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Green biodiesel production from Jatropha curcas oil using a carbon-based solid acid catalyst: A process optimization study

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  • Ruatpuia, Joseph V.L.
  • Changmai, Bishwajit
  • Pathak, Ayush
  • Alghamdi, Lana A.
  • Kress, Thomas
  • Halder, Gopinath
  • Wheatley, Andrew E.H.
  • Rokhum, Samuel Lalthazuala

Abstract

Biodiesel production from low cost, inedible oil represents an increasingly important target for reasons of both sustainability and cost. In this work, we comprehensively verify the batch reproducibility of a sulfonic acid functionalized carbonaceous material (SAFACAM) as catalyst for biodiesel production from inedible feedstock Jatropha curcas oil (JCO). The current catalyst benefits the environment through its atom-efficient, one-pot preparation from an abundant natural biomass derivative (glucose) and has the potential to reduce the overall biodiesel production cost by converting inexpensive raw materials. In this context, JCO has emerged as a crop of interest to the energy sector, potentially providing a reliable and renewable energy source for many countries. Through a central composite design (CCD) approach using response surface methodology (RSM), a 98.7 ± 0.6% conversion of biodiesel is achieved (methanol-to-oil molar ratio 20:1, reaction time 50 min, reaction temperature 120 °C and catalyst loading 9 wt % (with respect to oil)). The chemically satisfactory composition of the biodiesel product has been verified, the reusability of catalyst has been tested, and a significant enhancement in performance when using microwave heating demonstrated. An 83.0 ± 0.8% conversion of JCO is reported in the fifth cycle of reuse.

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  • Ruatpuia, Joseph V.L. & Changmai, Bishwajit & Pathak, Ayush & Alghamdi, Lana A. & Kress, Thomas & Halder, Gopinath & Wheatley, Andrew E.H. & Rokhum, Samuel Lalthazuala, 2023. "Green biodiesel production from Jatropha curcas oil using a carbon-based solid acid catalyst: A process optimization study," Renewable Energy, Elsevier, vol. 206(C), pages 597-608.
    • Handle: RePEc:eee:renene:v:206:y:2023:i:c:p:597-608
    DOI: 10.1016/j.renene.2023.02.041
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    2. Das, Arpita & Li, Hui & Kataki, Rupam & Agrawal, Pratibha S. & Moyon, N.S. & Gurunathan, Baskar & Rokhum, Samuel Lalthazuala, 2023. "Terminalia arjuna bark – A highly efficient renewable heterogeneous base catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 212(C), pages 185-196.
    3. Aghababaeian, Shiva & Beygzadeh, Mojtaba & Dehghan, Maziar & Halek, Farah-Sadat & Aminy, Mohammad, 2024. "Energy and economic aspects of efficient radiative heating for biodiesel production: Prospects and challenges of using solid magnetic CaO/CoFe2O4 nano-catalyst," Energy, Elsevier, vol. 289(C).
    4. Saikia, Kankana & Das, Arpita & Sema, Atoholi H. & Basumatary, Sanjay & Shaemningwar Moyon, N. & Mathimani, Thangavel & Rokhum, Samuel Lalthazuala, 2024. "Response surface optimization, kinetics, thermodynamics, and life cycle cost analysis of biodiesel production from Jatropha curcas oil using biomass-based functional activated carbon catalyst," Renewable Energy, Elsevier, vol. 229(C).
    5. Yuan, Zong & Zhu, Jishen & Lu, Jie & Li, Yueyun & Ding, Jincheng, 2024. "Preparation of biodiesel by transesterification of castor oil catalyzed by flaky halloysite supported ZnO/SnO2 heterojunction photocatalyst," Renewable Energy, Elsevier, vol. 227(C).

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