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Highly efficient utilization of walnut shell biochar through a facile designed portable direct carbon solid oxide fuel cell stack

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  • Xie, Yongmin
  • Xiao, Jie
  • Liu, Qingsheng
  • Wang, Xiaoqiang
  • Liu, Jiang
  • Wu, Peijia
  • Ouyang, Shaobo

Abstract

The direct carbon solid oxide fuel cell (DC-SOFC) is a green and efficient energy conversion device with all-solid-state structure, which can convert carbon fuel into electricity directly. Recently, using biomasses as fuels for DC-SOFC has become fascinating due to their abundance and renewable property. However, it usually provides inferior performance compared to that with gas fuel feeding (hydrogen). Here, we report a promising and high-performing tubular segmented-in-series YSZ electrolyte-supported DC-SOFC stack. Thereinto, the YSZ electrolyte supports are fabricated by dip-coating and both pure walnut shell biochar and Fe-loaded biochar are used as fuels. The single cell can achieve a maximum power density of 147 mW cm−2 at 800 °C and it is improved to 205 mW cm−2 as FenOm catalyst is loaded on the biochar fuel. Furthermore, a two-cell-stack of DC-SOFC operated with Fe-loaded walnut shell char is assembled and tested. It delivers an outstanding performance, with an OCV of 1.98 V, an output power of 1.11 W and a maximum volumetric power density of 505 mW cm−3 at 800 °C, indicating high potentials for developing into a high performance battery for portable or distributed applications.

Suggested Citation

  • Xie, Yongmin & Xiao, Jie & Liu, Qingsheng & Wang, Xiaoqiang & Liu, Jiang & Wu, Peijia & Ouyang, Shaobo, 2021. "Highly efficient utilization of walnut shell biochar through a facile designed portable direct carbon solid oxide fuel cell stack," Energy, Elsevier, vol. 227(C).
    • Handle: RePEc:eee:energy:v:227:y:2021:i:c:s0360544221007052
    DOI: 10.1016/j.energy.2021.120456
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    2. Muzyka, Roksana & Misztal, Edyta & Hrabak, Joanna & Banks, Scott W. & Sajdak, Marcin, 2023. "Various biomass pyrolysis conditions influence the porosity and pore size distribution of biochar," Energy, Elsevier, vol. 263(PE).
    3. Gu, Xiaofeng & Yan, Xiaomin & Zhou, Mingyang & Zou, Gaochang & Fan, Zidai & Liu, Jiang, 2024. "High efficiency electricity and gas cogeneration through direct carbon solid oxide fuel cell with cotton stalk biochar," Renewable Energy, Elsevier, vol. 226(C).
    4. Han, Tingting & Li, Lin & Xie, Yujiao & Zhang, Jinjin & Meng, Xiuxia & Yu, Fangyong & Lup, Andrew Ng Kay & Sunarso, Jaka & Yang, Naitao, 2024. "New insights into single-step fabrication of finger-like anode/electrolyte for high-performance direct carbon solid oxide fuel cells: Experimental and simulation studies," Applied Energy, Elsevier, vol. 354(PB).

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