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Sustainable synthesis of bio-diesel and jet-fuel range hydrocarbons from poisonous Abrus Precatorius seed oil over MoO3-HPW/Ga-KIT-6

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  • Gunasekaran, Vijayakumar
  • Gurusamy, Harichandran
  • Ravi, Ganesan
  • Rathinam, Yuvakkumar

Abstract

Energy problems and environmental deterioration can be combated by renewable biodiesel production from poisonous, waste, and non-edible oil seeds. Molybdenum oxide and phosphotungstic acid were impregnated into gallium-incorporated KIT-6 mesoporous silica employing a hydrothermal technique, to construct MoO3-HPW/Ga-KIT-6 catalyst. Abrus precatorius (Rosary Pea) seeds were utilized to extract non-edible oil, which was then submitted to a catalytic reaction with freshly prepared MoO3-HPW/Ga-KIT-6 for the synthesis of eco-friendly bio-diesel. An optimal biodiesel yield of 100% was reached from Abrus precatorius oil using MoO3(5)-HPW(10)/Ga (20)-KIT-6 catalyst at 6:1 methanol to oil molar ratio, 100 °C and 3 h reaction time. Oleic, linolenic, eicosapentaenoic, arachidic, and behenic acids were esterified under ideal conditions, and the 1H NMR spectroscopy revealed the result was an isolated methyl ester. Additionally, MoO3(5)-HPW(10)/Ga(20)-KIT-6 catalyst have been effectively produced C16–C18 range jet fuels from Abrus precatorius seed oil (APSO) and Abrus oil methyl ester (AOME) through the hydrodeoxygenation route at 400 °C, WHSV 2.7 h−1, 40 bar H2 pressure (62% of C18H38) and 400 °C, WHSV 1.8 h−1, 30 bar H2 pressure (67% of C18H38) respectively. The high dispersion of molybdenum and HPW on the Ga/KIT-6 catalyst and the more acidic centers, which promote the selectivity of the biodiesel and jet-fuel range hydrocarbons (JFRH), are credited with the good catalytic performance; this was demonstrated by HR-TEM and NH3-TPD (341 μmol/g) analyses.

Suggested Citation

  • Gunasekaran, Vijayakumar & Gurusamy, Harichandran & Ravi, Ganesan & Rathinam, Yuvakkumar, 2024. "Sustainable synthesis of bio-diesel and jet-fuel range hydrocarbons from poisonous Abrus Precatorius seed oil over MoO3-HPW/Ga-KIT-6," Renewable Energy, Elsevier, vol. 224(C).
    • Handle: RePEc:eee:renene:v:224:y:2024:i:c:s0960148124001952
    DOI: 10.1016/j.renene.2024.120130
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    References listed on IDEAS

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    1. Wei, Xiaocui & Cao, Yang & Li, Jin, 2022. "Synergistic effect of acid sites and a gallium-based modified meso-/microporous catalyst for the pyrolysis of biomass," Renewable Energy, Elsevier, vol. 191(C), pages 580-590.
    2. Mathimani, Thangavel & Uma, Lakshmanan & Prabaharan, Dharmar, 2015. "Homogeneous acid catalysed transesterification of marine microalga Chlorella sp. BDUG 91771 lipid – An efficient biodiesel yield and its characterization," Renewable Energy, Elsevier, vol. 81(C), pages 523-533.
    3. Zharova, P.A. & Chistyakov, A.V. & Shapovalov, S.S. & Pasynskii, A.A. & Tsodikov, M.V., 2019. "Original Pt-Sn/Al2O3 catalyst for selective hydrodeoxygenation of vegetable oils," Energy, Elsevier, vol. 172(C), pages 18-25.
    4. Salvi, B.L. & Panwar, N.L., 2012. "Biodiesel resources and production technologies – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3680-3689.
    5. Ramesh, Arumugam & Tamizhdurai, Perumal & Shanthi, Kannan, 2019. "Catalytic hydrodeoxygenation of jojoba oil to the green-fuel application on Ni-MoS/Mesoporous zirconia-silica catalysts," Renewable Energy, Elsevier, vol. 138(C), pages 161-173.
    6. Wang, Quan & Wenlei Xie, & Guo, Lihong, 2022. "Molybdenum and zirconium oxides supported on KIT-6 silica: A recyclable composite catalyst for one–pot biodiesel production from simulated low-quality oils," Renewable Energy, Elsevier, vol. 187(C), pages 907-922.
    7. Banković-Ilić, Ivana B. & Stamenković, Olivera S. & Veljković, Vlada B., 2012. "Biodiesel production from non-edible plant oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3621-3647.
    8. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2014. "Transesterification of crude Jatropha oil by activated carbon-supported heteropolyacid catalyst in an ultrasound-assisted reactor system," Renewable Energy, Elsevier, vol. 62(C), pages 10-17.
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