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Potential Liquid-Organic Hydrogen Carrier (LOHC) Systems: A Review on Recent Progress

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  • Purna Chandra Rao

    (Department of Chemistry & Green-Nano Materials Research Center, Kyungpook National University, Daegu 41566, Korea)

  • Minyoung Yoon

    (Department of Chemistry & Green-Nano Materials Research Center, Kyungpook National University, Daegu 41566, Korea)

Abstract

The depletion of fossil fuels and rising global warming challenges encourage to find safe and viable energy storage and delivery technologies. Hydrogen is a clean, efficient energy carrier in various mobile fuel-cell applications and owned no adverse effects on the environment and human health. However, hydrogen storage is considered a bottleneck problem for the progress of the hydrogen economy. Liquid-organic hydrogen carriers (LOHCs) are organic substances in liquid or semi-solid states that store hydrogen by catalytic hydrogenation and dehydrogenation processes over multiple cycles and may support a future hydrogen economy. Remarkably, hydrogen storage in LOHC systems has attracted dramatically more attention than conventional storage systems, such as high-pressure compression, liquefaction, and absorption/adsorption techniques. Potential LOHC media must provide fully reversible hydrogen storage via catalytic processes, thermal stability, low melting points, favorable hydrogenation thermodynamics and kinetics, large-scale availability, and compatibility with current fuel energy infrastructure to practically employ these molecules in various applications. In this review, we present various considerable aspects for the development of ideal LOHC systems. We highlight the recent progress of LOHC candidates and their catalytic approach, as well as briefly discuss the theoretical insights for understanding the reaction mechanism.

Suggested Citation

  • Purna Chandra Rao & Minyoung Yoon, 2020. "Potential Liquid-Organic Hydrogen Carrier (LOHC) Systems: A Review on Recent Progress," Energies, MDPI, vol. 13(22), pages 1-23, November.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:22:p:6040-:d:447474
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    References listed on IDEAS

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    1. Daniel Forberg & Tobias Schwob & Muhammad Zaheer & Martin Friedrich & Nobuyoshi Miyajima & Rhett Kempe, 2016. "Single-catalyst high-weight% hydrogen storage in an N-heterocycle synthesized from lignin hydrogenolysis products and ammonia," Nature Communications, Nature, vol. 7(1), pages 1-6, December.
    2. Eypasch, Martin & Schimpe, Michael & Kanwar, Aastha & Hartmann, Tobias & Herzog, Simon & Frank, Torsten & Hamacher, Thomas, 2017. "Model-based techno-economic evaluation of an electricity storage system based on Liquid Organic Hydrogen Carriers," Applied Energy, Elsevier, vol. 185(P1), pages 320-330.
    3. Haupt, Axel & Müller, Karsten, 2017. "Integration of a LOHC storage into a heat-controlled CHP system," Energy, Elsevier, vol. 118(C), pages 1123-1130.
    4. Saxena, R.C. & Seal, Diptendu & Kumar, Satinder & Goyal, H.B., 2008. "Thermo-chemical routes for hydrogen rich gas from biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(7), pages 1909-1927, September.
    5. Teichmann, Daniel & Stark, Katharina & Müller, Karsten & Zöttl, Gregor & Wasserscheid, Peter & Arlt, Wolfgang, 2012. "Energy storage in residential and commercial buildings via Liquid Organic Hydrogen Carriers (LOHC)," Munich Reprints in Economics 18079, University of Munich, Department of Economics.
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