IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v155y2018icp128-138.html
   My bibliography  Save this article

Experimental investigation on the CaO/CaCO3 thermochemical energy storage with SiO2 doping

Author

Listed:
  • Chen, Xiaoyi
  • Jin, Xiaogang
  • Liu, Zhimin
  • Ling, Xiang
  • Wang, Yan

Abstract

Thermochemical systems offer high energy densities and the possibility of long-term storage for the promotion of renewable energy utilization. In particular, CaO/CaCO3 is a very promising system in the field of thermochemical energy storage due to its high energy density, widespread availability and low cost. However, this system makes stringent demands on the performance of CaO/CaCO3 energy storage, including the high reactivity and robust cycling stability. In this study, thermodynamics, kinetics and cycling stability of SiO2-doped CaCO3 are investigated by thermogravimetric analysis and differential scanning calorimetry. The obtained results show that SiO2 has a slightly negative effect on heat storage capacity, but the amount of released heat is increased, and the specific heat capacity is improved by 20% due to the high thermal conductivity of SiO2. Additionally, samples with an optimal mass ratio of 5% SiO2 show a decrease in the activation energy by approximately 40 kJ/mol because an increase in SiO2 surface coverage (>10 wt.%) leads to a reduction in the calcination conversion. Moreover, the cycling stability of SiO2-doped CaCO3 is enhanced by 28% with an attenuation ratio of 0.85% per cycle, especially at 700 °C, which is ascribed to the faster CO2 diffusion at higher carbonation temperature.

Suggested Citation

  • Chen, Xiaoyi & Jin, Xiaogang & Liu, Zhimin & Ling, Xiang & Wang, Yan, 2018. "Experimental investigation on the CaO/CaCO3 thermochemical energy storage with SiO2 doping," Energy, Elsevier, vol. 155(C), pages 128-138.
    • Handle: RePEc:eee:energy:v:155:y:2018:i:c:p:128-138
    DOI: 10.1016/j.energy.2018.05.016
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218308363
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.05.016?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lee, Myung gyu & Jang, Young Nam & Ryu, Kyung won & Kim, Wonbeak & Bang, Jun-Hwan, 2012. "Mineral carbonation of flue gas desulfurization gypsum for CO2 sequestration," Energy, Elsevier, vol. 47(1), pages 370-377.
    2. Pan, Zhihao & Zhao, C.Y., 2015. "Dehydration/hydration of MgO/H2O chemical thermal storage system," Energy, Elsevier, vol. 82(C), pages 611-618.
    3. Chen, Huichao & Zhang, Pingping & Duan, Yufeng & Zhao, Changsui, 2016. "Reactivity enhancement of calcium based sorbents by doped with metal oxides through the sol–gel process," Applied Energy, Elsevier, vol. 162(C), pages 390-400.
    4. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    5. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
    6. Shkatulov, Alexandr & Aristov, Yuri, 2015. "Modification of magnesium and calcium hydroxides with salts: An efficient way to advanced materials for storage of middle-temperature heat," Energy, Elsevier, vol. 85(C), pages 667-676.
    7. Matthews, L. & Lipiński, W., 2012. "Thermodynamic analysis of solar thermochemical CO2 capture via carbonation/calcination cycle with heat recovery," Energy, Elsevier, vol. 45(1), pages 900-907.
    8. N'Tsoukpoe, Kokouvi Edem & Restuccia, Giovanni & Schmidt, Thomas & Py, Xavier, 2014. "The size of sorbents in low pressure sorption or thermochemical energy storage processes," Energy, Elsevier, vol. 77(C), pages 983-998.
    9. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    10. Perejón, Antonio & Miranda-Pizarro, Juan & Pérez-Maqueda, Luis A. & Valverde, Jose Manuel, 2016. "On the relevant role of solids residence time on their CO2 capture performance in the Calcium Looping technology," Energy, Elsevier, vol. 113(C), pages 160-171.
    11. Jing, Jie-ying & Li, Ting-yu & Zhang, Xue-wei & Wang, Shi-dong & Feng, Jie & Turmel, William A. & Li, Wen-ying, 2017. "Enhanced CO2 sorption performance of CaO/Ca3Al2O6 sorbents and its sintering-resistance mechanism," Applied Energy, Elsevier, vol. 199(C), pages 225-233.
    12. Erans, María & Manovic, Vasilije & Anthony, Edward J., 2016. "Calcium looping sorbents for CO2 capture," Applied Energy, Elsevier, vol. 180(C), pages 722-742.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Laurie André & Stéphane Abanades, 2020. "Recent Advances in Thermochemical Energy Storage via Solid–Gas Reversible Reactions at High Temperature," Energies, MDPI, vol. 13(22), pages 1-23, November.
    2. Ying Yang & Yingjie Li & Xianyao Yan & Jianli Zhao & Chunxiao Zhang, 2021. "Development of Thermochemical Heat Storage Based on CaO/CaCO 3 Cycles: A Review," Energies, MDPI, vol. 14(20), pages 1-26, October.
    3. Saman Setoodeh Jahromy & Mudassar Azam & Christian Jordan & Michael Harasek & Franz Winter, 2021. "The Potential Use of Fly Ash from the Pulp and Paper Industry as Thermochemical Energy and CO 2 Storage Material," Energies, MDPI, vol. 14(11), pages 1-21, June.
    4. Yang, Jie & Wei, Yi & Yang, Jing & Xiang, Huaping & Ma, Liping & Zhang, Wei & Wang, Lichun & Peng, Yuhui & Liu, Hongpan, 2019. "Syngas production by chemical looping gasification using Fe supported on phosphogypsum compound oxygen carrier," Energy, Elsevier, vol. 168(C), pages 126-135.
    5. Li, Caili & Li, Yingjie & Fang, Yi & Zhang, Chunxiao & Ren, Yu, 2024. "TiO2/MnFe2O4 co-modified alkaline papermaking waste for CaO-CaCO3 thermochemical energy storage," Applied Energy, Elsevier, vol. 362(C).
    6. Khosa, Azhar Abbas & Yan, J. & Zhao, C.Y., 2021. "Investigating the effects of ZnO dopant on the thermodynamic and kinetic properties of CaCO3/CaO TCES system," Energy, Elsevier, vol. 215(PA).
    7. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    8. Chen, Xiaoyi & Dong, Zhenbiao & Zhu, Liujuan & Ling, Xiang, 2023. "Mass transfer performance inside Ca-based thermochemical energy storage materials under different operating conditions," Renewable Energy, Elsevier, vol. 205(C), pages 340-348.
    9. Ma, Zhangke & Li, Yingjie & Zhang, Wan & Wang, Yuzhuo & Zhao, Jianli & Wang, Zeyan, 2020. "Energy storage and attrition performance of limestone under fluidization during CaO/CaCO3 cycles," Energy, Elsevier, vol. 207(C).
    10. Anti Kur & Jo Darkwa & John Calautit & Rabah Boukhanouf & Mark Worall, 2023. "Solid–Gas Thermochemical Energy Storage Materials and Reactors for Low to High-Temperature Applications: A Concise Review," Energies, MDPI, vol. 16(2), pages 1-35, January.
    11. Chen, Xiaoyi & Jin, Xiaogang & Ling, Xiang & Wang, Yan, 2020. "Indirect integration of thermochemical energy storage with the recompression supercritical CO2 Brayton cycle," Energy, Elsevier, vol. 209(C).
    12. Xu, T.X. & Tian, X.K. & Khosa, A.A. & Yan, J. & Ye, Q. & Zhao, C.Y., 2021. "Reaction performance of CaCO3/CaO thermochemical energy storage with TiO2 dopant and experimental study in a fixed-bed reactor," Energy, Elsevier, vol. 236(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Khosa, Azhar Abbas & Yan, J. & Zhao, C.Y., 2021. "Investigating the effects of ZnO dopant on the thermodynamic and kinetic properties of CaCO3/CaO TCES system," Energy, Elsevier, vol. 215(PA).
    2. Khosa, Azhar Abbas & Han, Xinyue & Zhao, C.Y., 2024. "Experimental investigation of CaCO3/CaO reaction pair in a fixed bed reactor for CSP application," Renewable Energy, Elsevier, vol. 221(C).
    3. Xu, Y.X. & Yan, J. & Zhao, C.Y., 2022. "Investigation on application temperature zone and exergy loss regulation based on MgCO3/MgO thermochemical heat storage and release process," Energy, Elsevier, vol. 239(PC).
    4. Benitez-Guerrero, Monica & Valverde, Jose Manuel & Perejon, Antonio & Sanchez-Jimenez, Pedro E. & Perez-Maqueda, Luis A., 2018. "Low-cost Ca-based composites synthesized by biotemplate method for thermochemical energy storage of concentrated solar power," Applied Energy, Elsevier, vol. 210(C), pages 108-116.
    5. Saman Setoodeh Jahromy & Mudassar Azam & Christian Jordan & Michael Harasek & Franz Winter, 2021. "The Potential Use of Fly Ash from the Pulp and Paper Industry as Thermochemical Energy and CO 2 Storage Material," Energies, MDPI, vol. 14(11), pages 1-21, June.
    6. Xia, B.Q. & Zhao, C.Y. & Yan, J. & Khosa, A.A., 2020. "Development of granular thermochemical heat storage composite based on calcium oxide," Renewable Energy, Elsevier, vol. 147(P1), pages 969-978.
    7. Adrián Caraballo & Santos Galán-Casado & Ángel Caballero & Sara Serena, 2021. "Molten Salts for Sensible Thermal Energy Storage: A Review and an Energy Performance Analysis," Energies, MDPI, vol. 14(4), pages 1-15, February.
    8. Han, Rui & Gao, Jihui & Wei, Siyu & Su, Yanlin & Sun, Fei & Zhao, Guangbo & Qin, Yukun, 2018. "Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage," Applied Energy, Elsevier, vol. 231(C), pages 412-422.
    9. Chi, Changyun & Li, Yingjie & Zhang, Wan & Wang, Zeyan, 2019. "Synthesis of a hollow microtubular Ca/Al sorbent with high CO2 uptake by hard templating," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    10. Flegkas, S. & Birkelbach, F. & Winter, F. & Freiberger, N. & Werner, A., 2018. "Fluidized bed reactors for solid-gas thermochemical energy storage concepts - Modelling and process limitations," Energy, Elsevier, vol. 143(C), pages 615-623.
    11. Yupeng Feng & Xuhan Li & Haowen Wu & Chaoran Li & Man Zhang & Hairui Yang, 2023. "Critical Review of Ca(OH) 2 /CaO Thermochemical Energy Storage Materials," Energies, MDPI, vol. 16(7), pages 1-23, March.
    12. Vigneshwaran, K. & Sodhi, Gurpreet Singh & Muthukumar, P. & Guha, Anurag & Senthilmurugan, S., 2019. "Experimental and numerical investigations on high temperature cast steel based sensible heat storage system," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    13. Seon Tae Kim & Haruka Miura & Hiroki Takasu & Yukitaka Kato & Alexandr Shkatulov & Yuri Aristov, 2019. "Adapting the MgO-CO 2 Working Pair for Thermochemical Energy Storage by Doping with Salts: Effect of the (LiK)NO 3 Content," Energies, MDPI, vol. 12(12), pages 1-13, June.
    14. Su, Chenglin & Duan, Lunbo & Donat, Felix & Anthony, Edward John, 2018. "From waste to high value utilization of spent bleaching clay in synthesizing high-performance calcium-based sorbent for CO2 capture," Applied Energy, Elsevier, vol. 210(C), pages 117-126.
    15. Scapino, Luca & Zondag, Herbert A. & Van Bael, Johan & Diriken, Jan & Rindt, Camilo C.M., 2017. "Sorption heat storage for long-term low-temperature applications: A review on the advancements at material and prototype scale," Applied Energy, Elsevier, vol. 190(C), pages 920-948.
    16. Ma, Xiaotong & Li, Yingjie & Duan, Lunbo & Anthony, Edward & Liu, Hantao, 2018. "CO2 capture performance of calcium-based synthetic sorbent with hollow core-shell structure under calcium looping conditions," Applied Energy, Elsevier, vol. 225(C), pages 402-412.
    17. Zhang, Wan & Li, Yingjie & He, Zirui & Ma, Xiaotong & Song, Haiping, 2017. "CO2 capture by carbide slag calcined under high-concentration steam and energy requirement in calcium looping conditions," Applied Energy, Elsevier, vol. 206(C), pages 869-878.
    18. André, Laurie & Abanades, Stéphane & Flamant, Gilles, 2016. "Screening of thermochemical systems based on solid-gas reversible reactions for high temperature solar thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 64(C), pages 703-715.
    19. Guillermo Martinez Castilla & Diana Carolina Guío-Pérez & Stavros Papadokonstantakis & David Pallarès & Filip Johnsson, 2021. "Techno-Economic Assessment of Calcium Looping for Thermochemical Energy Storage with CO 2 Capture," Energies, MDPI, vol. 14(11), pages 1-17, May.
    20. Wang, Ke & Zhou, Zhongyun & Zhao, Pengfei & Yin, Zeguang & Su, Zhen & Sun, Ji, 2016. "Synthesis of a highly efficient Li4SiO4 ceramic modified with a gluconic acid-based carbon coating for high-temperature CO2 capture," Applied Energy, Elsevier, vol. 183(C), pages 1418-1427.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:155:y:2018:i:c:p:128-138. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.