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Syngas evolutionary behavior during chicken manure pyrolysis and air gasification

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  • Burra, K.G.
  • Hussein, M.S.
  • Amano, R.S.
  • Gupta, A.K.

Abstract

The evolutionary behavior of syngas composition during the pyrolysis and gasification of chicken manure was examined at different temperatures and O2 concentrations. A gas chromatography was used to quantify the syngas evolved. Pure nitrogen was used for pyrolysis while two different oxygen concentrations (21% and 10%) in nitrogen were used for gasification. Five specific temperatures examined during pyrolysis and gasification were from 600 to 1000°C in steps of 100°C. Higher O2 concentration (21%) produced higher energy yields compared to lower O2 concentrations. Initial 8–10min yield produced CO2 dominant syngas from decarboxylation after which the compositions changed to equilibrium. High temperature and low O2 concentrations yielded higher CO flow rates and amounts. Equilibrium H2 content was reduced with an increase in O2 concentration due to the rapid oxidation of H2 in the presence of oxidative environment. CH4 was obtained from thermal cracking with its evolution being similar to that of other higher hydrocarbons evolved, albeit in smaller concentration.

Suggested Citation

  • Burra, K.G. & Hussein, M.S. & Amano, R.S. & Gupta, A.K., 2016. "Syngas evolutionary behavior during chicken manure pyrolysis and air gasification," Applied Energy, Elsevier, vol. 181(C), pages 408-415.
    • Handle: RePEc:eee:appene:v:181:y:2016:i:c:p:408-415
    DOI: 10.1016/j.apenergy.2016.08.095
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    2. Li, Jinhu & Burra, Kiran Raj G. & Wang, Zhiwei & Liu, Xuan & Gupta, Ashwani K., 2021. "Co-gasification of high-density polyethylene and pretreated pine wood," Applied Energy, Elsevier, vol. 285(C).
    3. Daya Shankar Pandey & Giannis Katsaros & Christian Lindfors & James J. Leahy & Savvas A. Tassou, 2019. "Fast Pyrolysis of Poultry Litter in a Bubbling Fluidised Bed Reactor: Energy and Nutrient Recovery," Sustainability, MDPI, vol. 11(9), pages 1-17, May.
    4. Burra, K.G. & Gupta, A.K., 2018. "Kinetics of synergistic effects in co-pyrolysis of biomass with plastic wastes," Applied Energy, Elsevier, vol. 220(C), pages 408-418.
    5. Xiaodong Pu & Mingdong Wei & Xiaopeng Chen & Linlin Wang & Liangwei Deng, 2022. "Thermal Decomposition Characteristics and Kinetic Analysis of Chicken Manure in Various Atmospheres," Agriculture, MDPI, vol. 12(5), pages 1-12, April.
    6. Burra, K.G. & Gupta, A.K., 2018. "Synergistic effects in steam gasification of combined biomass and plastic waste mixtures," Applied Energy, Elsevier, vol. 211(C), pages 230-236.
    7. Pasolini, Vinicius Holanda & Costa, Ariany Binda Silva & Perazzini, Maisa Tonon Bitti & Cipriano, Daniel Fernandes & Freitas, Jair Carlos Checon & Perazzini, Hugo & Sousa, Robson Costa, 2024. "Valorization of pure poultry manure for biomass applications: Drying and energy potential characteristics," Renewable Energy, Elsevier, vol. 220(C).
    8. Dmitry Porshnov, 2022. "Evolution of pyrolysis and gasification as waste to energy tools for low carbon economy," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 11(1), January.
    9. Fatma Abouelenien & Toyokazu Miura & Yutaka Nakashimada & Nooran S. Elleboudy & Mohammad S. Al-Harbi & Esmat F. Ali & Mustafa Shukry, 2021. "Optimization of Biomethane Production via Fermentation of Chicken Manure Using Marine Sediment: A Modeling Approach Using Response Surface Methodology," IJERPH, MDPI, vol. 18(22), pages 1-21, November.
    10. Xuejun Qian & Seong Lee & Ana-maria Soto & Guangming Chen, 2018. "Regression Model to Predict the Higher Heating Value of Poultry Waste from Proximate Analysis," Resources, MDPI, vol. 7(3), pages 1-14, June.
    11. Ng, Wei Cheng & You, Siming & Ling, Ran & Gin, Karina Yew-Hoong & Dai, Yanjun & Wang, Chi-Hwa, 2017. "Co-gasification of woody biomass and chicken manure: Syngas production, biochar reutilization, and cost-benefit analysis," Energy, Elsevier, vol. 139(C), pages 732-742.

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