IDEAS home Printed from https://ideas.repec.org/a/nat/natene/v4y2019i5d10.1038_s41560-019-0372-8.html
   My bibliography  Save this article

Poly(aryl piperidinium) membranes and ionomers for hydroxide exchange membrane fuel cells

Author

Listed:
  • Junhua Wang

    (Department of Chemical and Biomolecular Engineering, University of Delaware)

  • Yun Zhao

    (Department of Chemical and Biomolecular Engineering, University of Delaware)

  • Brian P. Setzler

    (Department of Chemical and Biomolecular Engineering, University of Delaware)

  • Santiago Rojas-Carbonell

    (Department of Chemical and Biomolecular Engineering, University of Delaware)

  • Chaya Ben Yehuda

    (Elbit Systems Ltd, Caesarea Business and Industrial Park)

  • Alina Amel

    (Elbit Systems Ltd, Caesarea Business and Industrial Park)

  • Miles Page

    (Elbit Systems Ltd, Caesarea Business and Industrial Park)

  • Lan Wang

    (Department of Chemical and Biomolecular Engineering, University of Delaware)

  • Keda Hu

    (Department of Chemical and Biomolecular Engineering, University of Delaware)

  • Lin Shi

    (Department of Chemical and Biomolecular Engineering, University of Delaware)

  • Shimshon Gottesfeld

    (Department of Chemical and Biomolecular Engineering, University of Delaware)

  • Bingjun Xu

    (Department of Chemical and Biomolecular Engineering, University of Delaware)

  • Yushan Yan

    (Department of Chemical and Biomolecular Engineering, University of Delaware)

Abstract

One promising approach to reduce the cost of fuel cell systems is to develop hydroxide exchange membrane fuel cells (HEMFCs), which open up the possibility of platinum-group-metal-free catalysts and low-cost bipolar plates. However, scalable alkaline polyelectrolytes (hydroxide exchange membranes and hydroxide exchange ionomers), a key component of HEMFCs, with desired properties are currently unavailable, which presents a major barrier to the development of HEMFCs. Here we show hydroxide exchange membranes and hydroxide exchange ionomers based on poly(aryl piperidinium) (PAP) that simultaneously possess adequate ionic conductivity, chemical stability, mechanical robustness, gas separation and selective solubility. These properties originate from the combination of the piperidinium cation and the rigid ether-bond-free aryl backbone. A low-Pt membrane electrode assembly with a Ag-based cathode using PAP materials showed an excellent peak power density of 920 mW cm−2 and operated stably at a constant current density of 500 mA cm−2 for 300 h with H2/CO2-free air at 95 °C.

Suggested Citation

  • Junhua Wang & Yun Zhao & Brian P. Setzler & Santiago Rojas-Carbonell & Chaya Ben Yehuda & Alina Amel & Miles Page & Lan Wang & Keda Hu & Lin Shi & Shimshon Gottesfeld & Bingjun Xu & Yushan Yan, 2019. "Poly(aryl piperidinium) membranes and ionomers for hydroxide exchange membrane fuel cells," Nature Energy, Nature, vol. 4(5), pages 392-398, May.
    • Handle: RePEc:nat:natene:v:4:y:2019:i:5:d:10.1038_s41560-019-0372-8
    DOI: 10.1038/s41560-019-0372-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41560-019-0372-8
    File Function: Abstract
    Download Restriction: Access to the full text of the articles in this series is restricted.
    File URL: https://libkey.io/10.1038/s41560-019-0372-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Peimiao Zou & Dinu Iuga & Sanliang Ling & Alex J. Brown & Shigang Chen & Mengfei Zhang & Yisong Han & A. Dominic Fortes & Christopher M. Howard & Shanwen Tao, 2024. "A fast ceramic mixed OH−/H+ ionic conductor for low temperature fuel cells," Nature Communications, Nature, vol. 15(1), pages 1-20, December.
    2. Wanjie Song & Kang Peng & Wei Xu & Xiang Liu & Huaqing Zhang & Xian Liang & Bangjiao Ye & Hongjun Zhang & Zhengjin Yang & Liang Wu & Xiaolin Ge & Tongwen Xu, 2023. "Upscaled production of an ultramicroporous anion-exchange membrane enables long-term operation in electrochemical energy devices," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Xingdong Wang & Xuerui Liu & Jinjie Fang & Houpeng Wang & Xianwei Liu & Haiyong Wang & Chengjin Chen & Yongsheng Wang & Xuejiang Zhang & Wei Zhu & Zhongbin Zhuang, 2024. "Tuning the apparent hydrogen binding energy to achieve high-performance Ni-based hydrogen oxidation reaction catalyst," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Zhongliang Huang & Shengnan Hu & Mingzi Sun & Yong Xu & Shangheng Liu & Renjie Ren & Lin Zhuang & Ting-Shan Chan & Zhiwei Hu & Tianyi Ding & Jing Zhou & Liangbin Liu & Mingmin Wang & Yu-Cheng Huang & , 2024. "Implanting oxophilic metal in PtRu nanowires for hydrogen oxidation catalysis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Ziang Xu & Lei Wan & Yiwen Liao & Maobin Pang & Qin Xu & Peican Wang & Baoguo Wang, 2023. "Continuous ammonia electrosynthesis using physically interlocked bipolar membrane at 1000 mA cm−2," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    6. Zhe Jiang & Xuerui Liu & Xiao-Zhi Liu & Shuang Huang & Ying Liu & Ze-Cheng Yao & Yun Zhang & Qing-Hua Zhang & Lin Gu & Li-Rong Zheng & Li Li & Jianan Zhang & Youjun Fan & Tang Tang & Zhongbin Zhuang &, 2023. "Interfacial assembly of binary atomic metal-Nx sites for high-performance energy devices," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    7. Qinglu Liu & Tang Tang & Ziyu Tian & Shiwen Ding & Linqin Wang & Dexin Chen & Zhiwei Wang & Wentao Zheng & Husileng Lee & Xingyu Lu & Xiaohe Miao & Lin Liu & Licheng Sun, 2024. "A high-performance watermelon skin ion-solvating membrane for electrochemical CO2 reduction," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    8. Xiaoning Wang & Lianming Zhao & Xuejin Li & Yong Liu & Yesheng Wang & Qiaofeng Yao & Jianping Xie & Qingzhong Xue & Zifeng Yan & Xun Yuan & Wei Xing, 2022. "Atomic-precision Pt6 nanoclusters for enhanced hydrogen electro-oxidation," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    9. Gumaa A. El-Nagar & Flora Haun & Siddharth Gupta & Sasho Stojkovikj & Matthew T. Mayer, 2023. "Unintended cation crossover influences CO2 reduction selectivity in Cu-based zero-gap electrolysers," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Yanyan Fang & Cong Wei & Zenan Bian & Xuanwei Yin & Bo Liu & Zhaohui Liu & Peng Chi & Junxin Xiao & Wanjie Song & Shuwen Niu & Chongyang Tang & Jun Liu & Xiaolin Ge & Tongwen Xu & Gongming Wang, 2024. "Unveiling the nature of Pt-induced anti-deactivation of Ru for alkaline hydrogen oxidation reaction," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    11. Yuhua Xia & Mengzheng Ouyang & Vladimir Yufit & Rui Tan & Anna Regoutz & Anqi Wang & Wenjie Mao & Barun Chakrabarti & Ashkan Kavei & Qilei Song & Anthony R. Kucernak & Nigel P. Brandon, 2022. "A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture," Nature Communications, Nature, vol. 13(1), pages 1-13, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natene:v:4:y:2019:i:5:d:10.1038_s41560-019-0372-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.