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Reactivity Effects of Inorganic Content in Biomass Gasification: A Review

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  • Anna Trubetskaya

    (Department of Engineering, University of Limerick, Castletroy, V94 T9PX Limerick, Ireland)

Abstract

This review article discusses the effects of inorganic content and mechanisms on raw biomass and char during gasification. The impacts of the inherent inorganics and externally added inorganic compounds are summarized based on a literature search from the most recent 40 years. The TGA and larger-scale studies involving K-, Ca-, and Si-related mechanisms are critically reviewed with the aim of understanding the reaction mechanisms and kinetics. Differences between the reaction pathways of inorganic matter, and subsequent effects on the reactivity during gasification, are discussed. The present results illustrate the complexity of ash transformation phenomena, which have a strong impact on the design of gasifiers as well as further operation and process control. The impregnation and mixing of catalytic compounds into raw biomass are emphasized as a potential solution to avoid reactivity-related operational challenges during steam and CO 2 gasification. This review clearly identifies a gap in experimental knowledge at the micro and macro levels in the advanced modelling of inorganics transformation with respect to gasification reactivity.

Suggested Citation

  • Anna Trubetskaya, 2022. "Reactivity Effects of Inorganic Content in Biomass Gasification: A Review," Energies, MDPI, vol. 15(9), pages 1-36, April.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:9:p:3137-:d:801940
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    References listed on IDEAS

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    Cited by:

    1. Maximilian Robert Heinrich & André Herrmann & Andy Gradel & Marco Klemm & Tobias Plessing, 2023. "Extensive Experimental Characterization with Kinetic Data for the Gasification Simulation of Solid Biofuels," Energies, MDPI, vol. 16(6), pages 1-31, March.
    2. N., Mohammed Asheruddin & Shivapuji, Anand M. & Dasappa, Srinivasaiah, 2023. "Thermochemical conversion of millimeter-sized single char particle in steam dominated environments under varying temperature, reactant composition and flux—Experimental and numerical analysis," Energy, Elsevier, vol. 269(C).
    3. Gerrit Ralf Surup & Hamideh Kaffash & Yan Ma & Anna Trubetskaya & Johan Berg Pettersen & Merete Tangstad, 2022. "Life Cycle Based Climate Emissions of Charcoal Conditioning Routes for the Use in the Ferro-Alloy Production," Energies, MDPI, vol. 15(11), pages 1-28, May.
    4. Juraj Kukuruzović & Ana Matin & Mislav Kontek & Tajana Krička & Božidar Matin & Ivan Brandić & Alan Antonović, 2023. "The Effects of Demineralization on Reducing Ash Content in Corn and Soy Biomass with the Goal of Increasing Biofuel Quality," Energies, MDPI, vol. 16(2), pages 1-12, January.

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