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Progress in Catalytic Hydrogen Production from Formic Acid over Supported Metal Complexes

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  • Dmitri A. Bulushev

    (Laboratory of Catalytic Methods of Solar Energy Transformation, Boreskov Institute of Catalysis, SB RAS, 630090 Novosibirsk, Russia)

Abstract

Formic acid is a liquid organic hydrogen carrier giving hydrogen on demand using catalysts. Metal complexes are known to be used as efficient catalysts for the hydrogen production from formic acid decomposition. Their performance could be better than those of supported catalysts with metal nanoparticles. However, difficulties to separate metal complexes from the reaction mixture limit their industrial applications. This problem can be resolved by supporting metal complexes on the surface of different supports, which may additionally provide some surface sites for the formic acid activation. The review analyzes the literature on the application of supported metal complexes in the hydrogen production from formic acid. It shows that the catalytic activity of some stable Ru and Ir supported metal complexes may exceed the activity of homogeneous metal complexes used for deposition. Non-noble metal-based complexes containing Fe demonstrated sufficiently high performance in the reaction; however, they can be poisoned by water present in formic acid. The proposed review could be useful for development of novel catalysts for the hydrogen production.

Suggested Citation

  • Dmitri A. Bulushev, 2021. "Progress in Catalytic Hydrogen Production from Formic Acid over Supported Metal Complexes," Energies, MDPI, vol. 14(5), pages 1-14, March.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:5:p:1334-:d:508227
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    References listed on IDEAS

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    1. Panagiota Stathi & Maria Solakidou & Maria Louloudi & Yiannis Deligiannakis, 2020. "From Homogeneous to Heterogenized Molecular Catalysts for H 2 Production by Formic Acid Dehydrogenation: Mechanistic Aspects, Role of Additives, and Co-Catalysts," Energies, MDPI, vol. 13(3), pages 1-25, February.
    2. Vladimir V. Chesnokov & Pavel P. Dik & Aleksandra S. Chichkan, 2020. "Formic Acid as a Hydrogen Donor for Catalytic Transformations of Tar," Energies, MDPI, vol. 13(17), pages 1-12, September.
    3. Purna Chandra Rao & Minyoung Yoon, 2020. "Potential Liquid-Organic Hydrogen Carrier (LOHC) Systems: A Review on Recent Progress," Energies, MDPI, vol. 13(22), pages 1-23, November.
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    Cited by:

    1. Ekaterina Matus & Olga Sukhova & Ilyas Ismagilov & Mikhail Kerzhentsev & Olga Stonkus & Zinfer Ismagilov, 2021. "Hydrogen Production through Autothermal Reforming of Ethanol: Enhancement of Ni Catalyst Performance via Promotion," Energies, MDPI, vol. 14(16), pages 1-16, August.
    2. Luyao Guo & Kaixuan Zhuge & Siyang Yan & Shiyi Wang & Jia Zhao & Saisai Wang & Panzhe Qiao & Jiaxu Liu & Xiaoling Mou & Hejun Zhu & Ziang Zhao & Li Yan & Ronghe Lin & Yunjie Ding, 2023. "Defect-driven nanostructuring of low-nuclearity Pt-Mo ensembles for continuous gas-phase formic acid dehydrogenation," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Gromov, Nikolay V. & Medvedeva, Tatiana B. & Lukoyanov, Ivan A. & Ogorodnikova, Olga L. & Panchenko, Valentina N. & Parmon, Valentin N. & Timofeeva, Maria N., 2024. "Hydrolysis-oxidation of starch to formic acid in the presence of vanadium-containing molybdophosphoric heteropoly acid (H3+xPMo12-xVxO40): Effect of acidity and vanadium content on the yield of formic," Renewable Energy, Elsevier, vol. 220(C).
    4. Xinchun Yang & Dmitri A. Bulushev & Jun Yang & Quan Zhang, 2022. "New Liquid Chemical Hydrogen Storage Technology," Energies, MDPI, vol. 15(17), pages 1-18, August.
    5. Dmitri A. Bulushev, 2021. "Advanced Catalysis in Hydrogen Production from Formic Acid and Methanol," Energies, MDPI, vol. 14(20), pages 1-5, October.
    6. Davide Clematis & Daria Bellotti & Massimo Rivarolo & Loredana Magistri & Antonio Barbucci, 2023. "Hydrogen Carriers: Scientific Limits and Challenges for the Supply Chain, and Key Factors for Techno-Economic Analysis," Energies, MDPI, vol. 16(16), pages 1-31, August.

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