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Design, economic evaluation, and market uncertainty analysis of LOHC-based, CO2 free, hydrogen delivery systems

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  • Brigljević, Boris
  • Byun, Manhee
  • Lim, Hankwon

Abstract

As the number of new candidates for liquid organic hydrogen carriers (LOHC) that are being identified and experimentally tested is increasing, so does the requirement to analytically evaluate large scale hydrogen delivery processes which will utilize these chemicals. Here, we detail a technological evaluation, cost estimation, and market performance analysis of a large-scale (1000 m3/h H2), CO2 emission-free, LOHC dehydrogenation system and the accompanying costs of supply logistics. Four reversible LOHC systems, Eutectic biphenyl/diphenylmethane mixture (EUT), 2-(N-Methylbenzyl)pyridine (MBP), N-phenylcarbazole (NPC), and N-ethylcarbazole (NEC) were evaluated in stand-alone cases, with the fifth case utilizing all four in a temperature-cascade (TC) process intensification. Total capital investments for this H2 output scale were found to range from 24 to 44 mil USD, with shipping cost and LOHC price determined to be main parameters affecting the process economics. Market performance results show that for the 3.5 USD/kg H2 selling price, the purchase prices of LOHC chemicals must be 5.44, 4.74, 4.01, 4.12 USD/kg for EUT, MBP, NPC and NEC respectively. Finally, the TC market operating and market performance was quantified and market conditions for justifiable investment in such a system were defined.

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  • Brigljević, Boris & Byun, Manhee & Lim, Hankwon, 2020. "Design, economic evaluation, and market uncertainty analysis of LOHC-based, CO2 free, hydrogen delivery systems," Applied Energy, Elsevier, vol. 274(C).
    • Handle: RePEc:eee:appene:v:274:y:2020:i:c:s0306261920308266
    DOI: 10.1016/j.apenergy.2020.115314
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    1. Daniel Forberg & Tobias Schwob & Muhammad Zaheer & Martin Friedrich & Nobuyoshi Miyajima & Rhett Kempe, 2016. "Single-catalyst high-weight% hydrogen storage in an N-heterocycle synthesized from lignin hydrogenolysis products and ammonia," Nature Communications, Nature, vol. 7(1), pages 1-6, December.
    2. Reuß, M. & Grube, T. & Robinius, M. & Preuster, P. & Wasserscheid, P. & Stolten, D., 2017. "Seasonal storage and alternative carriers: A flexible hydrogen supply chain model," Applied Energy, Elsevier, vol. 200(C), pages 290-302.
    3. Kalghatgi, Gautam, 2018. "Is it really the end of internal combustion engines and petroleum in transport?," Applied Energy, Elsevier, vol. 225(C), pages 965-974.
    4. Reuß, Markus & Grube, Thomas & Robinius, Martin & Stolten, Detlef, 2019. "A hydrogen supply chain with spatial resolution: Comparative analysis of infrastructure technologies in Germany," Applied Energy, Elsevier, vol. 247(C), pages 438-453.
    5. Wen, Chuang & Rogie, Brice & Kærn, Martin Ryhl & Rothuizen, Erasmus, 2020. "A first study of the potential of integrating an ejector in hydrogen fuelling stations for fuelling high pressure hydrogen vehicles," Applied Energy, Elsevier, vol. 260(C).
    6. Fikrt, André & Brehmer, Richard & Milella, Vito-Oronzo & Müller, Karsten & Bösmann, Andreas & Preuster, Patrick & Alt, Nicolas & Schlücker, Eberhard & Wasserscheid, Peter & Arlt, Wolfgang, 2017. "Dynamic power supply by hydrogen bound to a liquid organic hydrogen carrier," Applied Energy, Elsevier, vol. 194(C), pages 1-8.
    7. Runge, Philipp & Sölch, Christian & Albert, Jakob & Wasserscheid, Peter & Zöttl, Gregor & Grimm, Veronika, 2019. "Economic comparison of different electric fuels for energy scenarios in 2035," Applied Energy, Elsevier, vol. 233, pages 1078-1093.
    8. Eypasch, Martin & Schimpe, Michael & Kanwar, Aastha & Hartmann, Tobias & Herzog, Simon & Frank, Torsten & Hamacher, Thomas, 2017. "Model-based techno-economic evaluation of an electricity storage system based on Liquid Organic Hydrogen Carriers," Applied Energy, Elsevier, vol. 185(P1), pages 320-330.
    9. Juangsa, Firman Bagja & Prananto, Lukman Adi & Mufrodi, Zahrul & Budiman, Arief & Oda, Takuya & Aziz, Muhammad, 2018. "Highly energy-efficient combination of dehydrogenation of methylcyclohexane and hydrogen-based power generation," Applied Energy, Elsevier, vol. 226(C), pages 31-38.
    10. Cha, Junyoung & Jo, Young Suk & Jeong, Hyangsoo & Han, Jonghee & Nam, Suk Woo & Song, Kwang Ho & Yoon, Chang Won, 2018. "Ammonia as an efficient COX-free hydrogen carrier: Fundamentals and feasibility analyses for fuel cell applications," Applied Energy, Elsevier, vol. 224(C), pages 194-204.
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