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Esterification efficiency improvement of carbon-based solid acid catalysts induced by biomass pretreatments: Intrinsic mechanism

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  • Zhang, Bingxin
  • Gao, Ming
  • Tang, Weiqi
  • Wang, Xiaona
  • Wu, Chuanfu
  • Wang, Qunhui
  • Cheung, Siu Ming
  • Chen, Xiankun

Abstract

Effect of various reagents (i.e. H2O2, H2SO4, H3PO4 and their mixtures) pretreatments on esterification activities of carbon-based solid acid catalysts synthesised by one-step sulphonation (150 °C for 4 h) was investigated. The results demonstrated that sulphonic acid density of catalyst positively correlated with the esterification efficiency and the high lignin content of the biomass stimulated the loading of sulphonic acid groups. The bamboo powder pretreated with 1% H2SO4 yielded the highest lignin content (from 26.4% to 33.0%). The corresponding catalyst yielded the highest esterification efficiency (97.3%), which decreased to 82.9% after four cycles. On the other hand, the bamboo powder pretreated by H2O2 and 30% H3PO4 brought little effect on the increment of lignin content and esterification efficiency of the catalysts. Therefore, biomass pretreatment could be a solution of disposal acidic wastewater (like catalyst sulphonation wastewater) by reusing it as pretreatment reagents and improving the esterification efficiency of the catalysts.

Suggested Citation

  • Zhang, Bingxin & Gao, Ming & Tang, Weiqi & Wang, Xiaona & Wu, Chuanfu & Wang, Qunhui & Cheung, Siu Ming & Chen, Xiankun, 2023. "Esterification efficiency improvement of carbon-based solid acid catalysts induced by biomass pretreatments: Intrinsic mechanism," Energy, Elsevier, vol. 263(PB).
    • Handle: RePEc:eee:energy:v:263:y:2023:i:pb:s0360544222024926
    DOI: 10.1016/j.energy.2022.125606
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    1. Flores, Ken P. & Omega, Jan Laurence O. & Cabatingan, Luis K. & Go, Alchris W. & Agapay, Ramelito C. & Ju, Yi-Hsu, 2019. "Simultaneously carbonized and sulfonated sugarcane bagasse as solid acid catalyst for the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 130(C), pages 510-523.
    2. Zhang, Bingxin & Gao, Ming & Geng, Jiayu & Cheng, Yuwei & Wang, Xiaona & Wu, Chuanfu & Wang, Qunhui & Liu, Shu & Cheung, Siu Ming, 2021. "Catalytic performance and deactivation mechanism of a one-step sulfonated carbon-based solid-acid catalyst in an esterification reaction," Renewable Energy, Elsevier, vol. 164(C), pages 824-832.
    3. Guo, Feng & Xiu, Zhi-Long & Liang, Zhi-Xia, 2012. "Synthesis of biodiesel from acidified soybean soapstock using a lignin-derived carbonaceous catalyst," Applied Energy, Elsevier, vol. 98(C), pages 47-52.
    4. Lawan, Ibrahim & Garba, Zahraddeen N. & Zhou, Weiming & Zhang, Mingxin & Yuan, Zhanhui, 2020. "Synergies between the microwave reactor and CaO/zeolite catalyst in waste lard biodiesel production," Renewable Energy, Elsevier, vol. 145(C), pages 2550-2560.
    5. Sandouqa, Arwa & Al-Hamamre, Zayed & Asfar, Jamil, 2019. "Preparation and performance investigation of a lignin-based solid acid catalyst manufactured from olive cake for biodiesel production," Renewable Energy, Elsevier, vol. 132(C), pages 667-682.
    6. Ngaosuwan, Kanokwan & Goodwin, James G. & Prasertdham, Piyasan, 2016. "A green sulfonated carbon-based catalyst derived from coffee residue for esterification," Renewable Energy, Elsevier, vol. 86(C), pages 262-269.
    7. Shu, Qing & Gao, Jixian & Nawaz, Zeeshan & Liao, Yuhui & Wang, Dezheng & Wang, Jinfu, 2010. "Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst," Applied Energy, Elsevier, vol. 87(8), pages 2589-2596, August.
    8. Dechakhumwat, Suppasate & Hongmanorom, Plaifa & Thunyaratchatanon, Chachchaya & Smith, Siwaporn Meejoo & Boonyuen, Supakorn & Luengnaruemitchai, Apanee, 2020. "Catalytic activity of heterogeneous acid catalysts derived from corncob in the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 148(C), pages 897-906.
    9. Mendaros, Czarina M. & Go, Alchris W. & Nietes, Winston Jose T. & Gollem, Babe Eden Joy O. & Cabatingan, Luis K., 2020. "Direct sulfonation of cacao shell to synthesize a solid acid catalyst for the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 152(C), pages 320-330.
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    Cited by:

    1. Zhang, Bingxin & Gao, Ming & Tang, Weiqi & Wang, Xiaona & Wu, Chuanfu & Wang, Qunhui & Xie, Haijiao, 2023. "Reduced surface sulphonic acid concentration Alleviates carbon-based solid acid catalysts deactivation in biodiesel production," Energy, Elsevier, vol. 271(C).
    2. Ribeiro, Flaviana C.P. & Santos, Jamily L. & Araujo, Rayanne O. & Santos, Vanuza O. & Chaar, Jamal S. & Tenório, Jorge A.S. & de Souza, Luiz K.C., 2024. "Sustainable catalysts for esterification: Sulfonated carbon spheres from biomass waste using hydrothermal carbonization," Renewable Energy, Elsevier, vol. 220(C).

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