IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v168y2021icp981-990.html
   My bibliography  Save this article

Synthesis of the SrO–CaO–Al2O3 trimetallic oxide catalyst for transesterification to produce biodiesel

Author

Listed:
  • Zhang, Yujiao
  • Niu, Shengli
  • Han, Kuihua
  • Li, Yingjie
  • Lu, Chunmei

Abstract

Calcium oxide is one of the most promising heterogeneous catalysts for biodiesel production. However, an inherent drawback of CaO is the leaching of active species into the reaction solution with the degraded reusability. To strengthen the stability, different supports are composited with the SrO–CaO oxide through the hydrothermal method and mass ratio of SrO to CaO are optimized to get the best outcome of the catalyst. Meanwhile, various characterization methods, including TG, XRD, SEM-EDX, CO2-TPD, XPS, ATR-FTIR and ICP-AES, are used to explore the physicochemical properties of catalysts. The 0.4-SrO-CaO-Al2O3 catalyst shows the best catalytic capability in transesterification of palm oil with methanol to produce biodiesel, where the FAME yield of 98.16% is achieved with the molar ratio of methanol to oil of 18:1 and catalyst concentration of 7.5 wt% at 65 °C for 3 h. Besides, ascribed to the greatly reduced leaching out of the active species, this catalyst presents the satisfying reusability and the FAME yield is slightly decreased to 92.61% for the fifth reused cycle. Therefore, this modification method for SrO–CaO–Al2O3 is feasible for enhancing the catalytic stability in transesterification.

Suggested Citation

  • Zhang, Yujiao & Niu, Shengli & Han, Kuihua & Li, Yingjie & Lu, Chunmei, 2021. "Synthesis of the SrO–CaO–Al2O3 trimetallic oxide catalyst for transesterification to produce biodiesel," Renewable Energy, Elsevier, vol. 168(C), pages 981-990.
    • Handle: RePEc:eee:renene:v:168:y:2021:i:c:p:981-990
    DOI: 10.1016/j.renene.2020.12.132
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120320723
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.12.132?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, Rongyan & Zhu, Fenfen & Dong, Yi & Wu, Xuemin & Sun, Yihe & Zhang, Dongrui & Zhang, Tao & Han, Meiling, 2020. "Function promotion of SO42−/Al2O3–SnO2 catalyst for biodiesel production from sewage sludge," Renewable Energy, Elsevier, vol. 147(P1), pages 275-283.
    2. Papargyriou, Despoina & Broumidis, Emmanouil & de Vere-Tucker, Matthew & Gavrielides, Stelios & Hilditch, Paul & Irvine, John T.S. & Bonaccorso, Alfredo D., 2019. "Investigation of solid base catalysts for biodiesel production from fish oil," Renewable Energy, Elsevier, vol. 139(C), pages 661-669.
    3. Nayebzadeh, Hamed & Haghighi, Mohammad & Saghatoleslami, Naser & Alaei, Shervin & Yousefi, Sina, 2019. "Texture/phase evolution during plasma treatment of microwave-combustion synthesized KOH/Ca12Al14O33-C nanocatalyst for reusability enhancement in conversion of canola oil to biodiesel," Renewable Energy, Elsevier, vol. 139(C), pages 28-39.
    4. Lawan, Ibrahim & Garba, Zahraddeen N. & Zhou, Weiming & Zhang, Mingxin & Yuan, Zhanhui, 2020. "Synergies between the microwave reactor and CaO/zeolite catalyst in waste lard biodiesel production," Renewable Energy, Elsevier, vol. 145(C), pages 2550-2560.
    5. Mishra, Purna Chandra & Nayak, Swarup Kumar, 2018. "Pre-and post-mixed hybrid biodiesel blends as alternative energy fuels-an experimental case study on turbo-charged direct injection diesel engine," Energy, Elsevier, vol. 160(C), pages 910-923.
    6. Mahlia, T.M.I. & Syazmi, Z.A.H.S. & Mofijur, M. & Abas, A.E. Pg & Bilad, M.R. & Ong, Hwai Chyuan & Silitonga, A.S., 2020. "Patent landscape review on biodiesel production: Technology updates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    7. Niu, Shengli & Zhang, Xiangyu & Ning, Yilin & Zhang, Yujiao & Qu, Tongxin & Hu, Xun & Gong, Zhiqiang & Lu, Chunmei, 2020. "Dolomite incorporated with cerium to enhance the stability in catalyzing transesterification for biodiesel production," Renewable Energy, Elsevier, vol. 154(C), pages 107-116.
    8. Farooq, Muhammad & Ramli, Anita & Naeem, Abdul, 2015. "Biodiesel production from low FFA waste cooking oil using heterogeneous catalyst derived from chicken bones," Renewable Energy, Elsevier, vol. 76(C), pages 362-368.
    9. Goh, Brandon Han Hoe & Ong, Hwai Chyuan & Cheah, Mei Yee & Chen, Wei-Hsin & Yu, Kai Ling & Mahlia, Teuku Meurah Indra, 2019. "Sustainability of direct biodiesel synthesis from microalgae biomass: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 59-74.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Ying & Niu, Shengli & Hao, Yanan & Zhou, Wenbo & Wang, Jun & Liu, Jiangwei, 2022. "Role of oxygen vacancy on activity of Fe-doped SrTiO3 perovskite bifunctional catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 199(C), pages 1258-1271.
    2. Torkzaban, Sama & Feyzi, Mostafa & norouzi, Leila, 2022. "A novel robust CaO/ZnFe2O4 hollow magnetic microspheres heterogenous catalyst for synthesis biodiesel from waste frying sunflower oil," Renewable Energy, Elsevier, vol. 200(C), pages 996-1007.
    3. Shir Reen Chia & Saifuddin Nomanbhay & Kit Wayne Chew & Pau Loke Show & Jassinnee Milano & Abd Halim Shamsuddin, 2022. "Indigenous Materials as Catalyst Supports for Renewable Diesel Production in Malaysia," Energies, MDPI, vol. 15(8), pages 1-31, April.
    4. Chanthon, Narita & Munbupphachart, Nattawadee & Ngaosuwan, Kanokwan & Kiatkittipong, Worapon & Wongsawaeng, Doonyapong & Mens, Weerinda & Rokhum, Samuel Lalthazuala & Assabumrungrat, Suttichai, 2023. "Metal loading on CaO/Al2O3 pellet catalyst as a booster for transesterification in biodiesel production," Renewable Energy, Elsevier, vol. 218(C).
    5. Hoora Mazaheri & Hwai Chyuan Ong & Zeynab Amini & Haji Hassan Masjuki & M. Mofijur & Chia Hung Su & Irfan Anjum Badruddin & T.M. Yunus Khan, 2021. "An Overview of Biodiesel Production via Calcium Oxide Based Catalysts: Current State and Perspective," Energies, MDPI, vol. 14(13), pages 1-23, July.
    6. Jesús Andrés Tavizón-Pozos & Gerardo Chavez-Esquivel & Víctor Alejandro Suárez-Toriello & Carlos Eduardo Santolalla-Vargas & Oscar Abel Luévano-Rivas & Omar Uriel Valdés-Martínez & Alfonso Talavera-Ló, 2021. "State of Art of Alkaline Earth Metal Oxides Catalysts Used in the Transesterification of Oils for Biodiesel Production," Energies, MDPI, vol. 14(4), pages 1-24, February.
    7. Lani, Nurul Saadiah & Ngadi, Norzita & Haron, Saharudin & Mohammed Inuwa, Ibrahim & Anako Opotu, Lawal, 2024. "The catalytic effect of calcium oxide and magnetite loading on magnetically supported calcium oxide-zeolite catalyst for biodiesel production from used cooking oil," Renewable Energy, Elsevier, vol. 222(C).
    8. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fazril Ideris & Mohd Faiz Muaz Ahmad Zamri & Abd Halim Shamsuddin & Saifuddin Nomanbhay & Fitranto Kusumo & Islam Md Rizwanul Fattah & Teuku Meurah Indra Mahlia, 2022. "Progress on Conventional and Advanced Techniques of In Situ Transesterification of Microalgae Lipids for Biodiesel Production," Energies, MDPI, vol. 15(19), pages 1-32, September.
    2. Li, Ying & Niu, Shengli & Hao, Yanan & Zhou, Wenbo & Wang, Jun & Liu, Jiangwei, 2022. "Role of oxygen vacancy on activity of Fe-doped SrTiO3 perovskite bifunctional catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 199(C), pages 1258-1271.
    3. Teuku Meurah Indra Riayatsyah & Razali Thaib & Arridina Susan Silitonga & Jassinnee Milano & Abd. Halim Shamsuddin & Abdi Hanra Sebayang & Rahmawaty & Joko Sutrisno & Teuku Meurah Indra Mahlia, 2021. "Biodiesel Production from Reutealis trisperma Oil Using Conventional and Ultrasonication through Esterification and Transesterification," Sustainability, MDPI, vol. 13(6), pages 1-15, March.
    4. Hwai Chyuan Ong & M. Mofijur & A.S. Silitonga & D. Gumilang & Fitranto Kusumo & T.M.I. Mahlia, 2020. "Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils," Energies, MDPI, vol. 13(6), pages 1-14, March.
    5. Qu, Tongxin & Niu, Shengli & Gong, Zhiqiang & Han, Kuihua & Wang, Yongzheng & Lu, Chunmei, 2020. "Wollastonite decorated with calcium oxide as heterogeneous transesterification catalyst for biodiesel production: Optimized by response surface methodology," Renewable Energy, Elsevier, vol. 159(C), pages 873-884.
    6. M. Mofijur & F. Kusumo & I. M. Rizwanul Fattah & H. M. Mahmudul & M. G. Rasul & A. H. Shamsuddin & T. M. I. Mahlia, 2020. "Resource Recovery from Waste Coffee Grounds Using Ultrasonic-Assisted Technology for Bioenergy Production," Energies, MDPI, vol. 13(7), pages 1-15, April.
    7. Jing Han Siow & Muhammad Roil Bilad & Wahyu Caesarendra & Jia Jia Leam & Mohammad Azmi Bustam & Nonni Soraya Sambudi & Yusuf Wibisono & Teuku Meurah Indra Mahlia, 2021. "Progress in Development of Nanostructured Manganese Oxide as Catalyst for Oxygen Reduction and Evolution Reaction," Energies, MDPI, vol. 14(19), pages 1-16, October.
    8. Hamed Pourzolfaghar & Faisal Abnisa & Wan Mohd Ashri Wan Daud & Mohamed Kheireddine Aroua & Teuku Meurah Indra Mahlia, 2020. "Catalyst Characteristics and Performance of Silica-Supported Zinc for Hydrodeoxygenation of Phenol," Energies, MDPI, vol. 13(11), pages 1-13, June.
    9. Nong, Duy & Nguyen, Duong Binh & Nguyen, Trung H. & Wang, Can & Siriwardana, Mahinda, 2020. "A stronger energy strategy for a new era of economic development in Vietnam: A quantitative assessment," Energy Policy, Elsevier, vol. 144(C).
    10. Lau, Allen K.S. & Bilad, M.R. & Nordin, N.A.H.M. & Faungnawakij, Kajornsak & Narkkun, Thanitporn & Wang, David K. & Mahlia, T.M.I. & Jaafar, Juhana, 2020. "Effect of membrane properties on tilted panel performance of microalgae biomass filtration for biofuel feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 120(C).
    11. Mahlia, T.M.I. & Syazmi, Z.A.H.S. & Mofijur, M. & Abas, A.E. Pg & Bilad, M.R. & Ong, Hwai Chyuan & Silitonga, A.S., 2020. "Patent landscape review on biodiesel production: Technology updates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    12. Lani, Nurul Saadiah & Ngadi, Norzita & Inuwa, Ibrahim Mohammed, 2020. "New route for the synthesis of silica-supported calcium oxide catalyst in biodiesel production," Renewable Energy, Elsevier, vol. 156(C), pages 1266-1277.
    13. Lani, Nurul Saadiah & Ngadi, Norzita & Haron, Saharudin & Mohammed Inuwa, Ibrahim & Anako Opotu, Lawal, 2024. "The catalytic effect of calcium oxide and magnetite loading on magnetically supported calcium oxide-zeolite catalyst for biodiesel production from used cooking oil," Renewable Energy, Elsevier, vol. 222(C).
    14. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.
    15. Khan, Ihtisham Wali & Naeem, Abdul & Farooq, Muhammad & Mahmood, Tahira & Ahmad, Bashir & Hamayun, Muhammad & Ahmad, Zahoor & Saeed, Tooba, 2020. "Catalytic conversion of spent frying oil into biodiesel over raw and 12-tungsto-phosphoric acid modified clay," Renewable Energy, Elsevier, vol. 155(C), pages 181-188.
    16. Zharova, P.A. & Chistyakov, A.V. & Shapovalov, S.S. & Pasynskii, A.A. & Tsodikov, M.V., 2019. "Original Pt-Sn/Al2O3 catalyst for selective hydrodeoxygenation of vegetable oils," Energy, Elsevier, vol. 172(C), pages 18-25.
    17. Pang, Yunji & Wu, Yuting & Chen, Yisheng & Luo, Fuliang & Chen, Junjun, 2020. "Degradation effect of Ce/Al2O3 catalyst on pyrolysis volatility of pine," Renewable Energy, Elsevier, vol. 162(C), pages 134-143.
    18. Enagi, Ibrahim I. & Al-attab, K.A. & Zainal, Z.A., 2018. "Liquid biofuels utilization for gas turbines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 43-55.
    19. Thangarasu, Vinoth & M, Angkayarkan Vinayakaselvi & Ramanathan, Anand, 2021. "Artificial neural network approach for parametric investigation of biodiesel synthesis using biocatalyst and engine characteristics of diesel engine fuelled with Aegle Marmelos Correa biodiesel," Energy, Elsevier, vol. 230(C).
    20. Laura Aguado-Deblas & Jesús Hidalgo-Carrillo & Felipa M. Bautista & Carlos Luna & Juan Calero & Alejandro Posadillo & Antonio A. Romero & Diego Luna & Rafael Estévez, 2021. "Evaluation of Dimethyl Carbonate as Alternative Biofuel. Performance and Smoke Emissions of a Diesel Engine Fueled with Diesel/Dimethyl Carbonate/Straight Vegetable Oil Triple Blends," Sustainability, MDPI, vol. 13(4), pages 1-14, February.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:168:y:2021:i:c:p:981-990. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.