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Kinetics models of transesterification reaction for biodiesel production: A theoretical analysis

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  • Ezzati, Rohollah
  • Ranjbar, Shahram
  • Soltanabadi, Azim

Abstract

The kinetics of the transesterification reaction has been explored theoretically. A general rate equation (GRE) was obtained for kinetics modeling of transesterification at the entire time of reaction based on a three-step mechanism. It has been shown that the GRE model converts to a Second-Order (SO) model at short initial times of reaction and it converts to Pseudo-First-Order (PFO) model at short initial times of reaction and high concentration of alcohol. Also, a modified form of the Second-Order model (MSO) was derived when the reaction is spontaneous (at ΔrG≪0 conditions or at short initial times of reaction). The accuracy of theoretical models and our assumptions was evaluated by three sets of experimental data selected at literature. It has been shown that the accuracy of PFO, SO, and MSO models followed the order of MSO > SO > PFO at short initial times while the GRE model is a suitable kinetics model at the entire times of reaction. Also, our research, contrary to what has been reported so far in published papers, shows that pseudo-first-order and second-order models are only accurate for kinetics modeling of the transesterification reaction at short initial times of reaction.

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  • Ezzati, Rohollah & Ranjbar, Shahram & Soltanabadi, Azim, 2021. "Kinetics models of transesterification reaction for biodiesel production: A theoretical analysis," Renewable Energy, Elsevier, vol. 168(C), pages 280-296.
    • Handle: RePEc:eee:renene:v:168:y:2021:i:c:p:280-296
    DOI: 10.1016/j.renene.2020.12.055
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    1. Ramezani, K. & Rowshanzamir, S. & Eikani, M.H., 2010. "Castor oil transesterification reaction: A kinetic study and optimization of parameters," Energy, Elsevier, vol. 35(10), pages 4142-4148.
    2. Sulaiman, Nur Fatin & Hashim, Ainul Nadia Nor & Toemen, Susilawati & Rosid, Salmiah Jamal Mat & Mokhtar, Wan Nur Aini Wan & Nadarajan, Renugambaal & Bakar, Wan Azelee Wan Abu, 2020. "Biodiesel production from refined used cooking oil using co-metal oxide catalyzed transesterification," Renewable Energy, Elsevier, vol. 153(C), pages 1-11.
    3. Pessoa Junior, Wanison A.G. & Takeno, Mitsuo L. & Nobre, Francisco X. & Barros, Silma de S. & Sá, Ingrity S.C. & Silva, Edson P. & Manzato, Lizandro & Iglauer, Stefan & de Freitas, Flávio A., 2020. "Application of water treatment sludge as a low-cost and eco-friendly catalyst in the biodiesel production via fatty acids esterification: Process optimization," Energy, Elsevier, vol. 213(C).
    4. Lawan, Ibrahim & Garba, Zahraddeen N. & Zhou, Weiming & Zhang, Mingxin & Yuan, Zhanhui, 2020. "Synergies between the microwave reactor and CaO/zeolite catalyst in waste lard biodiesel production," Renewable Energy, Elsevier, vol. 145(C), pages 2550-2560.
    5. Xie, Wenlei & Wang, Hao, 2020. "Immobilized polymeric sulfonated ionic liquid on core-shell structured Fe3O4/SiO2 composites: A magnetically recyclable catalyst for simultaneous transesterification and esterifications of low-cost oi," Renewable Energy, Elsevier, vol. 145(C), pages 1709-1719.
    6. Patchimpet, Jaran & Simpson, Benjamin K. & Sangkharak, Kanokphorn & Klomklao, Sappasith, 2020. "Optimization of process variables for the production of biodiesel by transesterification of used cooking oil using lipase from Nile tilapia viscera," Renewable Energy, Elsevier, vol. 153(C), pages 861-869.
    7. Silitonga, A.S. & Shamsuddin, A.H. & Mahlia, T.M.I. & Milano, Jassinne & Kusumo, F. & Siswantoro, Joko & Dharma, S. & Sebayang, A.H. & Masjuki, H.H. & Ong, Hwai Chyuan, 2020. "Biodiesel synthesis from Ceiba pentandra oil by microwave irradiation-assisted transesterification: ELM modeling and optimization," Renewable Energy, Elsevier, vol. 146(C), pages 1278-1291.
    8. Ndiaye, Mbalo & Arhaliass, Abdellah & Legrand, Jack & Roelens, Guillaume & Kerihuel, Anthony, 2020. "Reuse of waste animal fat in biodiesel: Biorefining heavily-degraded contaminant-rich waste animal fat and formulation as diesel fuel additive," Renewable Energy, Elsevier, vol. 145(C), pages 1073-1079.
    9. Jayaraman, Jayaprabakar & Alagu, Karthikeyan & Appavu, Prabhu & Joy, Nivin & Jayaram, Parthipan & Mariadoss, Anish, 2020. "Enzymatic production of biodiesel using lipase catalyst and testing of an unmodified compression ignition engine using its blends with diesel," Renewable Energy, Elsevier, vol. 145(C), pages 399-407.
    10. Pascoal, C.V.P. & Oliveira, A.L.L. & Figueiredo, D.D. & Assunção, J.C.C., 2020. "Optimization and kinetic study of ultrasonic-mediated in situ transesterification for biodiesel production from the almonds of Syagrus cearensis," Renewable Energy, Elsevier, vol. 147(P1), pages 1815-1824.
    11. Muanruksa, Papasanee & Kaewkannetra, Pakawadee, 2020. "Combination of fatty acids extraction and enzymatic esterification for biodiesel production using sludge palm oil as a low-cost substrate," Renewable Energy, Elsevier, vol. 146(C), pages 901-906.
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