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Atomically dispersed chromium coordinated with hydroxyl clusters enabling efficient hydrogen oxidation on ruthenium

Author

Listed:
  • Bingxing Zhang

    (Zhejiang University)

  • Baohua Zhang

    (Zhejiang University)

  • Guoqiang Zhao

    (Zhejiang University)

  • Jianmei Wang

    (Zhejiang University)

  • Danqing Liu

    (Zhejiang University)

  • Yaping Chen

    (Zhejiang University)

  • Lixue Xia

    (International School of Materials Science and Engineering, Wuhan University of Technology)

  • Mingxia Gao

    (Zhejiang University)

  • Yongfeng Liu

    (Zhejiang University)

  • Wenping Sun

    (Zhejiang University)

  • Hongge Pan

    (Zhejiang University
    Xi’an Technological University)

Abstract

Overcoming the sluggish kinetics of alkaline hydrogen oxidation reaction (HOR) is challenging but is of critical importance for practical anion exchange membrane fuel cells. Herein, abundant and efficient interfacial active sites are created on ruthenium (Ru) nanoparticles by anchoring atomically isolated chromium coordinated with hydroxyl clusters (Cr1(OH)x) for accelerated alkaline HOR. This catalyst system delivers 50-fold enhanced HOR activity with excellent durability and CO anti-poisoning ability via switching the active sites from Ru surface to Cr1(OH)x-Ru interface. Fundamentally different from the conventional mechanism merely focusing on surface metal sites, the isolated Cr1(OH)x could provide unique oxygen species for accelerating hydrogen or CO spillover from Ru to Cr1(OH)x. Furthermore, the original oxygen species from Cr1(OH)x are confirmed to participate in hydrogen oxidation and H2O formation. The incorporation of such atomically isolated metal hydroxide clusters in heterostructured catalysts opens up new opportunities for rationally designing advanced electrocatalysts for HOR and other complex electrochemical reactions. This work also highlights the importance of size effect of co-catalysts, which should also be paid substantial attention to in the catalysis field.

Suggested Citation

  • Bingxing Zhang & Baohua Zhang & Guoqiang Zhao & Jianmei Wang & Danqing Liu & Yaping Chen & Lixue Xia & Mingxia Gao & Yongfeng Liu & Wenping Sun & Hongge Pan, 2022. "Atomically dispersed chromium coordinated with hydroxyl clusters enabling efficient hydrogen oxidation on ruthenium," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33625-x
    DOI: 10.1038/s41467-022-33625-x
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    1. Yu Duan & Zi-You Yu & Li Yang & Li-Rong Zheng & Chu-Tian Zhang & Xiao-Tu Yang & Fei-Yue Gao & Xiao-Long Zhang & Xingxing Yu & Ren Liu & Hong-He Ding & Chao Gu & Xu-Sheng Zheng & Lei Shi & Jun Jiang & , 2020. "Bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    2. Fuzhan Song & Wei Li & Jiaqi Yang & Guanqun Han & Peilin Liao & Yujie Sun, 2018. "Interfacing nickel nitride and nickel boosts both electrocatalytic hydrogen evolution and oxidation reactions," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
    3. Jiayuan Li & Jun Hu & Mingkai Zhang & Wangyan Gou & Sai Zhang & Zhong Chen & Yongquan Qu & Yuanyuan Ma, 2021. "A fundamental viewpoint on the hydrogen spillover phenomenon of electrocatalytic hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    4. Hong Bin Yang & Sung-Fu Hung & Song Liu & Kaidi Yuan & Shu Miao & Liping Zhang & Xiang Huang & Hsin-Yi Wang & Weizheng Cai & Rong Chen & Jiajian Gao & Xiaofeng Yang & Wei Chen & Yanqiang Huang & Hao M, 2018. "Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction," Nature Energy, Nature, vol. 3(2), pages 140-147, February.
    5. Yanrong Xue & Lin Shi & Xuerui Liu & Jinjie Fang & Xingdong Wang & Brian P. Setzler & Wei Zhu & Yushan Yan & Zhongbin Zhuang, 2020. "A highly-active, stable and low-cost platinum-free anode catalyst based on RuNi for hydroxide exchange membrane fuel cells," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    6. Isis Ledezma-Yanez & W. David Z. Wallace & Paula Sebastián-Pascual & Victor Climent & Juan M. Feliu & Marc T. M. Koper, 2017. "Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes," Nature Energy, Nature, vol. 2(4), pages 1-7, April.
    7. Shuai Qin & Yu Duan & Xiao-Long Zhang & Li-Rong Zheng & Fei-Yue Gao & Peng-Peng Yang & Zhuang-Zhuang Niu & Ren Liu & Yu Yang & Xu-Sheng Zheng & Jun-Fa Zhu & Min-Rui Gao, 2021. "Ternary nickel–tungsten–copper alloy rivals platinum for catalyzing alkaline hydrogen oxidation," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    8. Wenchao Sheng & Zhongbin Zhuang & Minrui Gao & Jie Zheng & Jingguang G. Chen & Yushan Yan, 2015. "Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy," Nature Communications, Nature, vol. 6(1), pages 1-6, May.
    9. Woong Hee Lee & Man Ho Han & Young-Jin Ko & Byoung Koun Min & Keun Hwa Chae & Hyung-Suk Oh, 2022. "Electrode reconstruction strategy for oxygen evolution reaction: maintaining Fe-CoOOH phase with intermediate-spin state during electrolysis," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
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    1. Yanyan Fang & Cong Wei & Zenan Bian & Xuanwei Yin & Bo Liu & Zhaohui Liu & Peng Chi & Junxin Xiao & Wanjie Song & Shuwen Niu & Chongyang Tang & Jun Liu & Xiaolin Ge & Tongwen Xu & Gongming Wang, 2024. "Unveiling the nature of Pt-induced anti-deactivation of Ru for alkaline hydrogen oxidation reaction," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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