IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v211y2020ics036054422032065x.html
   My bibliography  Save this article

Sulfur-tolerant Fe-doped La0·3Sr0·7TiO3 perovskite as anode of direct carbon solid oxide fuel cells

Author

Listed:
  • Cai, Weizi
  • Cao, Dan
  • Zhou, Mingyang
  • Yan, Xiaomin
  • Li, Yuzhi
  • Wu, Zhen
  • Lü, Shengping
  • Mao, Caiyun
  • Xie, Yongmin
  • Zhao, Caiwen
  • Yu, Jialing
  • Ni, Meng
  • Liu, Jiang
  • Wang, Hailin

Abstract

Fe-doped La0·3Sr0·7TiO3 (LSFT) is synthesized and systematically characterized towards application as an anode material for direct carbon solid oxide fuel cells (DC-SOFCs). The structural, electrical and electrochemical properties of LSFT under the operation conditions of DC-SOFCs have been evaluated. High structural stability, improved ionic conductivity, electrocatalytic activity, and electrochemical performance are demonstrated. Electrolyte-supported DC-SOFC with LSFT anode provides a maximum power density of 292 mW cm−2 at 850 °C, which is comparable to those state-of-the-art Ni-YSZ anode for DC-SOFC. In addition, it shows excellent long-term operational stability (over 110 h) in H2S-containing CO atmosphere. It thus promises as a novel anode candidate for DC-SOFCs with whole-solid-state configuration.

Suggested Citation

  • Cai, Weizi & Cao, Dan & Zhou, Mingyang & Yan, Xiaomin & Li, Yuzhi & Wu, Zhen & Lü, Shengping & Mao, Caiyun & Xie, Yongmin & Zhao, Caiwen & Yu, Jialing & Ni, Meng & Liu, Jiang & Wang, Hailin, 2020. "Sulfur-tolerant Fe-doped La0·3Sr0·7TiO3 perovskite as anode of direct carbon solid oxide fuel cells," Energy, Elsevier, vol. 211(C).
    • Handle: RePEc:eee:energy:v:211:y:2020:i:c:s036054422032065x
    DOI: 10.1016/j.energy.2020.118958
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S036054422032065X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2020.118958?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Jiao, Yong & Tian, Wenjuan & Chen, Huili & Shi, Huangang & Yang, Binbin & Li, Chao & Shao, Zongping & Zhu, Zhenping & Li, Si-Dian, 2015. "In situ catalyzed Boudouard reaction of coal char for solid oxide-based carbon fuel cells with improved performance," Applied Energy, Elsevier, vol. 141(C), pages 200-208.
    2. Kupecki, Jakub & Skrzypkiewicz, Marek & Motylinski, Konrad, 2018. "Variant analysis of the efficiency of industrial scale power station based on DC-SOFCs and DC-MCFCs," Energy, Elsevier, vol. 156(C), pages 292-298.
    3. Rady, Adam C. & Giddey, Sarbjit & Kulkarni, Aniruddha & Badwal, Sukhvinder P.S. & Bhattacharya, Sankar & Ladewig, Bradley P., 2014. "Direct carbon fuel cell operation on brown coal," Applied Energy, Elsevier, vol. 120(C), pages 56-64.
    4. Cai, Weizi & Zhou, Qian & Xie, Yongmin & Liu, Jiang & Long, Guohui & Cheng, Shuang & Liu, Meilin, 2016. "A direct carbon solid oxide fuel cell operated on a plant derived biofuel with natural catalyst," Applied Energy, Elsevier, vol. 179(C), pages 1232-1241.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gao, Juntao & Ma, Dan & Zhao, Hui & Li, Qiang & Lü, Zhe & Wei, Bo, 2022. "Synergistically improving electrocatalytic performance and CO2 tolerance of Fe-based cathode catalysts for solid oxide fuel cells," Energy, Elsevier, vol. 252(C).
    2. Dongxu Zhang & Ting Min & Ming Jiang & Yaxiong Yu & Qiang Zhou, 2021. "Numerical Simulation of Fluidized Bed Gasifier Coupled with Solid Oxide Fuel Cell Fed with Solid Carbon," Energies, MDPI, vol. 14(10), pages 1-24, May.
    3. Xie, Yongmin & Xiao, Jie & Liu, Qingsheng & Wang, Xiaoqiang & Liu, Jiang & Wu, Peijia & Ouyang, Shaobo, 2021. "Highly efficient utilization of walnut shell biochar through a facile designed portable direct carbon solid oxide fuel cell stack," Energy, Elsevier, vol. 227(C).
    4. Zheng, Yifeng & Wang, Shun & Pan, Zehua & Yin, Bo, 2021. "Electrochemical CO2 reduction to CO using solid oxide electrolysis cells with high-performance Ta-doped bismuth strontium ferrite air electrode," Energy, Elsevier, vol. 228(C).
    5. Han, Yuan & Zhang, Houcheng & Hu, Ziyang & Hou, Shujin, 2021. "An efficient hybrid system using a graphene-based cathode vacuum thermionic energy converter to harvest the waste heat from a molten hydroxide direct carbon fuel cell," Energy, Elsevier, vol. 223(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Qianyang & Qiu, Qianyuan & Yan, Xiaomin & Zhou, Mingyang & Zhang, Yapeng & Liu, Zhijun & Cai, Weizi & Wang, Wei & Liu, Jiang, 2020. "A compact and seal-less direct carbon solid oxide fuel cell stack stepping into practical application," Applied Energy, Elsevier, vol. 278(C).
    2. Gu, Xiaofeng & Yan, Xiaomin & Zhou, Mingyang & Zou, Gaochang & Fan, Zidai & Liu, Jiang, 2024. "High efficiency electricity and gas cogeneration through direct carbon solid oxide fuel cell with cotton stalk biochar," Renewable Energy, Elsevier, vol. 226(C).
    3. Cai, Weizi & Zhou, Qian & Xie, Yongmin & Liu, Jiang & Long, Guohui & Cheng, Shuang & Liu, Meilin, 2016. "A direct carbon solid oxide fuel cell operated on a plant derived biofuel with natural catalyst," Applied Energy, Elsevier, vol. 179(C), pages 1232-1241.
    4. Mushtaq, Usman & Mehran, Muhammad Taqi & Kim, Sun-Kyoung & Lim, Tak-Hyoung & Naqvi, Syed Asad Ali & Lee, Jong-Won & Lee, Seung-Bok & Park, Seok-Joo & Song, Rak-Hyun, 2017. "Evaluation of steady-state characteristics for solid oxide carbon fuel cell short-stacks," Applied Energy, Elsevier, vol. 187(C), pages 886-898.
    5. Duan, Nan-Qi & Tan, Yuan & Yan, Dong & Jia, Lichao & Chi, Bo & Pu, Jian & Li, Jian, 2016. "Biomass carbon fueled tubular solid oxide fuel cells with molten antimony anode," Applied Energy, Elsevier, vol. 165(C), pages 983-989.
    6. Wu, Hao & Xiao, Jie & Zeng, Xiaoyuan & Li, Xue & Yang, Jing & Zou, Yuling & Liu, Sudongfang & Dong, Peng & Zhang, Yingjie & Liu, Jiang, 2019. "A high performance direct carbon solid oxide fuel cell – A green pathway for brown coal utilization," Applied Energy, Elsevier, vol. 248(C), pages 679-687.
    7. Wang, Chaoqi & Lü, Zhe & Li, Jingwei & Cao, Zhiqun & Wei, Bo & Li, Huan & Shang, Minghao & Su, Chaoxiang, 2020. "Efficient use of waste carton for power generation, tar and fertilizer through direct carbon solid oxide fuel cell," Renewable Energy, Elsevier, vol. 158(C), pages 410-420.
    8. Lei, Libin & Keels, Jayson M. & Tao, Zetian & Zhang, Jihao & Chen, Fanglin, 2018. "Thermodynamic and experimental assessment of proton conducting solid oxide fuel cells with internal methane steam reforming," Applied Energy, Elsevier, vol. 224(C), pages 280-288.
    9. Ozalp, N. & Abedini, H. & Abuseada, M. & Davis, R. & Rutten, J. & Verschoren, J. & Ophoff, C. & Moens, D., 2022. "An overview of direct carbon fuel cells and their promising potential on coupling with solar thermochemical carbon production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    10. Yoon, Kwangsuk & Lee, Sang Soo & Ok, Yong Sik & Kwon, Eilhann E. & Song, Hocheol, 2019. "Enhancement of syngas for H2 production via catalytic pyrolysis of orange peel using CO2 and bauxite residue," Applied Energy, Elsevier, vol. 254(C).
    11. Jiao, Yong & Zhang, Liqin & An, Wenting & Zhou, Wei & Sha, Yujing & Shao, Zongping & Bai, Jianping & Li, Si-Dian, 2016. "Controlled deposition and utilization of carbon on Ni-YSZ anodes of SOFCs operating on dry methane," Energy, Elsevier, vol. 113(C), pages 432-443.
    12. Marek Skrzypkiewicz & Michal Wierzbicki & Stanislaw Jagielski & Yevgeniy Naumovich & Konrad Motylinski & Jakub Kupecki & Agnieszka Zurawska & Magdalena Kosiorek, 2022. "Influence of the Contamination of Fuel with Fly Ash Originating from Biomass Gasification on the Performance of the Anode-Supported SOFC," Energies, MDPI, vol. 15(4), pages 1-17, February.
    13. Duan, Nan-Qi & Cao, Yong & Hua, Bin & Chi, Bo & Pu, Jian & Luo, Jingli & Jian, Li, 2016. "Tubular direct carbon solid oxide fuel cells with molten antimony anode and refueling feasibility," Energy, Elsevier, vol. 95(C), pages 274-278.
    14. Qu, Jifa & Wang, Wei & Chen, Yubo & Wang, Feng & Ran, Ran & Shao, Zongping, 2015. "Ethylene glycol as a new sustainable fuel for solid oxide fuel cells with conventional nickel-based anodes," Applied Energy, Elsevier, vol. 148(C), pages 1-9.
    15. Valentina Zubkova & Andrzej Strojwas & Marcin Bielecki, 2021. "Analysis of the Pyrolytic Behaviour of Birch, Maple, and Rowan Leaves," Energies, MDPI, vol. 14(8), pages 1-18, April.
    16. Zhang, Ji & Liang, Yanna & Harpalani, Satya, 2016. "Optimization of methane production from bituminous coal through biogasification," Applied Energy, Elsevier, vol. 183(C), pages 31-42.
    17. Jiao, Yong & Tian, Wenjuan & Chen, Huili & Shi, Huangang & Yang, Binbin & Li, Chao & Shao, Zongping & Zhu, Zhenping & Li, Si-Dian, 2015. "In situ catalyzed Boudouard reaction of coal char for solid oxide-based carbon fuel cells with improved performance," Applied Energy, Elsevier, vol. 141(C), pages 200-208.
    18. Xie, Yongmin & Xiao, Jie & Liu, Qingsheng & Wang, Xiaoqiang & Liu, Jiang & Wu, Peijia & Ouyang, Shaobo, 2021. "Highly efficient utilization of walnut shell biochar through a facile designed portable direct carbon solid oxide fuel cell stack," Energy, Elsevier, vol. 227(C).
    19. Houcheng Zhang & Jiatang Wang & Jiapei Zhao & Fu Wang & He Miao & Jinliang Yuan, 2019. "Performance Analysis of a Hybrid System Consisting of a Molten Carbonate Direct Carbon Fuel Cell and an Absorption Refrigerator," Energies, MDPI, vol. 12(3), pages 1-13, January.
    20. Antar, Mohammed & Lyu, Dongmei & Nazari, Mahtab & Shah, Ateeq & Zhou, Xiaomin & Smith, Donald L., 2021. "Biomass for a sustainable bioeconomy: An overview of world biomass production and utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:211:y:2020:i:c:s036054422032065x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.