IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v109y2013icp220-228.html
   My bibliography  Save this article

Investigation of the intrinsic CO2 gasification kinetics of biomass char at medium to high temperatures

Author

Listed:
  • Lin, Leteng
  • Strand, Michael

Abstract

In total eight char samples from pelletized wood, miscanthus, and straw were prepared under various pyrolysis conditions. The CO2 gasification kinetics for each sample was established in the temperature range from 800°C to 1300°C by the combination of thermogravimetric analysis (TGA) and a novel aerosol-based method. The aerosol-based method was used for the high temperature range between 1100°C and 1300°C, by gasifying suspended char particles (0.5–10μm) in an oxidizing carrier gas. A tapered element oscillating microbalance (TEOM) was used to measure the change of mass concentrations of particles in the carrier gas, before and after gasification. The results showed that the aerosol-based method could be used to investigate the intrinsic gasification kinetics of biomass char, at least up to 1300°C. All char samples showed similar reactivity in the low temperature range. However, above 1000°C there were significant differences in reactivity, and at 1300°C the conversion of the wood was in the order of 10 times faster than that of straw. The general char reactivity order in this study was wood>miscanthus>straw.

Suggested Citation

  • Lin, Leteng & Strand, Michael, 2013. "Investigation of the intrinsic CO2 gasification kinetics of biomass char at medium to high temperatures," Applied Energy, Elsevier, vol. 109(C), pages 220-228.
    • Handle: RePEc:eee:appene:v:109:y:2013:i:c:p:220-228
    DOI: 10.1016/j.apenergy.2013.04.027
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261913003218
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2013.04.027?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ahmed, I.I. & Gupta, A.K., 2011. "Kinetics of woodchips char gasification with steam and carbon dioxide," Applied Energy, Elsevier, vol. 88(5), pages 1613-1619, May.
    2. Kirkels, Arjan F. & Verbong, Geert P.J., 2011. "Biomass gasification: Still promising? A 30-year global overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 471-481, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Morgalla, Mario & Lin, Leteng & Strand, Michael, 2017. "Decomposition of benzene using char aerosol particles dispersed in a high-temperature filter," Energy, Elsevier, vol. 118(C), pages 1345-1352.
    2. Gao, Xiaoyan & Zhang, Yaning & Xu, Fei & Yin, Zhaoqin & Wang, Yingying & Bao, Fubing & Li, Bingxi, 2019. "Experimental and kinetic studies on the intrinsic reactivities of rice husk char," Renewable Energy, Elsevier, vol. 135(C), pages 608-616.
    3. Tian, Hong & Hu, Qingsong & Wang, Jiawei & Chen, Donglin & Yang, Yang & Bridgwater, Anthony V., 2021. "Kinetic study on the CO2 gasification of biochar derived from Miscanthus at different processing conditions," Energy, Elsevier, vol. 217(C).
    4. Wang, Guangwei & Zhang, Jianliang & Chang, Weiwei & Li, Rongpeng & Li, Yanjiang & Wang, Chuan, 2018. "Structural features and gasification reactivity of biomass chars pyrolyzed in different atmospheres at high temperature," Energy, Elsevier, vol. 147(C), pages 25-35.
    5. Moon, Hyeong-Bin & Lee, Ji-Hwan & Kim, Hyung-Tae & Lee, Jin-Wook & Lee, Byoung-Hwa & Jeon, Chung-Hwan, 2024. "Effect of high-pressure pyrolysis on syngas and char structure of petroleum coke," Energy, Elsevier, vol. 299(C).
    6. Wei, Juntao & Guo, Qinghua & Ding, Lu & Yoshikawa, Kunio & Yu, Guangsuo, 2017. "Synergy mechanism analysis of petroleum coke and municipal solid waste (MSW)-derived hydrochar co-gasification," Applied Energy, Elsevier, vol. 206(C), pages 1354-1363.
    7. Ghulamullah Maitlo & Imran Ali & Kashif Hussain Mangi & Safdar Ali & Hubdar Ali Maitlo & Imran Nazir Unar & Abdul Majeed Pirzada, 2022. "Thermochemical Conversion of Biomass for Syngas Production: Current Status and Future Trends," Sustainability, MDPI, vol. 14(5), pages 1-30, February.
    8. Chaiwatanodom, Paphonwit & Vivanpatarakij, Supawat & Assabumrungrat, Suttichai, 2014. "Thermodynamic analysis of biomass gasification with CO2 recycle for synthesis gas production," Applied Energy, Elsevier, vol. 114(C), pages 10-17.
    9. Shengguo Zhao & Liang Ding & Yun Ruan & Bin Bai & Zegang Qiu & Zhiqin Li, 2021. "Experimental and Kinetic Studies on Steam Gasification of a Biomass Char," Energies, MDPI, vol. 14(21), pages 1-23, November.
    10. Stoesser, P. & Schneider, C. & Kreitzberg, T. & Kneer, R. & Kolb, T., 2018. "On the influence of different experimental systems on measured heterogeneous gasification kinetics," Applied Energy, Elsevier, vol. 211(C), pages 582-589.
    11. Anna Trubetskaya, 2022. "Reactivity Effects of Inorganic Content in Biomass Gasification: A Review," Energies, MDPI, vol. 15(9), pages 1-36, April.
    12. Pallarés Ranz, Javier & Gil, Antonia & Cortés, Cristóbal & Arauzo, Inmaculada, 2024. "Modeling of the evolution of the porous structure during a physical activation process for the production of activated biocarbon: A novel low conversion approach," Renewable Energy, Elsevier, vol. 224(C).
    13. Salem, Ahmed M. & Elsherbiny, Khaled, 2022. "Innovative concept for the effect of changing gasifying medium and injection points on syngas quality: Towards higher H2 production, and Free-CO2 emissions," Energy, Elsevier, vol. 261(PB).
    14. Lopez, Gartzen & Alvarez, Jon & Amutio, Maider & Arregi, Aitor & Bilbao, Javier & Olazar, Martin, 2016. "Assessment of steam gasification kinetics of the char from lignocellulosic biomass in a conical spouted bed reactor," Energy, Elsevier, vol. 107(C), pages 493-501.
    15. Elsaddik, Majd & Nzihou, Ange & Delmas, Michel & Delmas, Guo-Hua, 2023. "Steam gasification of cellulose pulp char: Insights on experimental and kinetic study with a focus on the role of Silicon," Energy, Elsevier, vol. 271(C).
    16. Bach-Oller, Albert & Furusjö, Erik & Umeki, Kentaro, 2019. "On the role of potassium as a tar and soot inhibitor in biomass gasification," Applied Energy, Elsevier, vol. 254(C).
    17. Salem, Ahmed M. & Abd Elbar, Ayman Refat, 2023. "The feasibility and performance of using producer gas as a gasifying medium," Energy, Elsevier, vol. 283(C).
    18. Lahijani, Pooya & Zainal, Zainal Alimuddin & Mohammadi, Maedeh & Mohamed, Abdul Rahman, 2015. "Conversion of the greenhouse gas CO2 to the fuel gas CO via the Boudouard reaction: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 615-632.
    19. Wu, Ruochen & Beutler, Jacob & Baxter, Larry L., 2023. "Biomass char gasification kinetic rates compared to data, including ash effects," Energy, Elsevier, vol. 266(C).
    20. Sun, Zhao & Russell, Christopher K. & Fan, Maohong, 2021. "Effect of calcium ferrites on carbon dioxide gasification reactivity and kinetics of pine wood derived char," Renewable Energy, Elsevier, vol. 163(C), pages 445-452.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ghulamullah Maitlo & Imran Ali & Kashif Hussain Mangi & Safdar Ali & Hubdar Ali Maitlo & Imran Nazir Unar & Abdul Majeed Pirzada, 2022. "Thermochemical Conversion of Biomass for Syngas Production: Current Status and Future Trends," Sustainability, MDPI, vol. 14(5), pages 1-30, February.
    2. Kotowicz, Janusz & Sobolewski, Aleksander & Iluk, Tomasz, 2013. "Energetic analysis of a system integrated with biomass gasification," Energy, Elsevier, vol. 52(C), pages 265-278.
    3. Zhang, Ziyin & Pang, Shusheng & Levi, Tana, 2017. "Influence of AAEM species in coal and biomass on steam co-gasification of chars of blended coal and biomass," Renewable Energy, Elsevier, vol. 101(C), pages 356-363.
    4. Sérgio Ferreira & Eliseu Monteiro & Luís Calado & Valter Silva & Paulo Brito & Cândida Vilarinho, 2019. "Experimental and Modeling Analysis of Brewers´ Spent Grains Gasification in a Downdraft Reactor," Energies, MDPI, vol. 12(23), pages 1-18, November.
    5. Hussain, C.M. Iftekhar & Norton, Brian & Duffy, Aidan, 2017. "Technological assessment of different solar-biomass systems for hybrid power generation in Europe," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P2), pages 1115-1129.
    6. Prabowo, Bayu & Aziz, Muhammad & Umeki, Kentaro & Susanto, Herri & Yan, Mi & Yoshikawa, Kunio, 2015. "CO2-recycling biomass gasification system for highly efficient and carbon-negative power generation," Applied Energy, Elsevier, vol. 158(C), pages 97-106.
    7. Eksi, Guner & Karaosmanoglu, Filiz, 2017. "Combined bioheat and biopower: A technology review and an assessment for Turkey," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 1313-1332.
    8. Sharma, Monikankana & N, Rakesh & Dasappa, S., 2016. "Solid oxide fuel cell operating with biomass derived producer gas: Status and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 450-463.
    9. Salem, Ahmed M. & Abd Elbar, Ayman Refat, 2023. "The feasibility and performance of using producer gas as a gasifying medium," Energy, Elsevier, vol. 283(C).
    10. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part II," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1446-1466.
    11. Pérez-Fortes, Mar & Laínez-Aguirre, José Miguel & Arranz-Piera, Pol & Velo, Enrique & Puigjaner, Luis, 2012. "Design of regional and sustainable bio-based networks for electricity generation using a multi-objective MILP approach," Energy, Elsevier, vol. 44(1), pages 79-95.
    12. Chadwick, Dara T. & McDonnell, Kevin P. & Brennan, Liam P. & Fagan, Colette C. & Everard, Colm D., 2014. "Evaluation of infrared techniques for the assessment of biomass and biofuel quality parameters and conversion technology processes: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 672-681.
    13. Anna Trubetskaya, 2022. "Reactivity Effects of Inorganic Content in Biomass Gasification: A Review," Energies, MDPI, vol. 15(9), pages 1-36, April.
    14. Pio, D.T. & Tarelho, L.A.C., 2021. "Industrial gasification systems (>3 MWth) for bioenergy in Europe: Current status and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    15. Ahmed, I.I. & Gupta, A.K., 2013. "Experiments and stochastic simulations of lignite coal during pyrolysis and gasification," Applied Energy, Elsevier, vol. 102(C), pages 355-363.
    16. Howaniec, Natalia & Smoliński, Adam, 2017. "Biowaste utilization in the process of co-gasification with bituminous coal and lignite," Energy, Elsevier, vol. 118(C), pages 18-23.
    17. Guan, Guoqing & Kaewpanha, Malinee & Hao, Xiaogang & Abudula, Abuliti, 2016. "Catalytic steam reforming of biomass tar: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 450-461.
    18. Guan, JianCheng & Zhang, JingJing, 2018. "The dynamics of partner and knowledge portfolios in alternative energy field," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2869-2879.
    19. Ruiz, J.A. & Juárez, M.C. & Morales, M.P. & Muñoz, P. & Mendívil, M.A., 2013. "Biomass gasification for electricity generation: Review of current technology barriers," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 174-183.
    20. Dahou, T. & Defoort, F. & Khiari, B. & Labaki, M. & Dupont, C. & Jeguirim, M., 2021. "Role of inorganics on the biomass char gasification reactivity: A review involving reaction mechanisms and kinetics models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:109:y:2013:i:c:p:220-228. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.