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Role of inorganics on the biomass char gasification reactivity: A review involving reaction mechanisms and kinetics models

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  • Dahou, T.
  • Defoort, F.
  • Khiari, B.
  • Labaki, M.
  • Dupont, C.
  • Jeguirim, M.

Abstract

This review article presents the effects of the inorganic elements and compounds on gasification and their mechanisms of action. The influence of inorganics on the gasification reaction have been described in the literature. However, the specific phenomena involved and the mechanisms of action are not stated with consensus. Therefore, the present review gathers the various mechanisms proposed by authors. Some have been demonstrated to be unlikely such as the mechanisms involving intercalation compounds or mechanical actions. In order to give more practical applications of this work, the review also gathers the gasification kinetic models that take these inorganic effects into account.

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  • Dahou, T. & Defoort, F. & Khiari, B. & Labaki, M. & Dupont, C. & Jeguirim, M., 2021. "Role of inorganics on the biomass char gasification reactivity: A review involving reaction mechanisms and kinetics models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    • Handle: RePEc:eee:rensus:v:135:y:2021:i:c:s1364032120304275
    DOI: 10.1016/j.rser.2020.110136
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    3. Krzysztof M. Czajka, 2021. "Gasification of Coal by CO 2 : The Impact of the Heat Transfer Limitation on the Progress, Reaction Rate and Kinetics of the Process," Energies, MDPI, vol. 14(17), pages 1-22, September.
    4. Yao, Xin & Liu, Yang & Yu, Qingbo & Wang, Shuhuan, 2023. "Energy consumption of two-stage system of biomass pyrolysis and bio-oil reforming to recover waste heat from granulated BF slag," Energy, Elsevier, vol. 273(C).
    5. Elsaddik, Majd & Nzihou, Ange & Delmas, Michel & Delmas, Guo-Hua, 2023. "Steam gasification of cellulose pulp char: Insights on experimental and kinetic study with a focus on the role of Silicon," Energy, Elsevier, vol. 271(C).
    6. Baath, Yuvraj Singh & Nikrityuk, Petr A. & Gupta, Rajender, 2022. "Experimental and numerical verifications of biochar gasification kinetics using TGA," Renewable Energy, Elsevier, vol. 185(C), pages 717-733.
    7. Ibrahim, A. & Veremieiev, S. & Gaskell, P.H., 2022. "An advanced, comprehensive thermochemical equilibrium model of a downdraft biomass gasifier," Renewable Energy, Elsevier, vol. 194(C), pages 912-925.
    8. Zhang, Jinchun & Hou, Jinxiu & Zhang, Zichuan, 2022. "Real-time identification of out-of-control and instability in process parameter for gasification process: Integrated application of control chart and kalman filter," Energy, Elsevier, vol. 238(PB).

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