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Development of granular thermochemical heat storage composite based on calcium oxide

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  • Xia, B.Q.
  • Zhao, C.Y.
  • Yan, J.
  • Khosa, A.A.

Abstract

Thermochemical heat storage is a promising technology for the efficient utilization of renewable energy. Among available thermochemical systems, the CaO/Ca(OH)2 system is the most popular because of availability and cost. However, poor powder properties and low heat storage rates hinder the successful implementation of this system. This study presented a novel synthetic method of granular composites based on carboxymethyl cellulose sodium (CMC) and vermiculite in order to mitigate the drawbacks of natural materials and stabilize the size of materials for use in moving bed reactors. TGA and DSC experiments and some essential characterizations were done in order to evaluate the improvements on the basis of three objectives: the heat storage rate, heat storage density, and mechanical properties, compared with natural materials. Results showed that the granular composite still had great structural integrity after several dehydration/hydration cycles, whereas compacted natural materials had fragmented. Additionally, composite had a higher heat storage rate than natural materials. The gravimetric storage density of granular composite was slightly reduced while the volumetric storage density was enhanced up to approximately 124% as compared to the powdery Ca(OH)2 material. It was concluded that present synthetic method is a promising route for the development of Ca-based composite materials.

Suggested Citation

  • Xia, B.Q. & Zhao, C.Y. & Yan, J. & Khosa, A.A., 2020. "Development of granular thermochemical heat storage composite based on calcium oxide," Renewable Energy, Elsevier, vol. 147(P1), pages 969-978.
    • Handle: RePEc:eee:renene:v:147:y:2020:i:p1:p:969-978
    DOI: 10.1016/j.renene.2019.09.065
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    Cited by:

    1. Jun Yan & Lei Jiang & Changying Zhao, 2023. "Numerical Simulation of the Ca(OH) 2 /CaO Thermochemical Heat Storage Process in an Internal Heating Fixed-Bed Reactor," Sustainability, MDPI, vol. 15(9), pages 1-14, April.
    2. Laurie André & Stéphane Abanades, 2020. "Recent Advances in Thermochemical Energy Storage via Solid–Gas Reversible Reactions at High Temperature," Energies, MDPI, vol. 13(22), pages 1-23, November.
    3. Yupeng Feng & Xuhan Li & Haowen Wu & Chaoran Li & Man Zhang & Hairui Yang, 2023. "Critical Review of Ca(OH) 2 /CaO Thermochemical Energy Storage Materials," Energies, MDPI, vol. 16(7), pages 1-23, March.
    4. Carro, A. & Chacartegui, R. & Ortiz, C. & Becerra, J.A., 2022. "Analysis of a thermochemical energy storage system based on the reversible Ca(OH)2/CaO reaction," Energy, Elsevier, vol. 261(PA).
    5. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2020. "Development and characteristics analysis of salt-hydrate based composite sorbent for low-grade thermochemical energy storage," Renewable Energy, Elsevier, vol. 157(C), pages 920-940.
    6. Chaoying Sun & Xianyao Yan & Yingjie Li & Jianli Zhao & Zeyan Wang & Tao Wang, 2020. "Coupled CO2 capture and thermochemical heat storage of CaO derived from calcium acetate," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(5), pages 1027-1038, October.
    7. Xu, T.X. & Tian, X.K. & Khosa, A.A. & Yan, J. & Ye, Q. & Zhao, C.Y., 2021. "Reaction performance of CaCO3/CaO thermochemical energy storage with TiO2 dopant and experimental study in a fixed-bed reactor," Energy, Elsevier, vol. 236(C).

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