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Unveiling the nature of Pt-induced anti-deactivation of Ru for alkaline hydrogen oxidation reaction

Author

Listed:
  • Yanyan Fang

    (University of Science and Technology of China)

  • Cong Wei

    (University of Science and Technology of China)

  • Zenan Bian

    (University of Science and Technology of China)

  • Xuanwei Yin

    (University of Science and Technology of China)

  • Bo Liu

    (University of Science and Technology of China)

  • Zhaohui Liu

    (University of Science and Technology of China)

  • Peng Chi

    (University of Science and Technology of China)

  • Junxin Xiao

    (University of Science and Technology of China)

  • Wanjie Song

    (University of Science and Technology of China)

  • Shuwen Niu

    (University of Science and Technology of China)

  • Chongyang Tang

    (University of Science and Technology of China)

  • Jun Liu

    (Chinese Academy of Sciences)

  • Xiaolin Ge

    (University of Science and Technology of China)

  • Tongwen Xu

    (University of Science and Technology of China)

  • Gongming Wang

    (University of Science and Technology of China)

Abstract

While Ru owns superior catalytic activity toward hydrogen oxidation reaction and cost advantages, the catalyst deactivation under high anodic potential range severely limits its potential to replace the Pt benchmark catalyst. Unveiling the deactivation mechanism of Ru and correspondingly developing protection strategies remain a great challenge. Herein, we develop atomic Pt-functioned Ru nanoparticles with excellent anti-deactivation feature and meanwhile employ advanced operando characterization tools to probe the underlying roles of Pt in the anti-deactivation. Our studies reveal the introduced Pt single atoms effectively prevent Ru from oxidative passivation and consequently preserve the interfacial water network for the critical H* oxidative release during catalysis. Clearly understanding the deactivation nature of Ru and Pt-induced anti-deactivation under atomic levels could provide valuable insights for rationally designing stable Ru-based catalysts for hydrogen oxidation reaction and beyond.

Suggested Citation

  • Yanyan Fang & Cong Wei & Zenan Bian & Xuanwei Yin & Bo Liu & Zhaohui Liu & Peng Chi & Junxin Xiao & Wanjie Song & Shuwen Niu & Chongyang Tang & Jun Liu & Xiaolin Ge & Tongwen Xu & Gongming Wang, 2024. "Unveiling the nature of Pt-induced anti-deactivation of Ru for alkaline hydrogen oxidation reaction," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45873-0
    DOI: 10.1038/s41467-024-45873-0
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    1. Yu Duan & Zi-You Yu & Li Yang & Li-Rong Zheng & Chu-Tian Zhang & Xiao-Tu Yang & Fei-Yue Gao & Xiao-Long Zhang & Xingxing Yu & Ren Liu & Hong-He Ding & Chao Gu & Xu-Sheng Zheng & Lei Shi & Jun Jiang & , 2020. "Bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    2. Junhua Wang & Yun Zhao & Brian P. Setzler & Santiago Rojas-Carbonell & Chaya Ben Yehuda & Alina Amel & Miles Page & Lan Wang & Keda Hu & Lin Shi & Shimshon Gottesfeld & Bingjun Xu & Yushan Yan, 2019. "Poly(aryl piperidinium) membranes and ionomers for hydroxide exchange membrane fuel cells," Nature Energy, Nature, vol. 4(5), pages 392-398, May.
    3. Yanrong Xue & Lin Shi & Xuerui Liu & Jinjie Fang & Xingdong Wang & Brian P. Setzler & Wei Zhu & Yushan Yan & Zhongbin Zhuang, 2020. "A highly-active, stable and low-cost platinum-free anode catalyst based on RuNi for hydroxide exchange membrane fuel cells," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    4. Isis Ledezma-Yanez & W. David Z. Wallace & Paula Sebastián-Pascual & Victor Climent & Juan M. Feliu & Marc T. M. Koper, 2017. "Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes," Nature Energy, Nature, vol. 2(4), pages 1-7, April.
    5. Juntao Zhang & Xiaozhi Liu & Yujin Ji & Xuerui Liu & Dong Su & Zhongbin Zhuang & Yu-Chung Chang & Chih-Wen Pao & Qi Shao & Zhiwei Hu & Xiaoqing Huang, 2023. "Atomic-thick metastable phase RhMo nanosheets for hydrogen oxidation catalysis," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Qi Hu & Keru Gao & Xiaodeng Wang & Hongju Zheng & Jianyong Cao & Lingren Mi & Qihua Huo & Hengpan Yang & Jianhong Liu & Chuanxin He, 2022. "Subnanometric Ru clusters with upshifted D band center improve performance for alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Bingxing Zhang & Baohua Zhang & Guoqiang Zhao & Jianmei Wang & Danqing Liu & Yaping Chen & Lixue Xia & Mingxia Gao & Yongfeng Liu & Wenping Sun & Hongge Pan, 2022. "Atomically dispersed chromium coordinated with hydroxyl clusters enabling efficient hydrogen oxidation on ruthenium," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    8. Wanjie Song & Kang Peng & Wei Xu & Xiang Liu & Huaqing Zhang & Xian Liang & Bangjiao Ye & Hongjun Zhang & Zhengjin Yang & Liang Wu & Xiaolin Ge & Tongwen Xu, 2023. "Upscaled production of an ultramicroporous anion-exchange membrane enables long-term operation in electrochemical energy devices," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
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