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Tubular direct carbon solid oxide fuel cells with molten antimony anode and refueling feasibility

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  • Duan, Nan-Qi
  • Cao, Yong
  • Hua, Bin
  • Chi, Bo
  • Pu, Jian
  • Luo, Jingli
  • Jian, Li

Abstract

Tubular direct carbon SOFCs (solid oxide fuel cells) supported by YSZ (Y2O3 stabilized ZrO2) electrolyte are fabricated by slurry-casting, slurry-dipping and sintering processes with La0.6Sr0.4Co0.2Fe0.8O3-10 mol.% Gd2O3 doped CeO2 (LSCF-10GDC) as the cathode. Their electrochemical performance is examined at temperatures from 700 to 800 °C using molten antimony (Sb) anode and activated carbon fuel. The ohmic resistance of the cell is between 1.01 and 0.37 Ω cm2 mainly originated from the thick YSZ electrolyte (150 μm); the polarization resistance ranges from 0.22 to 0.06 Ω cm2. The maximum power density at 800 °C is 304 mW cm−2 and can be greatly increased by using a thinner and/or more conductive electrolyte. With 1 g activated carbon as the fuel, the cell performance is stable at 200 mW cm−2 at 800 °C for more than 6 h by chemical consumption (oxidization) of the carbon, which reduces the electrochemically formed Sb2O3 to Sb. The cell performance decreases as the fuel is used up and is recovered by refueling.

Suggested Citation

  • Duan, Nan-Qi & Cao, Yong & Hua, Bin & Chi, Bo & Pu, Jian & Luo, Jingli & Jian, Li, 2016. "Tubular direct carbon solid oxide fuel cells with molten antimony anode and refueling feasibility," Energy, Elsevier, vol. 95(C), pages 274-278.
    • Handle: RePEc:eee:energy:v:95:y:2016:i:c:p:274-278
    DOI: 10.1016/j.energy.2015.10.033
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    2. Eom, Seongyong & Ahn, Seongyool & Kang, Kijoong & Choi, Gyungmin, 2017. "Correlations between electrochemical resistances and surface properties of acid-treated fuel in coal fuel cells," Energy, Elsevier, vol. 140(P1), pages 885-892.
    3. Xie, Yongmin & Xiao, Jie & Liu, Qingsheng & Wang, Xiaoqiang & Liu, Jiang & Wu, Peijia & Ouyang, Shaobo, 2021. "Highly efficient utilization of walnut shell biochar through a facile designed portable direct carbon solid oxide fuel cell stack," Energy, Elsevier, vol. 227(C).
    4. Jiang, Yidong & Gu, Xin & Shi, Jixin & Shi, Yixiang & Cai, Ningsheng, 2023. "Co-generation of gas and electricity on liquid antimony anode solid oxide fuel cells for high efficiency, long-term kerosene power generation," Energy, Elsevier, vol. 263(PC).
    5. Lei, Libin & Wang, Yao & Fang, Shumin & Ren, Cong & Liu, Tong & Chen, Fanglin, 2016. "Efficient syngas generation for electricity storage through carbon gasification assisted solid oxide co-electrolysis," Applied Energy, Elsevier, vol. 173(C), pages 52-58.
    6. Cao, Tianyu & Shi, Yixiang & Jiang, Yanqi & Cai, Ningsheng & Gong, Qianming, 2017. "Performance enhancement of liquid antimony anode fuel cell by in-situ electrochemical assisted oxidation process," Energy, Elsevier, vol. 125(C), pages 526-532.
    7. Ozalp, N. & Abedini, H. & Abuseada, M. & Davis, R. & Rutten, J. & Verschoren, J. & Ophoff, C. & Moens, D., 2022. "An overview of direct carbon fuel cells and their promising potential on coupling with solar thermochemical carbon production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    8. Hao, Wenbin & Mi, Yongli, 2016. "Evaluation of waste paper as a source of carbon fuel for hybrid direct carbon fuel cells," Energy, Elsevier, vol. 107(C), pages 122-130.

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