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Catalytic activity of trimetallic sulfided Re-Ni-Mo/γ-Al2O3 toward deoxygenation of palm feedstocks

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  • Thongkumkoon, Skonrach
  • Kiatkittipong, Worapon
  • Hartley, Unalome Wetwatana
  • Laosiripojana, Navadol
  • Daorattanachai, Pornlada

Abstract

Catalytic activities of trimetallic ReNiMo sulfide supported on γ-Al2O3 toward the deoxygenation of oleic acid, palm fatty acid distillate (PFAD), refined palm stearin (RPS) and refined palm olein (RPO) were studied. Relevant monometallic and bimetallic (i.e. Mo-, W-, Re-, ReMo-, ReW-, NiMo-) sulfides were also tested for comparison. Experiments revealed that, among all catalysts, ReNiMo sulfide catalyst exhibited the highest diesel yield of 76.5% from oleic acid, 72.5% from PFAD, 69.7% from RPS and 69.5% from RPO. Furthermore, the catalyst could maintain constant diesel yield level for at least six consecutive runs, whereas significant deactivation was observed from other catalysts due to high carbon deposition. Importantly, glycerol was also successfully employed as a hydrogen donor for deoxygenation reaction over this catalyst. From the catalyst characterizations, additional of Re increased the NiMo surface area by 20.4%, furthermore, it reduced the metal particle size and promote the metal dispersion on the support.

Suggested Citation

  • Thongkumkoon, Skonrach & Kiatkittipong, Worapon & Hartley, Unalome Wetwatana & Laosiripojana, Navadol & Daorattanachai, Pornlada, 2019. "Catalytic activity of trimetallic sulfided Re-Ni-Mo/γ-Al2O3 toward deoxygenation of palm feedstocks," Renewable Energy, Elsevier, vol. 140(C), pages 111-123.
    • Handle: RePEc:eee:renene:v:140:y:2019:i:c:p:111-123
    DOI: 10.1016/j.renene.2019.03.039
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    1. Pattanaik, Bhabani Prasanna & Misra, Rahul Dev, 2017. "Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 545-557.
    2. Hermida, Lilis & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2015. "Deoxygenation of fatty acid to produce diesel-like hydrocarbons: A review of process conditions, reaction kinetics and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1223-1233.
    3. Mahmudul, H.M. & Hagos, F.Y. & Mamat, R. & Adam, A. Abdul & Ishak, W.F.W. & Alenezi, R., 2017. "Production, characterization and performance of biodiesel as an alternative fuel in diesel engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 497-509.
    4. Arun, Naveenji & Sharma, Rajesh V. & Dalai, Ajay K., 2015. "Green diesel synthesis by hydrodeoxygenation of bio-based feedstocks: Strategies for catalyst design and development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 240-255.
    5. Daorattanachai, Pornlada & Laosiripojana, Weerawan & Laobuthee, Apirat & Laosiripojana, Navadol, 2018. "Type of contribution: Research article catalytic activity of sewage sludge char supported Re-Ni bimetallic catalyst toward cracking/reforming of biomass tar," Renewable Energy, Elsevier, vol. 121(C), pages 644-651.
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    1. Mingyuan Zhang & Xue Han & Huanang Wang & Yimin Zeng & Chunbao Charles Xu, 2023. "Hydrodeoxygenation of Pyrolysis Oil in Supercritical Ethanol with Formic Acid as an In Situ Hydrogen Source over NiMoW Catalysts Supported on Different Materials," Sustainability, MDPI, vol. 15(10), pages 1-15, May.
    2. Giuseppe Di Vito Nolfi & Katia Gallucci & Leucio Rossi, 2021. "Green Diesel Production by Catalytic Hydrodeoxygenation of Vegetables Oils," IJERPH, MDPI, vol. 18(24), pages 1-28, December.
    3. Stefania Lucantonio & Andrea Di Giuliano & Leucio Rossi & Katia Gallucci, 2023. "Green Diesel Production via Deoxygenation Process: A Review," Energies, MDPI, vol. 16(2), pages 1-44, January.
    4. Li, Xingyong & Wu, Yankun & Wang, Qi & Li, Shuirong & Ye, Yueyuan & Wang, Dechao & Zheng, Zhifeng, 2022. "Effect of preparation method of NiMo/γ-Al2O3 on the FAME hydrotreatment to produce C15–C18 alkanes," Renewable Energy, Elsevier, vol. 193(C), pages 1-12.

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