IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v75y2014icp555-559.html
   My bibliography  Save this article

Liquid antimony anode direct carbon fuel cell fueled with mass-produced de-ash coal

Author

Listed:
  • Wang, Hongjian
  • Cao, Tianyu
  • Shi, Yixiang
  • Cai, Ningsheng
  • Yuan, Wei

Abstract

A liquid antimony (Sb) anode DCFC (direct carbon fuel cell) is fabricated on a smooth single crystal YSZ (Yttria Stabilized Zirconia) electrolyte substrate with porous Pt cathode to reveal the intrinsic reaction kinetics of electrochemical oxidation of liquid Sb and the reduction reaction characteristics of Sb2O3 with the reaction mass-produced Taixi de-ash coal fuel. The reduction kinetics of Sb2O3 with the de-ash coal is obtained using a temperature programmed reaction testing system. The reaction kinetics of the Sb2O3 with the de-ash coal can be enhanced by decreasing the coal particle size, and by adding de-ash coal into the anode chamber. The Sb2O3 accumulation at the interface between anode and electrolyte lead to the increase of ohmic resistance. While effective reaction active sites increase when the mole content of oxygen ion conductor Sb2O3 increase at the earlier stage of the cell discharging processes which further decrease the electrode polarization. The Si and Fe in the ash possibly accumulate at the interface between anode and electrolyte.

Suggested Citation

  • Wang, Hongjian & Cao, Tianyu & Shi, Yixiang & Cai, Ningsheng & Yuan, Wei, 2014. "Liquid antimony anode direct carbon fuel cell fueled with mass-produced de-ash coal," Energy, Elsevier, vol. 75(C), pages 555-559.
    • Handle: RePEc:eee:energy:v:75:y:2014:i:c:p:555-559
    DOI: 10.1016/j.energy.2014.08.017
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214009530
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.08.017?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Carton, J.G. & Olabi, A.G., 2010. "Design of experiment study of the parameters that affect performance of three flow plate configurations of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 35(7), pages 2796-2806.
    2. Carton, J.G. & Olabi, A.G., 2010. "Wind/hydrogen hybrid systems: Opportunity for Ireland’s wind resource to provide consistent sustainable energy supply," Energy, Elsevier, vol. 35(12), pages 4536-4544.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xu, Haoran & Chen, Bin & Tan, Peng & Zhang, Houcheng & Yuan, Jinliang & Liu, Jiang & Ni, Meng, 2017. "Performance improvement of a direct carbon solid oxide fuel cell system by combining with a Stirling cycle," Energy, Elsevier, vol. 140(P1), pages 979-987.
    2. Jiang, Yidong & Gu, Xin & Shi, Jixin & Shi, Yixiang & Cai, Ningsheng, 2023. "Co-generation of gas and electricity on liquid antimony anode solid oxide fuel cells for high efficiency, long-term kerosene power generation," Energy, Elsevier, vol. 263(PC).
    3. Cao, Tianyu & Shi, Yixiang & Jiang, Yanqi & Cai, Ningsheng & Gong, Qianming, 2017. "Performance enhancement of liquid antimony anode fuel cell by in-situ electrochemical assisted oxidation process," Energy, Elsevier, vol. 125(C), pages 526-532.
    4. Duan, Nan-Qi & Cao, Yong & Hua, Bin & Chi, Bo & Pu, Jian & Luo, Jingli & Jian, Li, 2016. "Tubular direct carbon solid oxide fuel cells with molten antimony anode and refueling feasibility," Energy, Elsevier, vol. 95(C), pages 274-278.
    5. Duan, Nan-Qi & Tan, Yuan & Yan, Dong & Jia, Lichao & Chi, Bo & Pu, Jian & Li, Jian, 2016. "Biomass carbon fueled tubular solid oxide fuel cells with molten antimony anode," Applied Energy, Elsevier, vol. 165(C), pages 983-989.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Rahnavard, Aylin & Rowshanzamir, Soosan & Parnian, Mohammad Javad & Amirkhanlou, Gholam Reza, 2015. "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells," Energy, Elsevier, vol. 82(C), pages 746-757.
    2. Yang, Shipin & Chellali, Ryad & Lu, Xiaohua & Li, Lijuan & Bo, Cuimei, 2016. "Modeling and optimization for proton exchange membrane fuel cell stack using aging and challenging P systems based optimization algorithm," Energy, Elsevier, vol. 109(C), pages 569-577.
    3. Díaz, Manuel Antonio & Iranzo, Alfredo & Rosa, Felipe & Isorna, Fernando & López, Eduardo & Bolivar, Juan Pedro, 2015. "Effect of carbon dioxide on the contamination of low temperature and high temperature PEM (polymer electrolyte membrane) fuel cells. Influence of temperature, relative humidity and analysis of regener," Energy, Elsevier, vol. 90(P1), pages 299-309.
    4. An, Myung-Gi & Mehmood, Asad & Hwang, Jinyeon & Ha, Heung Yong, 2016. "A novel method of methanol concentration control through feedback of the amplitudes of output voltage fluctuations for direct methanol fuel cells," Energy, Elsevier, vol. 100(C), pages 217-226.
    5. Wang, Luwen & He, Mingyan & Hu, Yue & Zhang, Yufeng & Liu, Xiaowei & Wang, Gaofeng, 2015. "A “4-cell” modular passive DMFC (direct methanol fuel cell) stack for portable applications," Energy, Elsevier, vol. 82(C), pages 229-235.
    6. Li, Dazi & Yu, Yadi & Jin, Qibing & Gao, Zhiqiang, 2014. "Maximum power efficiency operation and generalized predictive control of PEM (proton exchange membrane) fuel cell," Energy, Elsevier, vol. 68(C), pages 210-217.
    7. Chou, Chang-Chen & Liu, Cheng-Hong & Chen, Bing-Hung, 2014. "Effects of reduction temperature and pH value of polyol process on reduced graphene oxide supported Pt electrocatalysts for oxygen reduction reaction," Energy, Elsevier, vol. 70(C), pages 231-238.
    8. Gong, Wenyin & Cai, Zhihua, 2013. "Accelerating parameter identification of proton exchange membrane fuel cell model with ranking-based differential evolution," Energy, Elsevier, vol. 59(C), pages 356-364.
    9. Beltrán-Gastélum, M. & Salazar-Gastélum, M.I. & Félix-Navarro, R.M. & Pérez-Sicairos, S. & Reynoso-Soto, E.A. & Lin, S.W. & Flores-Hernández, J.R. & Romero-Castañón, T. & Albarrán-Sánchez, I.L. & Para, 2016. "Evaluation of PtAu/MWCNT (Multiwalled Carbon Nanotubes) electrocatalyst performance as cathode of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 109(C), pages 446-455.
    10. Blal, Mohamed & Benatiallah, Ali & NeÇaibia, Ammar & Lachtar, Salah & Sahouane, Nordine & Belasri, Ahmed, 2019. "Contribution and investigation to compare models parameters of (PEMFC), comprehensives review of fuel cell models and their degradation," Energy, Elsevier, vol. 168(C), pages 182-199.
    11. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
    12. Bizon, Nicu & Radut, Marin & Oproescu, Mihai, 2015. "Energy control strategies for the Fuel Cell Hybrid Power Source under unknown load profile," Energy, Elsevier, vol. 86(C), pages 31-41.
    13. Stoševski, Ivan & Krstić, Jelena & Milikić, Jadranka & Šljukić, Biljana & Kačarević-Popović, Zorica & Mentus, Slavko & Miljanić, Šćepan, 2016. "Radiolitically synthesized nano Ag/C catalysts for oxygen reduction and borohydride oxidation reactions in alkaline media, for potential applications in fuel cells," Energy, Elsevier, vol. 101(C), pages 79-90.
    14. Park, Taehyun & Chang, Ikwhang & Lee, Yoon Ho & Ji, Sanghoon & Cha, Suk Won, 2014. "Analysis of operational characteristics of polymer electrolyte fuel cell with expanded graphite flow-field plates via electrochemical impedance investigation," Energy, Elsevier, vol. 66(C), pages 77-81.
    15. Huang, Zhen-Ming & Su, Ay & Liu, Ying-Chieh, 2013. "Hydrogen generator system using Ru catalyst for PEMFC (proton exchange membrane fuel cell) applications," Energy, Elsevier, vol. 51(C), pages 230-236.
    16. Enevoldsen, Peter & Sovacool, Benjamin K., 2016. "Integrating power systems for remote island energy supply: Lessons from Mykines, Faroe Islands," Renewable Energy, Elsevier, vol. 85(C), pages 642-648.
    17. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    18. Luo, Yu & Shi, Yixiang & Li, Wenying & Cai, Ningsheng, 2014. "Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide," Energy, Elsevier, vol. 70(C), pages 420-434.
    19. Okur, Osman & İyigün Karadağ, Çiğdem & Boyacı San, Fatma Gül & Okumuş, Emin & Behmenyar, Gamze, 2013. "Optimization of parameters for hot-pressing manufacture of membrane electrode assembly for PEM (polymer electrolyte membrane fuel cells) fuel cell," Energy, Elsevier, vol. 57(C), pages 574-580.
    20. Díaz-González, Francisco & Sumper, Andreas & Gomis-Bellmunt, Oriol & Villafáfila-Robles, Roberto, 2012. "A review of energy storage technologies for wind power applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2154-2171.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:75:y:2014:i:c:p:555-559. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.