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Movable type printing method to synthesize high-entropy single-atom catalysts

Author

Listed:
  • Peng Rao

    (Hainan University)

  • Yijie Deng

    (University of South China)

  • Wenjun Fan

    (Chinese Academy of Sciences)

  • Junming Luo

    (Hainan University)

  • Peilin Deng

    (Hainan University)

  • Jing Li

    (Hainan University)

  • Yijun Shen

    (Hainan University)

  • Xinlong Tian

    (Hainan University)

Abstract

The controllable anchoring of multiple isolated metal atoms into a single support exhibits scientific and technological opportunities, while the synthesis of catalysts with multiple single metal atoms remains a challenge and has been rarely reported. Herein, we present a general route for anchoring up to eleven metals as highly dispersed single-atom centers on porous nitride-doped carbon supports with the developed movable type printing method, and label them as high-entropy single-atom catalysts. Various high-entropy single-atom catalysts with tunable multicomponent are successfully synthesized with the same method by adjusting only the printing templates and carbonization parameters. To prove utility, quinary high-entropy single-atom catalysts (FeCoNiCuMn) is investigated as oxygen reduction reaction catalyst with much more positive activity and durability than commercial Pt/C catalyst. This work broadens the family of single-atom catalysts and opens a way to investigate highly efficient single-atom catalysts with multiple compositions.

Suggested Citation

  • Peng Rao & Yijie Deng & Wenjun Fan & Junming Luo & Peilin Deng & Jing Li & Yijun Shen & Xinlong Tian, 2022. "Movable type printing method to synthesize high-entropy single-atom catalysts," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32850-8
    DOI: 10.1038/s41467-022-32850-8
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    1. Laihao Luo & Jie Luo & Hongliang Li & Fangning Ren & Yifei Zhang & Andong Liu & Wei-Xue Li & Jie Zeng, 2021. "Water enables mild oxidation of methane to methanol on gold single-atom catalysts," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    2. Haisheng Wei & Xiaoyan Liu & Aiqin Wang & Leilei Zhang & Botao Qiao & Xiaofeng Yang & Yanqiang Huang & Shu Miao & Jingyue Liu & Tao Zhang, 2014. "FeOx-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes," Nature Communications, Nature, vol. 5(1), pages 1-8, December.
    3. Huan Yan & Yue Lin & Hong Wu & Wenhua Zhang & Zhihu Sun & Hao Cheng & Wei Liu & Chunlei Wang & Junjie Li & Xiaohui Huang & Tao Yao & Jinlong Yang & Shiqiang Wei & Junling Lu, 2017. "Bottom-up precise synthesis of stable platinum dimers on graphene," Nature Communications, Nature, vol. 8(1), pages 1-11, December.
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    1. Junxiong Guo & Shuyi Gu & Lin Lin & Yu Liu & Ji Cai & Hongyi Cai & Yu Tian & Yuelin Zhang & Qinghua Zhang & Ze Liu & Yafei Zhang & Xiaosheng Zhang & Yuan Lin & Wen Huang & Lin Gu & Jinxing Zhang, 2024. "Type-printable photodetector arrays for multichannel meta-infrared imaging," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Xinyi Yang & Wanqing Song & Kang Liao & Xiaoyang Wang & Xin Wang & Jinfeng Zhang & Haozhi Wang & Yanan Chen & Ning Yan & Xiaopeng Han & Jia Ding & Wenbin Hu, 2024. "Cohesive energy discrepancy drives the fabrication of multimetallic atomically dispersed materials for hydrogen evolution reaction," Nature Communications, Nature, vol. 15(1), pages 1-14, December.

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