IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v80y2017icp1072-1088.html
   My bibliography  Save this article

Catalytic hydrodeoxygenation of triglycerides: An approach to clean diesel fuel production

Author

Listed:
  • Ameen, Mariam
  • Azizan, Mohammad Tazli
  • Yusup, Suzana
  • Ramli, Anita
  • Yasir, Madiha

Abstract

The catalytic upgrading of vegetable oil to green diesel is one of the distinct research subjects in biorefineries. The catalytic conversion of triglycerides entails the method of hydrotreating such as hydrogenation, hydrodeoxygenation, decarboxylation and decarbonylation as well as isomerization. The product derived is renewable green diesel (straight chain hydrocarbon), of which its production addresses the sustainability of the future energy. The main challenges faced by hydrodeoxygenation are the selection and synthesis of suitable catalysts, selection of appropriate feedstocks, optimization of the thermodynamic parameters, and the reaction pathways. The literature on the selection of feedstock and model compounds is discussed in the sub-section. This review also includes the evaluation on several potential catalysts such as bimetallic solid acid, sulphided, non-sulphided, nitrides, phosphided, isomerization and hydrocracking catalysts as well as the noble metal catalysts. The selection of the metal supports catalysts, the catalyst designed practice and the overall performance is also reviewed and discussed. The most common supports used for the hydrodeoxygenation is solid acid composites such as Al2O3 and zeolites. In addition, the promoters tested yield different results with different reaction mechanisms demonstrated. The research on the hydrodeoxygenation pathways and the product distribution related with all kinds of catalysts are also addressed. In addition, the advancement of co-hydroprocessing of mix-vegetable oil and vacuumed gas oil is addressed and summarized as well. Overall, this review provides a comprehensive discussion on the hydrodeoxygenation issues and challenges in all relevant technical aspects.

Suggested Citation

  • Ameen, Mariam & Azizan, Mohammad Tazli & Yusup, Suzana & Ramli, Anita & Yasir, Madiha, 2017. "Catalytic hydrodeoxygenation of triglycerides: An approach to clean diesel fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1072-1088.
    • Handle: RePEc:eee:rensus:v:80:y:2017:i:c:p:1072-1088
    DOI: 10.1016/j.rser.2017.05.268
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032117309048
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2017.05.268?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kim, Seok Ki & Han, Jae Young & Lee, Hong-shik & Yum, Taewoo & Kim, Yunje & Kim, Jaehoon, 2014. "Production of renewable diesel via catalytic deoxygenation of natural triglycerides: Comprehensive understanding of reaction intermediates and hydrocarbons," Applied Energy, Elsevier, vol. 116(C), pages 199-205.
    2. Bergthorson, Jeffrey M. & Thomson, Murray J., 2015. "A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1393-1417.
    3. Kandaramath Hari, Thushara & Yaakob, Zahira & Binitha, Narayanan N., 2015. "Aviation biofuel from renewable resources: Routes, opportunities and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1234-1244.
    4. Arun, Naveenji & Sharma, Rajesh V. & Dalai, Ajay K., 2015. "Green diesel synthesis by hydrodeoxygenation of bio-based feedstocks: Strategies for catalyst design and development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 240-255.
    5. Mohammad, Masita & Kandaramath Hari, Thushara & Yaakob, Zahira & Chandra Sharma, Yogesh & Sopian, Kamaruzzaman, 2013. "Overview on the production of paraffin based-biofuels via catalytic hydrodeoxygenation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 121-132.
    6. Calero, Juan & Luna, Diego & Sancho, Enrique D. & Luna, Carlos & Bautista, Felipa M. & Romero, Antonio A. & Posadillo, Alejandro & Berbel, Julio & Verdugo-Escamilla, Cristóbal, 2015. "An overview on glycerol-free processes for the production of renewable liquid biofuels, applicable in diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1437-1452.
    7. Hermida, Lilis & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2015. "Deoxygenation of fatty acid to produce diesel-like hydrocarbons: A review of process conditions, reaction kinetics and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1223-1233.
    8. Moniruzzaman, M. & Yaakob, Zahira & Khatun, Rahima, 2016. "Biotechnology for Jatropha improvement: A worthy exploration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1262-1277.
    9. Zhang, Huiming & Wang, Qunwei & Mortimer, Simon R., 2012. "Waste cooking oil as an energy resource: Review of Chinese policies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5225-5231.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    2. Ho, Calvin K. & McAuley, Kimberley B. & Peppley, Brant A., 2019. "Biolubricants through renewable hydrocarbons: A perspective for new opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    3. Wang, Fei & Pace, Robert & Ji, Yaying & Jiang, Jianchun & Jiang, Xiaoxiang & Krystianiak, Anna & Heintz, Olivier & Caboche, Gilles & Santillan-Jimenez, Eduardo & Crocker, Mark, 2022. "Effect of Pd promotion and catalyst support on the Ni-catalyzed deoxygenation of tristearin to fuel-like hydrocarbons," Renewable Energy, Elsevier, vol. 195(C), pages 1468-1479.
    4. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.
    5. Resende, K.A. & Noronha, F.B. & Hori, C.E., 2020. "Hydrodeoxygenation of phenol over metal supported niobia catalysts," Renewable Energy, Elsevier, vol. 149(C), pages 198-207.
    6. Główka, Marek & Wójcik, Jan & Boberski, Przemysław & Białecki, Tomasz & Gawron, Bartosz & Skolniak, Marta & Suchocki, Tomasz, 2024. "Sustainable aviation fuel – Comprehensive study on highly selective isomerization route towards HEFA based bioadditives," Renewable Energy, Elsevier, vol. 220(C).
    7. Ameen, Mariam & Azizan, Mohammad Tazli & Yusup, Suzana & Ramli, Anita & Shahbaz, Muhammad & Aqsha, Aqsha, 2020. "Process optimization of green diesel selectivity and understanding of reaction intermediates," Renewable Energy, Elsevier, vol. 149(C), pages 1092-1106.
    8. Barbera, Elena & Naurzaliyev, Rustem & Asiedu, Alexander & Bertucco, Alberto & Resurreccion, Eleazer P. & Kumar, Sandeep, 2020. "Techno-economic analysis and life-cycle assessment of jet fuels production from waste cooking oil via in situ catalytic transfer hydrogenation," Renewable Energy, Elsevier, vol. 160(C), pages 428-449.
    9. Chen, Yu-Kai & Lin, Cheng-Han & Wang, Wei-Cheng, 2020. "The conversion of biomass into renewable jet fuel," Energy, Elsevier, vol. 201(C).
    10. Burimsitthigul, Thikhamporn & Yoosuk, Boonyawan & Ngamcharussrivichai, Chawalit & Prasassarakich, Pattarapan, 2021. "Hydrocarbon biofuel from hydrotreating of palm oil over unsupported Ni–Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 163(C), pages 1648-1659.
    11. Oh, Shinyoung & Lee, Jae Hoon & Choi, Joon Weon, 2020. "Hydrodeoxygenation of crude bio-oil with various metal catalysts in a continuous-flow reactor and evaluation of emulsion properties of upgraded bio-oil with petroleum fuel," Renewable Energy, Elsevier, vol. 160(C), pages 1160-1167.
    12. Chen, Shuang & Zhou, Guilin & Miao, Caixia, 2019. "Green and renewable bio-diesel produce from oil hydrodeoxygenation: Strategies for catalyst development and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 568-589.
    13. Yoosuk, Boonyawan & Sanggam, Paphawee & Wiengket, Sakdipat & Prasassarakich, Pattarapan, 2019. "Hydrodeoxygenation of oleic acid and palmitic acid to hydrocarbon-like biofuel over unsupported Ni-Mo and Co-Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 139(C), pages 1391-1399.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    2. Ameen, Mariam & Azizan, Mohammad Tazli & Yusup, Suzana & Ramli, Anita & Shahbaz, Muhammad & Aqsha, Aqsha, 2020. "Process optimization of green diesel selectivity and understanding of reaction intermediates," Renewable Energy, Elsevier, vol. 149(C), pages 1092-1106.
    3. Li, Xin & Luo, Xingyi & Jin, Yangbin & Li, Jinyan & Zhang, Hongdan & Zhang, Aiping & Xie, Jun, 2018. "Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3762-3797.
    4. Burimsitthigul, Thikhamporn & Yoosuk, Boonyawan & Ngamcharussrivichai, Chawalit & Prasassarakich, Pattarapan, 2021. "Hydrocarbon biofuel from hydrotreating of palm oil over unsupported Ni–Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 163(C), pages 1648-1659.
    5. Barbosa, Ian V. & Scapim, Letícia A. & Cavalcante, Raquel M. & Young, André F., 2023. "Industrial production of green diesel in Brazil: Process simulation and economic perspectives," Renewable Energy, Elsevier, vol. 219(P2).
    6. Thongkumkoon, Skonrach & Kiatkittipong, Worapon & Hartley, Unalome Wetwatana & Laosiripojana, Navadol & Daorattanachai, Pornlada, 2019. "Catalytic activity of trimetallic sulfided Re-Ni-Mo/γ-Al2O3 toward deoxygenation of palm feedstocks," Renewable Energy, Elsevier, vol. 140(C), pages 111-123.
    7. Scaldaferri, C.A. & Pasa, V.M.D., 2019. "Green diesel production from upgrading of cashew nut shell liquid," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 303-313.
    8. Pattanaik, Bhabani Prasanna & Misra, Rahul Dev, 2017. "Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 545-557.
    9. Joshi, Girdhar & Pandey, Jitendra K. & Rana, Sravendra & Rawat, Devendra S., 2017. "Challenges and opportunities for the application of biofuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 850-866.
    10. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    11. Giwa, Adewale & Adeyemi, Idowu & Dindi, Abdallah & Lopez, Celia García-Baños & Lopresto, Catia Giovanna & Curcio, Stefano & Chakraborty, Sudip, 2018. "Techno-economic assessment of the sustainability of an integrated biorefinery from microalgae and Jatropha: A review and case study," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 239-257.
    12. Iraklis Zahos-Siagos & Vlasios Karathanassis & Dimitrios Karonis, 2018. "Exhaust Emissions and Physicochemical Properties of n -Butanol/Diesel Blends with 2-Ethylhexyl Nitrate (EHN) or Hydrotreated Used Cooking Oil (HUCO) as Cetane Improvers," Energies, MDPI, vol. 11(12), pages 1-20, December.
    13. Neves, Renato Cruz & Klein, Bruno Colling & da Silva, Ricardo Justino & Rezende, Mylene Cristina Alves Ferreira & Funke, Axel & Olivarez-Gómez, Edgardo & Bonomi, Antonio & Maciel-Filho, Rubens, 2020. "A vision on biomass-to-liquids (BTL) thermochemical routes in integrated sugarcane biorefineries for biojet fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    14. Buffi, Marco & Valera-Medina, Agustin & Marsh, Richard & Pugh, Daniel & Giles, Anthony & Runyon, Jon & Chiaramonti, David, 2017. "Emissions characterization tests for hydrotreated renewable jet fuel from used cooking oil and its blends," Applied Energy, Elsevier, vol. 201(C), pages 84-93.
    15. Haseeb Yaqoob & Yew Heng Teoh & Farooq Sher & Muhammad Umer Farooq & Muhammad Ahmad Jamil & Zareena Kausar & Noor Us Sabah & Muhammad Faizan Shah & Hafiz Zia Ur Rehman & Atiq Ur Rehman, 2021. "Potential of Waste Cooking Oil Biodiesel as Renewable Fuel in Combustion Engines: A Review," Energies, MDPI, vol. 14(9), pages 1-20, April.
    16. Peter N. Ciesielski & M. Brennan Pecha & Vivek S. Bharadwaj & Calvin Mukarakate & G. Jeremy Leong & Branden Kappes & Michael F. Crowley & Seonah Kim & Thomas D. Foust & Mark R. Nimlos, 2018. "Advancing catalytic fast pyrolysis through integrated multiscale modeling and experimentation: Challenges, progress, and perspectives," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 7(4), July.
    17. Chen, Lihong & Ren, Jingzheng, 2018. "Multi-attribute sustainability evaluation of alternative aviation fuels based on fuzzy ANP and fuzzy grey relational analysis," Journal of Air Transport Management, Elsevier, vol. 68(C), pages 176-186.
    18. Merola, Simona Silvia & Tornatore, Cinzia & Irimescu, Adrian & Marchitto, Luca & Valentino, Gerardo, 2016. "Optical diagnostics of early flame development in a DISI (direct injection spark ignition) engine fueled with n-butanol and gasoline," Energy, Elsevier, vol. 108(C), pages 50-62.
    19. Mikulski, Maciej & Ambrosewicz-Walacik, Marta & Duda, Kamil & Hunicz, Jacek, 2020. "Performance and emission characterization of a common-rail compression-ignition engine fuelled with ternary mixtures of rapeseed oil, pyrolytic oil and diesel," Renewable Energy, Elsevier, vol. 148(C), pages 739-755.
    20. Zharova, P.A. & Chistyakov, A.V. & Shapovalov, S.S. & Pasynskii, A.A. & Tsodikov, M.V., 2019. "Original Pt-Sn/Al2O3 catalyst for selective hydrodeoxygenation of vegetable oils," Energy, Elsevier, vol. 172(C), pages 18-25.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:80:y:2017:i:c:p:1072-1088. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.