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Performance Analysis of the Perhydro-Dibenzyl-Toluene Dehydrogenation System—A Simulation Study

Author

Listed:
  • Farea Asif

    (Department of Chemical Engineering, COMSATS University Islamabad, Lahore Campus, Defence Road, Off Raiwind Road, Lahore 54000, Pakistan)

  • Muhammad Haris Hamayun

    (Department of Chemical Engineering, COMSATS University Islamabad, Lahore Campus, Defence Road, Off Raiwind Road, Lahore 54000, Pakistan)

  • Murid Hussain

    (Department of Chemical Engineering, COMSATS University Islamabad, Lahore Campus, Defence Road, Off Raiwind Road, Lahore 54000, Pakistan)

  • Arif Hussain

    (Department of Chemical Engineering, COMSATS University Islamabad, Lahore Campus, Defence Road, Off Raiwind Road, Lahore 54000, Pakistan)

  • Ibrahim M. Maafa

    (Department of Chemical Engineering, College of Engineering, Jazan University, Jazan 45142, Saudi Arabia)

  • Young-Kwon Park

    (School of Environmental Engineering, University of Seoul, Dongdaemun-Gu 02504, Korea)

Abstract

The depletion of conventional energy resources has drawn the world’s attention towards the use of alternate energy resources, which are not only efficient but sustainable as well. For this purpose, hydrogen is considered the fuel of the future. Liquid organic hydrogen carriers (LOHCs) have proved themselves as a potential option for the release and storage of hydrogen. The present study is aimed to analyze the performance of the perhydro-dibenzyl-toluene (PDBT) dehydrogenation system, for the release of hydrogen, under various operational conditions, i.e., temperature range of 270–320 °C, pressure range of 1–3 bar, and various platinum/palladium-based catalysts. For the operational system, the optimum operating conditions selected are 320 °C and 2 bar, and 2 wt. % Pt/Al 2 O 3 as a suitable catalyst. The configuration is analyzed based on exergy analysis i.e., % exergy efficiency, and exergy destruction rate (kW), and two optimization strategies are developed using principles of process integration. Based on exergy analysis, strategy # 2, where the product’s heat is utilized to preheat the feed, and utilities consumption is minimized, is selected as the most suitable option for the dehydrogenation system. The process is simulated and optimized using Aspen HYSYS ® V10.

Suggested Citation

  • Farea Asif & Muhammad Haris Hamayun & Murid Hussain & Arif Hussain & Ibrahim M. Maafa & Young-Kwon Park, 2021. "Performance Analysis of the Perhydro-Dibenzyl-Toluene Dehydrogenation System—A Simulation Study," Sustainability, MDPI, vol. 13(11), pages 1-14, June.
    • Handle: RePEc:gam:jsusta:v:13:y:2021:i:11:p:6490-:d:570337
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    References listed on IDEAS

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    1. Purna Chandra Rao & Minyoung Yoon, 2020. "Potential Liquid-Organic Hydrogen Carrier (LOHC) Systems: A Review on Recent Progress," Energies, MDPI, vol. 13(22), pages 1-23, November.
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    1. Hoang, Anh Tuan & Pandey, Ashok & Martinez De Osés, Francisco Javier & Chen, Wei-Hsin & Said, Zafar & Ng, Kim Hoong & Ağbulut, Ümit & Tarełko, Wiesław & Ölçer, Aykut I. & Nguyen, Xuan Phuong, 2023. "Technological solutions for boosting hydrogen role in decarbonization strategies and net-zero goals of world shipping: Challenges and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).

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