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Catalytic Conversion of Palm Oil to Bio-Hydrogenated Diesel over Novel N-Doped Activated Carbon Supported Pt Nanoparticles

Author

Listed:
  • Wei Jin

    (Chemical & Process Engineering Department, University of Surrey, Guildford GU2 7XH, UK)

  • Laura Pastor-Pérez

    (Chemical & Process Engineering Department, University of Surrey, Guildford GU2 7XH, UK
    Laboratorio de Materiales Avanzados, Departamento de Química Inorgánica Instituto Universitario de Materiales de Alicante, Universidad de Alicante, 03690 Alicante, Spain)

  • Juan J. Villora-Pico

    (Laboratorio de Materiales Avanzados, Departamento de Química Inorgánica Instituto Universitario de Materiales de Alicante, Universidad de Alicante, 03690 Alicante, Spain)

  • Mercedes M. Pastor-Blas

    (Laboratorio de Materiales Avanzados, Departamento de Química Inorgánica Instituto Universitario de Materiales de Alicante, Universidad de Alicante, 03690 Alicante, Spain)

  • Antonio Sepúlveda-Escribano

    (Laboratorio de Materiales Avanzados, Departamento de Química Inorgánica Instituto Universitario de Materiales de Alicante, Universidad de Alicante, 03690 Alicante, Spain)

  • Sai Gu

    (Chemical & Process Engineering Department, University of Surrey, Guildford GU2 7XH, UK)

  • Nikolaos D. Charisiou

    (Department of Chemical Engineering, University of Western Macedonia, 50100 Kozani, Greece)

  • Kyriakos Papageridis

    (Department of Chemical Engineering, University of Western Macedonia, 50100 Kozani, Greece)

  • Maria A. Goula

    (Department of Chemical Engineering, University of Western Macedonia, 50100 Kozani, Greece)

  • Tomas R. Reina

    (Chemical & Process Engineering Department, University of Surrey, Guildford GU2 7XH, UK)

Abstract

Bio-hydrogenated diesel (BHD), derived from vegetable oil via hydrotreating technology, is a promising alternative transportation fuel to replace nonsustainable petroleum diesel. In this work, a novel Pt-based catalyst supported on N-doped activated carbon prepared from polypyrrole as the nitrogen source (Pt/N-AC) was developed and applied in the palm oil deoxygenation process to produce BHD in a fixed bed reactor system. High conversion rates of triglycerides (conversion of TG > 90%) and high deoxygenation percentage (DeCO x % = 76% and HDO% = 7%) were obtained for the palm oil deoxygenation over Pt/N-AC catalyst at optimised reaction conditions: T = 300 °C, 30 bar of H 2 , and LHSV = 1.5 h −1 . In addition to the excellent performance, the Pt/N-AC catalyst is highly stable in the deoxygenation reaction, as confirmed by the XRD and TEM analyses of the spent sample. The incorporation of N atoms in the carbon structure alters the electronic density of the catalyst, favouring the interaction with electrophilic groups such as carbonyls, and thus boosting the DeCO x route over the HDO pathway. Overall, this work showcases a promising route to produce added value bio-fuels from bio-compounds using advanced N-doped catalysts.

Suggested Citation

  • Wei Jin & Laura Pastor-Pérez & Juan J. Villora-Pico & Mercedes M. Pastor-Blas & Antonio Sepúlveda-Escribano & Sai Gu & Nikolaos D. Charisiou & Kyriakos Papageridis & Maria A. Goula & Tomas R. Reina, 2019. "Catalytic Conversion of Palm Oil to Bio-Hydrogenated Diesel over Novel N-Doped Activated Carbon Supported Pt Nanoparticles," Energies, MDPI, vol. 13(1), pages 1-15, December.
    • Handle: RePEc:gam:jeners:v:13:y:2019:i:1:p:132-:d:302255
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    References listed on IDEAS

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    1. Pattanaik, Bhabani Prasanna & Misra, Rahul Dev, 2017. "Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 545-557.
    2. Hermida, Lilis & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2015. "Deoxygenation of fatty acid to produce diesel-like hydrocarbons: A review of process conditions, reaction kinetics and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1223-1233.
    3. Na, Jeong-Geol & Yi, Bo Eun & Han, Jun Kyu & Oh, You-Kwan & Park, Jong-Ho & Jung, Tae Sung & Han, Sang Sup & Yoon, Hyung Chul & Kim, Jong-Nam & Lee, Hyunjoo & Ko, Chang Hyun, 2012. "Deoxygenation of microalgal oil into hydrocarbon with precious metal catalysts: Optimization of reaction conditions and supports," Energy, Elsevier, vol. 47(1), pages 25-30.
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    Cited by:

    1. Papageridis, Kyriakos N. & Charisiou, Nikolaos D. & Douvartzides, Savvas & Sebastian, Victor & Hinder, Steven J. & Baker, Mark A. & AlKhoori, Sara & Polychronopoulou, Kyriaki & Goula, Maria A., 2020. "Promoting effect of CaO-MgO mixed oxide on Ni/γ-Al2O3 catalyst for selective catalytic deoxygenation of palm oil," Renewable Energy, Elsevier, vol. 162(C), pages 1793-1810.
    2. Tsiotsias, Anastasios I. & Hafeez, Sanaa & Charisiou, Nikolaos D. & Al-Salem, Sultan M. & Manos, George & Constantinou, Achilleas & AlKhoori, Sara & Sebastian, Victor & Hinder, Steven J. & Baker, Mark, 2023. "Selective catalytic deoxygenation of palm oil to produce green diesel over Ni catalysts supported on ZrO2 and CeO2–ZrO2: Experimental and process simulation modelling studies," Renewable Energy, Elsevier, vol. 206(C), pages 582-596.
    3. Du, Yuchan & Wang, Fei & Xia, Xueying & Zhu, Hao & Zhang, Zeng & You, Chaoqun & Jiang, Xiaoxiang & Jiang, Jianchun & Li, Changzhu, 2022. "MOF-derived Co nanoparticle on nitrogen-rich carbon for fatty acid hydrotreatment into green diesel," Renewable Energy, Elsevier, vol. 198(C), pages 246-253.

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