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Metal hydrated-salts as efficient and reusable catalysts for pre-treating waste cooking oils and animal fats for an effective production of biodiesel

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  • di Bitonto, Luigi
  • Pastore, Carlo

Abstract

A very efficient chemical pre-treatment method that uses cheap and safe hydrated-salts as catalysts for the conversion of waste cooking oils and animal fats having a high Free Fatty Acids (FFAs) content into an oily feedstock convertible into biodiesel through a conventional route (basic catalysis) was investigated. These hydrated-salts allow FFAs to be efficiently (>99%) esterified with alcohols under very mild conditions (343 K, 2 h). At the end of this treatment, a very convenient separation of products was verified. Two different phases were eventually obtained: an upper alcoholic phase, which contains most of the unreacted alcohol, water obtained by direct-esterification (>95%), and the salt that was used as catalyst (recovery >99%); and a lower oily-phase mainly composed of glycerides, methyl-esters derived from direct-esterification of FFAs (residual acidity of about 0.8 mg KOH/g), and part of unreacted alcohol (7–10%wt). Such a separation was convenient because the oily-phase could be directly trans-esterified through conventional base-catalysis, without any further pre-treatments, thus avoiding production of salty-waste. Also, the alcoholic phase could be recovered and directly re-used for new pre-treatments cycles of fresh waste-oils. A final scheme of the proposed process was discussed and the relevant advantages with respect to conventional routes were highlighted.

Suggested Citation

  • di Bitonto, Luigi & Pastore, Carlo, 2019. "Metal hydrated-salts as efficient and reusable catalysts for pre-treating waste cooking oils and animal fats for an effective production of biodiesel," Renewable Energy, Elsevier, vol. 143(C), pages 1193-1200.
    • Handle: RePEc:eee:renene:v:143:y:2019:i:c:p:1193-1200
    DOI: 10.1016/j.renene.2019.05.100
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    References listed on IDEAS

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    1. Atabani, A.E. & Silitonga, A.S. & Ong, H.C. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Fayaz, H., 2013. "Non-edible vegetable oils: A critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 211-245.
    2. di Bitonto, Luigi & Lopez, Antonio & Mascolo, Giuseppe & Mininni, Giuseppe & Pastore, Carlo, 2016. "Efficient solvent-less separation of lipids from municipal wet sewage scum and their sustainable conversion into biodiesel," Renewable Energy, Elsevier, vol. 90(C), pages 55-61.
    3. Salvi, B.L. & Panwar, N.L., 2012. "Biodiesel resources and production technologies – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3680-3689.
    4. Ma, Yingqun & Wang, Qunhui & Sun, Xiaohong & Wu, Chuanfu & Gao, Zhen, 2017. "Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst," Renewable Energy, Elsevier, vol. 107(C), pages 522-530.
    5. Ma, Yingqun & Wang, Qunhui & Gao, Zhen & Sun, Xiaohong & Wang, Nan & Niu, Ruxuan & Ma, Hongzhi, 2016. "Transesterification of waste cooking oil using FeCl3-modified resin catalyst and the research of catalytic mechanism," Renewable Energy, Elsevier, vol. 86(C), pages 643-650.
    6. Baskar, G. & Aiswarya, R., 2016. "Trends in catalytic production of biodiesel from various feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 496-504.
    7. Bozbas, Kahraman, 2008. "Biodiesel as an alternative motor fuel: Production and policies in the European Union," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 542-552, February.
    8. Borugadda, Venu Babu & Goud, Vaibhav V., 2012. "Biodiesel production from renewable feedstocks: Status and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4763-4784.
    9. D'Souza, Reena & Vats, Tripti & Chattree, Amit & Siril, Prem Felix, 2018. "Graphene supported magnetically separable solid acid catalyst for the single step conversion of waste cooking oil to biodiesel," Renewable Energy, Elsevier, vol. 126(C), pages 1064-1073.
    10. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
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    Cited by:

    1. Carlo Pastore & Valeria D’Ambrosio, 2021. "Intensification of Processes for the Production of Ethyl Levulinate Using AlCl 3 ·6H 2 O," Energies, MDPI, vol. 14(5), pages 1-11, February.
    2. Sandouqa, Arwa & Al-Hamamre, Zayed, 2021. "Economical evaluation of jojoba cultivation for biodiesel production in Jordan," Renewable Energy, Elsevier, vol. 177(C), pages 1116-1132.
    3. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    4. di Bitonto, Luigi & Reynel-Ávila, Hilda Elizabeth & Mendoza-Castillo, Didilia Ileana & Bonilla-Petriciolet, Adrián & Durán-Valle, Carlos J. & Pastore, Carlo, 2020. "Synthesis and characterization of nanostructured calcium oxides supported onto biochar and their application as catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 160(C), pages 52-66.
    5. Ella Cebisa Linganiso & Boitumelo Tlhaole & Lindokuhle Precious Magagula & Silas Dziike & Linda Zikhona Linganiso & Tshwafo Elias Motaung & Nosipho Moloto & Zikhona Nobuntu Tetana, 2022. "Biodiesel Production from Waste Oils: A South African Outlook," Sustainability, MDPI, vol. 14(4), pages 1-21, February.
    6. di Bitonto, Luigi & Locaputo, Vito & D'Ambrosio, Valeria & Pastore, Carlo, 2020. "Direct Lewis-Brønsted acid ethanolysis of sewage sludge for production of liquid fuels," Applied Energy, Elsevier, vol. 259(C).

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