thus changes the rate-determining step of HER on Ru from water dissociation to hydrogen recombination.

Suggested Citation

  • Jiadong Chen & Chunhong Chen & Minkai Qin & Ben Li & Binbin Lin & Qing Mao & Hongbin Yang & Bin Liu & Yong Wang, 2022. "Reversible hydrogen spillover in Ru-WO3-x enhances hydrogen evolution activity in neutral pH water splitting," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33007-3
    DOI: 10.1038/s41467-022-33007-3
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    References listed on IDEAS

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    1. Sheng Zhao & Sung-Fu Hung & Liming Deng & Wen-Jing Zeng & Tian Xiao & Shaoxiong Li & Chun-Han Kuo & Han-Yi Chen & Feng Hu & Shengjie Peng, 2024. "Constructing regulable supports via non-stoichiometric engineering to stabilize ruthenium nanoparticles for enhanced pH-universal water splitting," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Zhi Wen Chen & Jian Li & Pengfei Ou & Jianan Erick Huang & Zi Wen & LiXin Chen & Xue Yao & GuangMing Cai & Chun Cheng Yang & Chandra Veer Singh & Qing Jiang, 2024. "Unusual Sabatier principle on high entropy alloy catalysts for hydrogen evolution reactions," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Zhigang Chen & Wenbin Gong & Juan Wang & Shuang Hou & Guang Yang & Chengfeng Zhu & Xiyue Fan & Yifan Li & Rui Gao & Yi Cui, 2023. "Metallic W/WO2 solid-acid catalyst boosts hydrogen evolution reaction in alkaline electrolyte," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Yaoda Liu & Lei Li & Li Wang & Na Li & Xiaoxu Zhao & Ya Chen & Thangavel Sakthivel & Zhengfei Dai, 2024. "Janus electronic state of supported iridium nanoclusters for sustainable alkaline water electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Jinqi Xiong & Shanjun Mao & Qian Luo & Honghui Ning & Bing Lu & Yanling Liu & Yong Wang, 2024. "Mediating trade-off between activity and selectivity in alkynes semi-hydrogenation via a hydrophilic polar layer," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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