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Using solar microreactors and photocatalysts to synthesize biodiesel

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  • Aghel, Babak
  • Biabani, Arash

Abstract

This paper investigates the transesterification of waste cooking oil using TiO2, CuO, and GO as catalysts in solar plain and helical glass microreactors. Catalyst properties were determined through XRD, SEM, and FT-IR analyses. Response surface methodology was employed to optimize biodiesel production, with GO catalyst and helical microreactor proving most effective due to their unique geometry. The highest biodiesel purity was achieved with GO at 99.98%, followed by TiO2 at 95.78% and CuO at 93.55%, all with a 3% catalyst dose, 200 s residence time, and oil-to-methanol volume ratio of 2. The study utilized solar energy and glass microreactors, resulting in a 94% reduction in energy consumption.

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  • Aghel, Babak & Biabani, Arash, 2024. "Using solar microreactors and photocatalysts to synthesize biodiesel," Renewable Energy, Elsevier, vol. 220(C).
    • Handle: RePEc:eee:renene:v:220:y:2024:i:c:s0960148123015690
    DOI: 10.1016/j.renene.2023.119654
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    References listed on IDEAS

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    1. Cao, Xiyue & Xu, Hui & Li, Fosheng & Zou, Yijun & Ran, Yulu & Ma, Xiaorui & Cao, Yu & Xu, Qingrui & Qiao, Dairong & Cao, Yi, 2021. "One-step direct transesterification of wet yeast for biodiesel production catalyzed by magnetic nanoparticle-immobilized lipase," Renewable Energy, Elsevier, vol. 171(C), pages 11-21.
    2. Aghel, Babak & Gouran, Ashkan & Nasirmanesh, Farzad, 2022. "Transesterification of waste cooking oil using clinoptilolite/ industrial phosphoric waste as green and environmental catalysts," Energy, Elsevier, vol. 244(PB).
    3. Ambat, Indu & Srivastava, Varsha & Sillanpää, Mika, 2018. "Recent advancement in biodiesel production methodologies using various feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 356-369.
    4. Aghel, Babak & Gouran, Ashkan & Parandi, Ehsan & Jumeh, Binta Hadi & Nodeh, Hamid Rashidi, 2022. "Production of biodiesel from high acidity waste cooking oil using nano GO@MgO catalyst in a microreactor," Renewable Energy, Elsevier, vol. 200(C), pages 294-302.
    5. Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.
    6. Borah, Manash Jyoti & Devi, Anuchaya & Borah, Raju & Deka, Dhanapati, 2019. "Synthesis and application of Co doped ZnO as heterogeneous nanocatalyst for biodiesel production from non-edible oil," Renewable Energy, Elsevier, vol. 133(C), pages 512-519.
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